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Low-phosphorous pre-film former used for industrial circulating cooling water system pipeline and heat exchanger

A technology of circulating cooling water and heat exchangers, applied in the coating process of metal materials, etc., can solve the problems of poor prevention of electrochemical corrosion and under-deposit corrosion, inability to effectively remove rust and scale, and shorten the service life of equipment , to achieve the effect of good operating conditions, good pre-film effect, and guaranteed use effect

Inactive Publication Date: 2016-11-23
仙桃市信达化工有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The object of the present invention is to provide a low-phosphorus pre-film agent for industrial circulating cooling water system pipelines and heat exchangers, to solve the long film-forming time proposed in the above-mentioned background technology, and its operating conditions are relatively poor, which cannot be effectively removed. Residual rust and scale have a poor effect on preventing electrochemical corrosion and under-deposit corrosion, reducing the service life of equipment

Method used

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  • Low-phosphorous pre-film former used for industrial circulating cooling water system pipeline and heat exchanger
  • Low-phosphorous pre-film former used for industrial circulating cooling water system pipeline and heat exchanger

Examples

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Embodiment 1

[0012] A low-phosphorus pre-coating agent for industrial circulating cooling water system pipelines and heat exchangers, comprising the following raw materials in proportions by weight: 10 parts of 2-phosphonic acid butane-1,2,4-tricarboxylic acid, hydroxyl 6 parts of phosphonoacetic acid, 8 parts of acrylic acid-hydroxypropyl acrylate-AMPS terpolymer, 6 parts of hydrolyzed polymaleic anhydride, 13 parts of zinc sulfate heptahydrate, 2 parts of methyl benzotriazole and 0.5 parts of sodium gluconate Parts, hydrolyzed polymaleic anhydride is a low molecular weight polyelectrolyte, generally with a relative molecular weight of 400-800, non-toxic, easily soluble in water, high chemical and thermal stability, and the decomposition temperature is above 330 °C.

[0013] A low-phosphorus pre-film agent for industrial circulating cooling water system pipelines and heat exchangers, comprising the following steps: sequentially adding 10 parts of 2-phosphonic acid butane-1,2,4-tricarboxyli...

Embodiment 2

[0015] A low-phosphorus pre-coating agent for industrial circulating cooling water system pipelines and heat exchangers, comprising the following raw materials in proportions by weight: 10 parts of 2-phosphonic acid butane-1,2,4-tricarboxylic acid, hydroxyl 8 parts of phosphonoacetic acid, 8 parts of acrylic acid-hydroxypropyl acrylate-AMPS terpolymer, 8 parts of hydrolyzed polymaleic anhydride, 14 parts of zinc sulfate heptahydrate, 2 parts of methyl benzotriazole and 1 part of sodium gluconate Parts, hydrolyzed polymaleic anhydride is a low molecular weight polyelectrolyte, generally with a relative molecular weight of 400-800, non-toxic, easily soluble in water, high chemical and thermal stability, and the decomposition temperature is above 330 °C.

[0016] A low-phosphorus pre-film agent for industrial circulating cooling water system pipelines and heat exchangers, comprising the following steps: sequentially adding 10 parts of 2-phosphonic acid butane-1,2,4-tricarboxylic a...

Embodiment 3

[0018] A low-phosphorus pre-coating agent for industrial circulating cooling water system pipelines and heat exchangers, comprising the following raw materials in proportions by weight: 8 parts of 2-phosphonic acid butane-1,2,4-tricarboxylic acid, hydroxyl 6 parts of phosphonoacetic acid, 6 parts of acrylic acid-hydroxypropyl acrylate-AMPS terpolymer, 6 parts of hydrolyzed polymaleic anhydride, 13 parts of zinc sulfate heptahydrate, 1 part of methyl benzotriazole and 0.5 parts of sodium gluconate Parts, hydrolyzed polymaleic anhydride is a low molecular weight polyelectrolyte, generally with a relative molecular weight of 400-800, non-toxic, easily soluble in water, high chemical and thermal stability, and the decomposition temperature is above 330 °C.

[0019] A low-phosphorus pre-filming agent for industrial circulating cooling water system pipelines and heat exchangers, comprising the following steps: sequentially adding 8 parts of 2-phosphonic acid butane-1,2,4-tricarboxyli...

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Abstract

The invention discloses a low-phosphorous pre-film former used for an industrial circulating cooling water system pipeline and a heat exchanger. The low-phosphorous pre-film former is prepared from the following raw materials in parts by weight: 8 to 10 parts of 2-phosphono butane-1,2,4-tricarboxylic acid, 6 to 8 parts of hydroxyphosphonoacetic acid, 6 to 8 parts of acrylic acid-hydroxy-propyl acrylate-AMPS terpolymers, 6 to 8 parts of hydrolytic polymaleic anhydride, 13 to 14 parts of heptahydrate, 1 to 2 parts of tolytriazole and 0.5 to 1 part of sodium gluconate. According to the low-phosphorous pre-film former used for the industrial circulating cooling water system pipeline and the heat exchanger, due to the cooperation of the 2-phosphono butane-1,2,4-tricarboxylic acid, the hydroxyphosphonoacetic acid and the acrylic acid-hydroxy-propyl acrylate-AMPS terpolymers, the time of film forming is greatly shortened; the operation conditions are better; residual rust deposits and water scales can be effectively removed; the low-phosphorous pre-film former is better in effect on prevention of electrochemical corrosion and under-deposit corrosion, and the service life of equipment is prolonged; and furthermore, the compounding of the various components cannot generate greater counteraction, so that the normal use effect is guaranteed.

Description

technical field [0001] The invention relates to the technical field of pre-filming agents, in particular to a low-phosphorus pre-filming agent for industrial circulating cooling water system pipelines and heat exchangers. Background technique [0002] Pre-film agents are often used in industrial circulating cooling water system pipelines and heat exchangers. Pre-film agents are a class of chemicals that can pre-form a protective film on metal surfaces during the pretreatment process of water treatment. However, the existing low-phosphorus pre-coating agents used for industrial circulating cooling water system pipelines and heat exchangers have an antagonistic effect due to improper compounding of various components, resulting in reduced or lost effects from time to time. The dosage is increasing so that the cost increases significantly, and the film forming time is longer, the operating conditions are poor, and the residual rust and scale cannot be effectively removed, which...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C22/48
CPCC23C22/48
Inventor 张正亮潘浩张旭鸿谢远枝
Owner 仙桃市信达化工有限责任公司
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