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Acid, solvent, and thermal resistant metal-organic frameworks

A metal-organic framework and solvent-resistance technology, applied in the fields of acid-resistance, solvent-resistance, and heat-resistance metal-organic frameworks, which can solve the problems of multiple applications and environments.

Active Publication Date: 2016-10-12
RGT UNIV OF CALIFORNIA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The MOFs of the present disclosure can be used in a variety of applications and environments that cannot be addressed by using conventional framework materials

Method used

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  • Acid, solvent, and thermal resistant metal-organic frameworks
  • Acid, solvent, and thermal resistant metal-organic frameworks
  • Acid, solvent, and thermal resistant metal-organic frameworks

Examples

Experimental program
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Embodiment

[0302] Materials: Formic acid (>98% purity) was obtained from Aldrich Chemical Co. or from EMD Millipore Chemicals. N,N-dimethylformamide (DMF) and anhydrous methanol were obtained from EMD Millipore Chemicals; anhydrous acetone was obtained from Acros Organics; zirconium oxychloride octahydrate (ZrOCl 2 ·8H 2 O, purity ≥ 99.5%) and Siliconizing reagents were obtained from Sigma-Aldrich Co. Fumaric acid, 2,5-dihydroxy-1,4-phthalic acid [H 2 BDC-(OH) 2 ], 3,3′-dihydroxy-4,4′-biphenyldicarboxylic acid [H 2 BPDC-(OH) 2 ], thiophene-2,5-dicarboxylic acid (H 2 TDC), 1H-pyrazole-3,5-dicarboxylic acid (H 2 PZDC), hafnium tetrachloride (HfCl 4 ), acetic acid, and N,N-dimethylformamide (DEF) were purchased from Aldrich Chemical Company and obtained from Aldrich Corporation. 1,3,5-Benzenetricarboxylic acid (H 3 BTC) were obtained from Aldrich Chemical Company or from EMD Millipore Chemical Company. 1,5-Dihydroxynaphthalene-2,6-dicarboxylic acid [H 2 NDC-(OH) 2 ] was purcha...

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Abstract

The disclosure provides for thermal, solvent, and / or acid resistant metal organic frameworks and the use of these frameworks in devices and methods for gas separation, gas storage, and catalysis. The disclosure further provides for MOFs that are strong solid acids, and the use of these strong solid acid MOFs in catalytic devices and catalytic methods.

Description

[0001] Cross References to Related Applications [0002] This application claims priority under 35 USC § 119 to Provisional Application Serial No. 61 / 941,791 filed February 19, 2014, the disclosure of which is incorporated herein by reference. [0003] Statement Regarding Federally Funded Research [0004] This invention was made with government support under Grant Nos. DE-AC02-05CH11231 and DE-SC000105 awarded by the U.S. Department of Energy. The US Government has certain rights in this invention. technical field [0005] The present disclosure provides acid-resistant, solvent-resistant, and / or heat-resistant metal-organic frameworks (MOFs), including solid acid MOFs (sa-MOFs); and uses of said MOFs for gas adsorption, gas separation, and catalysis . Background technique [0006] Metal-organic frameworks (MOFs) are porous crystalline materials built by linking metal clusters called secondary binding units (SBUs) and organic linking moieties. MOFs have high surface area...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07F7/00B01D33/00B01J31/00
CPCB01D33/00C07F7/003B01J20/226B01J20/3085B01J31/1691B01D2253/204B01J2531/46B01J2531/48B01J2531/49B01J31/00B01D53/047B01D53/228B01J37/04
Inventor 奥马尔·M·雅琪李承奎蒋骏骢章跃标
Owner RGT UNIV OF CALIFORNIA
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