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A kind of sncr-based combined mercury removal method and device

A mercury removal and removal technology, applied in separation methods, chemical instruments and methods, mixers, etc., can solve problems such as high cost, high operating cost, and difficulty in further improving denitrification efficiency, so as to improve efficiency and reduce initial investment costs. Effect of low and saving facility settings

Active Publication Date: 2017-11-14
CHINA HUANENG GRP CO LTD +1
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  • Claims
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Problems solved by technology

[0004] The current problem is that although the denitrification efficiency of the SNCR process is difficult to further improve, it has high flexibility and simplicity and can be used in combination with other technologies
In addition, the cost of existing mercury removal technologies is relatively high. For example, the operating cost of activated carbon mercury removal is quite high. To achieve a mercury removal efficiency of 90%, it needs 25,000-70,000 US dollars per pound of mercury treated

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  • A kind of sncr-based combined mercury removal method and device
  • A kind of sncr-based combined mercury removal method and device
  • A kind of sncr-based combined mercury removal method and device

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Embodiment Construction

[0022] The present invention will be further described in detail below in conjunction with specific embodiments, which are explanations of the present invention rather than limitations.

[0023] The present invention is a combined mercury removal method based on SNCR. Solid ammonium chloride and urea are added into the SNCR system as raw materials to form a mixed solution of urea and ammonium chloride, which are then sprayed into the corresponding flue through the SNCR system. NH obtained by thermal decomposition of urea and ammonium chloride 3 NO in flue gas x Reductive removal is carried out, and the zero-valent mercury in the flue gas is oxidized and removed by the HCl obtained by the thermal decomposition of ammonium chloride. When solid ammonium chloride and urea are added to the SNCR system as raw materials, the solid ammonium chloride and urea are mixed according to the required ratio and then added or added sequentially according to the required ratio; the required ra...

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Abstract

The invention provides an SNCR-based combined mercury removal device, which can effectively combine two flue gas treatment technologies, and achieve the purpose of denitrification and mercury removal while reducing costs. It includes two sets of independent metering systems, a set of solution preparation system connected to the output ends of the two sets of metering systems, and a solution delivery system and a solution injection system sequentially connected to the output ends of the solution preparation system; the solution injection system includes injection inlets and spray guns; The injection inlet is set on the furnace in the SNCR system, and the spray gun is connected to the injection inlet and extended into the furnace for setting; two sets of metering systems are used to measure urea and ammonium chloride solids according to the demand for removing NOx and zero-valent mercury . Combining mercury removal technology with SNCR to obtain the superiority of two-in-one technology and develop advanced SNCR technology. On the basis of the original facilities, no additional process equipment is added except for the metering system, making the process more simple, economical, and economical. Capital cost.

Description

technical field [0001] The invention relates to the technical field of flue gas combined pollutant removal, in particular to an SNCR-based combined mercury removal method and device. Background technique [0002] Due to its highly toxic, highly volatile, and accumulative properties in the biological chain, mercury has become a global circular polluting element, and has attracted great attention from domestic and foreign scholars in recent years. Hg emissions from coal-fired power plants can account for 70% of man-made emissions, so the control of mercury pollution emissions from coal-fired power plants has become another focus of environmental protection today. The average mercury content in coal in my country is about 0.22mg / kg, which is much higher than the world average of 0.13mg / kg. Therefore, the mercury pollution control of coal-fired power plants in my country is facing a more severe test. Zero-valent mercury (Hg0) is the main form of Hg emitted from coal-fired power...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01D53/79B01D53/64B01D53/56B01F13/10B01F1/00
Inventor 向小凤张波张向宇高宁徐宏杰
Owner CHINA HUANENG GRP CO LTD
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