Fluorescent paint, and preparation method and application thereof
A fluorescent coating and fluorescent particle technology, applied in the field of fluorescent coatings, can solve the problems of deterioration of luminous effect, easy cracking of the coating, poor light resistance, weather resistance and chemical stability, etc. The effect of improving stability
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Embodiment 1
[0031] Example 1 Preparation of coated long-lasting phosphor
[0032] Add 500g of long-lasting fluorescent particles to 2000ml of NaOH solution with pH=12-13, stir for 10min, drain the supernatant, and wash three times in total. Adding mass percentage is 5-10% Ca(NO 3 ) 2 The solution was stirred for 10 min. Then add mass percent as 3-10% NaH 2 PO 4 Stir for 10 min. Ca(NO 3 ) 2 and NaH 2 PO 4 generate Ca 3 (PO 4 ) 2 , Ca 3 (PO 4 ) 2 Cover the outer surface of long-lasting fluorescent particles to form a calcium phosphate film. The solution after the complete reaction is dehydrated and dried at 110-140° C. for 10 hours to obtain the coated phosphor. The mesh of the coated fluorescent powder is 100-500 mesh, and the thickness of the calcium phosphate film layer is 5-20nm.
Embodiment 2
[0033] Example 2 Preparation of Fluorescent Paint
[0034] The mass percentage is 45%-80% epoxy resin, 2%-10% ethylene glycol, 0.5%-5% alkyl phosphate (CP-88), 2%-15% acrylic resin and 0.1 %-5% of silicon dioxide is mixed to make a solvent, and then 5%-50% of coated long-lasting phosphor powder prepared in Example 1 is added, mixed and stirred at room temperature for 0.5 hours to make a fluorescent paint.
Embodiment 3
[0035] Example 3 Preparation of coated long-lasting phosphor
[0036] Add 500g of long-lasting fluorescent particles to 2000ml of NaOH solution with pH=12-13, stir for 10min, drain the supernatant, and wash three times in total. Adding mass percentage is 5-10% CaCl 2 The solution was stirred for 10 min. Then add mass percent as 3-10% KH 2 PO 4 Stir for 10 min. CaCl 2 and KH 2 PO 4 generate Ca 3 (PO4) 2 , Ca 3 (PO 4 ) 2 Cover the outer surface of long-lasting fluorescent particles to form a calcium phosphate film. The solution after the complete reaction is dehydrated and dried at 110-140° C. for 10 hours to obtain the coated phosphor. The mesh of the coated fluorescent powder is 100-500 mesh, and the thickness of the calcium phosphate film layer is 5-20nm.
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