Harmless resource utilization method of zinc electrolysis acid leaching residue
An electrolytic zinc acid leaching, harmless technology, applied in sustainable waste treatment, cement production, solid waste management and other directions, can solve the problems of large investment and long process, achieve simple disposal methods, reduce environmental resources and energy consumption and environmental pollution, and the effect of eliminating heavy metal pollution and hidden dangers
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Embodiment 1
[0083] A method for recycling and harmless utilization of electrolytic zinc acid leaching slag: take fresh wet zinc acid leaching slag from a factory, use commercially available P.O42.5 Portland cement powder as the silicate powder, and change The active agent is selected from commercially available silica fume, sodium polyphosphate (a kind of polymeric phosphate), polymerized silica sol, and sodium rosinate microfoam. Zinc acid leaching slag, Portland cement powder, modifier by mass ratio zinc acid leaching slag 83%: silicate powder 12%: modifier (silica fume 3.75%+sodium polyphosphate 0.2%+polysilicon Sol 1% + Sodium Rosinate Microfoam 0.05%) 5% of the ingredients, mixed with a mixer to form a plastic microfoam slurry.
[0084] The plastic micro-foam slurry is poured into a 600×200×250mm block, cured by natural curing, the average compressive strength of 7 days is 7.9MPa, the average compressive strength of 28 days is 11.3MPa, the softening coefficient is 0.98, and the dry d...
Embodiment 2
[0086] A method for recycling and harmless utilization of electrolytic zinc acid leaching slag: take fresh wet zinc acid leaching slag from a factory, use commercially available P.C32.5 grade Portland cement powder as the silicate powder, and change The active agent is selected from commercially available diatomite powder, potassium polyphosphate (a kind of polymer phosphate), and polymerized silica sol. Zinc acid leaching slag, Portland cement powder, modifier by mass ratio zinc acid leaching slag 65%: silicate powder 25%: modifier (diatomite powder 8%+potassium polyphosphate 0.3%+ Polymerized silica sol 1.7%) and 10% of the ingredients are mixed evenly by a mixer to form a slurry-like cementing material.
[0087] Mix the paste-like cement and crushed stone sand evenly according to the mass ratio of paste-like cement 1: crushed stone-sand 3, and shape it into a block of 240×115×53mm, which is naturally cured and cured, with an average resistance of 7 days. Compressive streng...
Embodiment 3
[0090] A method for recycling and harmless utilization of electrolytic zinc acid leaching slag: take fresh wet zinc acid leaching slag from a factory, use commercially available aluminate cement powder as the aluminate powder, and use commercially available aluminate cement powder as the modifier Silica fume, sodium polyphosphate (polyphosphate), sodium metaaluminate, sodium rosinate microfoam. Zinc acid leaching slag, aluminate cement powder, modifier by mass ratio zinc acid leaching slag 70%: aluminate powder 20%: modifier (silica fume 8% + sodium polyphosphate 0.2% + partial aluminum Sodium acid sodium 1.75% + sodium rosin acid microfoam 0.05%) 10% of the ingredients, mixed with a mixer to form a plastic microfoam slurry.
[0091] The plastic micro-foam slurry is poured into a 600×200×250mm block, cured by natural curing, the average compressive strength of 7 days is 9.7MPa, the average compressive strength of 28 days is 13.4MPa, the softening coefficient is 0.96, and the d...
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