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Method and Catalyst for Resin Hydrogenation

A catalyst, nickel catalyst technology, applied in physical/chemical process catalysts, catalyst protection, metal/metal oxide/metal hydroxide catalysts, etc., can solve problems such as hydrogenation of hydrocarbon resins that are not mentioned

Active Publication Date: 2018-05-18
BASF CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Hydrogenation of hydrocarbon resins is not mentioned in this document

Method used

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  • Method and Catalyst for Resin Hydrogenation
  • Method and Catalyst for Resin Hydrogenation

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] Embodiment 1 (comparison)

[0039] According to WO-A-01 / 36093, the nickel catalyst is prepared by mixing various solutions of salts, silicates, and sodium carbonate containing nickel, iron, and aluminum oxide at a temperature of 95 ° C in a fully stirred Mix in the settling vessel. The resulting slurry had a pH of approximately 7.5 and precipitation was complete after 1 hour. After washing the precipitate, the catalyst precursor was filtered and dried in an oven at 110°C. The catalyst is activated with hydrogen and passivated in the presence of air. The composition and physical properties of the obtained catalysts are listed in Table 1.

Embodiment 2

[0040] Embodiment 2 (comparison)

[0041] The various solutions containing salts of nickel and alumina, silicates, and sodium carbonate were mixed in a well-stirred settling vessel at a temperature of 95°C. The resulting slurry had a pH of approximately 7.5 and precipitation was complete after 1 hour. After washing the precipitate, the catalyst precursor was filtered and dried in an oven at 110°C. The catalyst is activated with hydrogen and passivated in the presence of air. The composition and physical properties of the obtained catalysts are listed in Table 1.

Embodiment 3

[0043] Various solutions containing salts such as nickel, cobalt, and alumina, silicate, and sodium carbonate were mixed in a well-stirred settling vessel at a temperature of 95°C. The resulting slurry had a pH of approximately 7.5 and precipitation was complete after 1 hour. After washing the precipitate, the catalyst precursor was filtered and dried in an oven at 110°C. The catalyst is activated with hydrogen and passivated in the presence of air. The resulting material contains 64wt.% Ni, 25wt.% SiO 2 , 2wt.%Al 2 o 3 and 0.3wt.% Co. Other physical properties of the resulting catalyst are listed in Table 1.

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Abstract

The invention belongs to the field of catalysts. In particular, the invention relates to catalytic hydrogenation processes and catalysts used therein. According to the present invention, there is provided a process for the hydrogenation of hydrocarbon resins, the catalyst itself, and a process for the preparation of the catalyst, in particular the use of cobalt-promoted nickel on silica / alumina catalysts with relatively high of sulfur content.

Description

technical field [0001] The present invention relates to the field of catalysts. In more detail, the present invention relates to catalytic hydrogenation methods and catalysts used in the methods. Background technique [0002] WO-A-01 / 36093 describes nickel-iron-silica-alumina catalysts for the hydrogenation of hydrocarbon resins. These and other known nickel hydrogenation catalysts have low activity in hydrocarbon resin feeds, especially when the amount of sulfur in the feed exceeds 100 ppm. Accordingly, there is a need to provide a catalyst and process which yields good catalyst activity for the hydrogenation of hydrocarbon resins having relatively high amounts of sulfur. [0003] It is therefore an object of the present invention to provide a catalyst and a process for the hydrogenation of hydrocarbon resins which achieve this advantage. Another object is to provide a process for the preparation of this catalyst. A further object of the present invention is to provide ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J37/03B01J23/755B01J23/78B01J23/80C10G49/04
CPCB01J37/03B01J23/755C10G45/06C10G45/00B01J2523/00B01J37/18B01J33/00C08F8/04C10G49/04B01J35/392B01J35/633B01J35/651B01J35/66B01J35/647B01J35/615B01J2523/31B01J2523/41B01J2523/845B01J2523/847B01J37/06B01J2523/842
Inventor 艾伯塔斯·詹考伯斯·桑迪约格什·钦塔达罗伯特·约翰·安德里亚·玛丽亚·泰罗勒杰
Owner BASF CORP