A metal-modified composite molecular sieve, its preparation method and its application in the reaction of methanol conversion to propylene and butene

A composite molecular sieve and metal modification technology, applied in molecular sieve catalysts, chemical instruments and methods, and hydrocarbon production from oxygen-containing organic compounds, can solve the problem of reducing the selectivity of propylene
CN106179481BActive Publication Date: 2018-12-11CHNA ENERGY INVESTMENT CORP LTD +1

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
CHNA ENERGY INVESTMENT CORP LTD
Publication Date
2018-12-11

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Abstract

The invention discloses a metal-modified SAPO-5 / SAPO-34 composite molecular sieve, particularly, metal-modified lanthanide series metal isomorphous substitution. The invention further discloses a preparation method of the metal-modified SAPO-5 / SAPO-34 composite molecular sieve. When the metal-modified SAPO-5 / SAPO-34 composite molecular sieve is used for a reaction of preparing low carbon olefins by using organic oxygen-containing compounds, the composite molecular sieve has favorable catalytic activity, excellent propylene and butene selectivity and long service life.
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Description

technical field

[0001] The invention relates to a metal-modified SAPO-5 / SAPO-34 composite molecular sieve and a preparation method thereof. The metal-modified composite molecular sieve is used for preparing low-carbon olefins from organic oxygen-containing compounds to increase the yield of propylene and butene. Background technique

[0002] With the shortage of petroleum resources and rising prices, the production of ethylene and propylene is light, and C 4 Resources are increasingly scarce.

[0003] The traditional methanol-to-olefins process (MTO) mainly uses ethylene and / or propylene as the target products, butene and C 5 + Components above hydrocarbons are only by-products, where C 4 The yield of mixed hydrocarbons is about 5.5%, the C 4 Among the mixed hydrocarbons, the content of 1,3-butadiene and isobutene is relatively low, and the main components are butene-1 and butene-2, which account for about 90%. (See "Market Demand and Processing Technology Analysis of C...

Claims

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