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Low-cost slagging and dephosphorizing technique for high-phosphorus molten iron through converter smelting

A converter smelting, low-cost technology, applied in the direction of improving process efficiency, manufacturing converters, etc., can solve the problems of high slagging cost, high slag material consumption, poor slagging effect, etc., to reduce the comprehensive cost per ton of steel, prolong the The effect of good furnace downtime and equipment versatility

Active Publication Date: 2016-06-15
WUKUN STEEL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] (4) In the original process, the timing of adding slag material, the timing of turning down the furnace, and the control of the gun position are unreasonable. For example, the magnesite balls are added too early and the double slag is poured out too early, and the effect of slag removal is difficult to reflect when the slag agent is added too early. Problems such as premature timing of double slag pouring and insufficient deep blowing time at the end point
[0007] Aiming at the problems of excess heat, poor slag melting effect, high slag material consumption and high slagging cost in smelting high-phosphorus molten iron in the above-mentioned converter, the present invention aims to analyze, design and improve the smelting process operation system of each stage of smelting high-phosphorus molten iron in the converter, Propose a low-cost slagging dephosphorization process for smelting high-phosphorus molten iron in a converter to achieve smooth dephosphorization and effectively reduce the cost of comprehensive slagging

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] (1) Raw materials for smelting and slagging:

[0044] The composition and properties of the final slag are as follows: CaO44.90%, MgO12.20%, SiO 2 11.50%, TFe17.20%, P 2 o 5 3.24%, alkalinity 2.9.

[0045] The composition and properties of raw dolomite are as follows: block size 40mm, CaO34.67%, MgO18.22%, SiO 2 0.10%, S0.020%, burn reduction 46%.

[0046] The composition and properties of lime are as follows: CaO89.52%, MgO3.24%, activity 300 (according to 4mol / L hydrochloric acid).

[0047] The composition and properties of lightly burned dolomite are as follows: block size 35mm, CaO34.67%, MgO28.22%, SiO2 2 1.10%, burning by 25%.

[0048] The composition and properties of high phosphorus molten iron are as follows: C4.12%, Si0.45%, Mn0.32%, P0.42%, S0.035%.

[0049] The composition and properties of steel scrap are as follows: C0.18%, Si0.20%, Mn1.15%, S0.028%, P0.032%, the maximum length is 500mm, the maximum height is 300mm, the maximum width is 250mm, and t...

Embodiment 2

[0060] (1) Raw materials for smelting and slagging:

[0061] The composition and properties of the final slag are as follows: CaO42.50%, MgO11.50%, SiO 2 10.60%, TFe18.20%, P 2 o 5 4.24%, alkalinity 4.7.

[0062] The composition and properties of raw dolomite are as follows: block size 30-50mm, CaO35.27%, MgO19.22%, SiO 2 0.12%, S0.025%, burning by 45%.

[0063] The composition and properties of lime are as follows: CaO88.32%, MgO2.92%, activity 320 (according to 4mol / L hydrochloric acid).

[0064] The composition and properties of lightly burned dolomite are as follows: block size 38mm, CaO23.67%, MgO27.82%, SiO2 2 1.15%, burning by 25%.

[0065] The composition and properties of high phosphorus molten iron are as follows: C3.98%, Si0.42%, Mn0.28%, P0.39%, S0.032%.

[0066] The composition and properties of steel scrap are as follows: C0.21%, Si0.18%, Mn1.25%, S0.025%, P0.028%, the maximum length is less than 500mm, the maximum height is 350mm, the maximum width is 250...

Embodiment 3

[0077] (1) Raw materials for smelting and slagging:

[0078]The composition and properties of the final slag are as follows: CaO41.50%, MgO13.50%, SiO 2 10.60%, TFe17.82%, P 2 O 5 3.56%, alkalinity 5.6.

[0079] The composition and properties of raw dolomite are as follows: block size 30~50mm, CaO34.28%, MgO18.88%, SiO 2 0.11%, S0.021%, burning reduction 45.50%.

[0080] The composition and properties of lime are as follows: CaO87.82%, MgO2.32%, activity degree 310 (calculated by 4mol / L hydrochloric acid).

[0081] The composition and properties of lightly burned dolomite are as follows: block size 42mm, CaO38.67%, MgO27.82%, SiO 2 2.11%, 23.% reduction.

[0082] The composition and properties of high phosphorus molten iron are as follows: C4.28%, Si0.33%, Mn0.24%, P0.45%, S0.025%.

[0083] The composition and properties of scrap steel are as follows: C0.20%, Si0.20%, Mn0.95%, S0.028%, P0.028%, the maximum length is less than 400mm, the maximum height is 250mm, the maxi...

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Abstract

The invention discloses a low-cost slagging and dephosphorizing technique for high-phosphorus molten iron through converter smelting. The slagging and dephosphorizing technique comprises the steps of slag remaining and splashing, primary charging, primary blowing, turning down and deslagging, secondary feeding, secondary blowing, and terminal control and steel tapping, all final slag is reserved for slag splashing after steel tapping, and the steps are repeated circularly. The obtained final slag comprises, 35-48% of CaO, 8-14% of MgO, 8-13% of SiO2, 10.20-18.50% of TFe, and 2.50-5.60% of P2O5, and the alkalinity is 2.5-6. By the adoption of the slagging and dephosphorizing technique, smelting of the high-phosphorus molten iron is integrally optimized; materials, such as high-cost slagging agents, magnesite pellets and light-burned magnesian limestone, are partially or completely replaced by low-cost and environment-friendly sintered and returned mines and raw magnesian limestone, and a corresponding technological system is set; and the extra heat is balanced while smooth dephosphorizing is guaranteed, the slag oxidation, the P2O5 content and the final slag MgO content are improved, the slagging cost is reduced by over 8 yuan / t while a furnace lining is protected and the dephosphorizing effect is achieved, the furnace age is prolonged from 12000 times to 15000 times, and the application value and popularization value are high.

Description

technical field [0001] The invention belongs to the technical field of converter smelting slag making and dephosphorization, and particularly relates to a low-cost slagging and dephosphorization process for converter smelting high-phosphorus molten iron. Background technique [0002] Wuhan Iron and Steel Group Kunming Iron and Steel Co., Ltd. uses self-produced cheap high-phosphorus ore to make iron. The phosphorus content of high-phosphorus hot metal produced is as high as 0.35 to 0.80%, with an average of 0.62%. It has been at the leading level of industrialized mass production at home and abroad. The intensification of homogenization competition and the need for enterprises to survive require continuous reduction of the cost of slag-making and dephosphorization. The present invention investigates and analyzes the traditional slagging process of converter smelting, and finds that the traditional slagging process has the following problems: [0003] (1) Due to the short ta...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C21C5/30C21C5/36C21C7/064
CPCC21C5/30C21C5/36C21C7/064Y02P10/20
Inventor 杨春雷赵宇张卫强陆大章王卫东陈伟李金柱岳伟文玉兵张红斌张瑜张志波曹阳
Owner WUKUN STEEL
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