Unlock instant, AI-driven research and patent intelligence for your innovation.

Method for preparing building materials by utilizing industrial by-product gypsum

A technology of industrial by-product gypsum and building materials, which is applied in the field of comprehensive utilization of industrial by-product gypsum and aluminosilicate industrial waste to manufacture building materials. It can solve the problems of low strength and poor durability, achieve high strength and overcome fatal Defects, the effect of simple production process

Active Publication Date: 2019-11-05
ZHONGBEI UNIV
View PDF5 Cites 2 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] The technical problem to be solved by the present invention is to provide a method for preparing building materials using industrial by-product gypsum, at least overcoming the shortcomings of low strength and poor durability of existing gypsum products

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Method for preparing building materials by utilizing industrial by-product gypsum
  • Method for preparing building materials by utilizing industrial by-product gypsum
  • Method for preparing building materials by utilizing industrial by-product gypsum

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0044] The specific surface area will be 600 m 2 / kg fluorine gypsum 400g (40%), specific surface area 600 m 2 / kg slag 300g (30%), specific surface area 780 m 2 / kgP·O42.5 50g (5%) of cement and 250g (25%) of river sand with a fineness modulus of 2.8 are dry mixed in a mixer for 3 minutes; then add 180g of water (18% of the dry mass of all solid materials) , an additional 1.5g of alkaline activator (accounting for 0.5% of the slag powder) was added to the water, and wet mixed for 10 minutes; after standing for 15 minutes, the pressure was maintained at 40MPa for 30s to obtain a super-strong material body; it was cured in a concrete curing room at room temperature and saturated water 28 days to get super high-strength material C 1 , after resting for 1 hour, curing in saturated steam at 100°C for 9 hours, the super-high-strength material C 2 , compressive strength see figure 2 .

Embodiment 2

[0046] Put 2500g of fluorogypsum and 2500g of phosphorus slag into a 500×500mm standard ball mill to grind for 50min to obtain a specific surface area of ​​650 m 2 / kg of mixture, take 620g of mixture (of which dry fluorine gypsum accounts for 31% of the total dry basis material, phosphorus slag accounts for 31% of the total dry basis material), and the specific surface area is 480 m 2 / kg P·O4 2.5 cement 80g (accounting for 8% of the total dry basis material) and 300g of river sand with a fineness modulus of 2.8 (accounting for 30% of the total dry basis material) are dry mixed in the mixer for 4min; then add 180g of water (plus the water brought in by gypsum accounts for 18% of the total dry material), add an additional 1.8g of alkaline activator (accounting for 0.6% of the CFB powder) in the water, wet mix for 8 minutes; after standing for 30 minutes, under 45MPa Hold the pressure for 15s to obtain a super-strength material green body; in the laboratory (temperature 20°C-31...

Embodiment 3

[0048] Put 2800g of fluorogypsum and 2200g of water-quenched slag into a 500×500mm standard ball mill to grind for 65min to obtain a specific surface area of ​​580 m 2 / kg of mixture, take 670g of mixture (of which fluorine gypsum accounts for 37.5% of the total dry basis material, water quenching slag accounts for 29.5% of the total dry basis material), and the specific surface area is 600 m 2 / kg P·O4 2.5 cement 90g (accounting for 9% of the total dry basis material) and 240g of machine-made sand with a fineness modulus of 3.2 (accounting for 24% of the total dry basis material) are dry mixed in the mixer for 3min; then add 200g of water (plus the water brought in by gypsum accounted for 20% of the total dry-based material), an additional 1.4g of alkaline activator (accounting for 0.47% of the water-quenched slag powder) was added to the water, and wet mixed for 9 minutes; after standing for 30 minutes, the Hold the pressure at 45MPa for 50s to produce a super-strength mater...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
particle diameteraaaaaaaaaa
specific surface areaaaaaaaaaaa
compressive strengthaaaaaaaaaa
Login to View More

Abstract

The invention relates to a method for preparing a building material by use of industrial byproduct gypsum. Firstly, a dry mixture is prepared from industrial gypsum, aluminosilicate industrial waste residues, calcium cementing materials and aggregate, water or water with an activator dissolved in is added, a wet mixture is prepared, left to stand and subjected to static pressure forming, and finally, an ultrahigh-strength material is prepared through natural or steam curing. The problems that the industrial byproduct gypsum is low in strength, poor in durability and difficult to utilize and contains many impurities are solved, the industrial byproduct gypsum is coupled with a large quantity of the aluminosilicate industrial waste residues, and the ultrahigh-strength building material is prepared. The ultrahigh-strength material can be used for preparing high-strength building bricks, high-strength road bricks, high-strength water-permeable bricks, paving stone, various decorative boards and other products with a changing molding mold method.

Description

technical field [0001] The invention relates to a new type of building material, in particular to a method for manufacturing building materials through the coupling of industrial by-product gypsum and aluminosilicate industrial waste slag. Background technique [0002] Fluorogypsum is a by-product in the production process of hydrofluoric acid. The waste residue mainly containing calcium sulfate produced by the reaction of sulfuric acid and fluorite is mainly produced in inorganic fluoride and organic fluoride production plants and other hydrofluoric acid production plants. The output is quite considerable. Every 1t of hydrofluoric acid produces more than 4 tons of fluorogypsum. The amount of fluorogypsum discharged from fluoride salt factories in my country reaches more than 1 million tons every year. Fluorogypsum contains residual fluorite and sulfuric acid when it is just out of the device, and the content of fluorine and sulfuric acid is relatively high, both of which exc...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): C04B28/00
CPCC04B28/00C04B2201/50C04B22/146C04B18/141C04B14/068C04B18/04
Inventor 靳秀芝韩涛王慧奇连坤钟军超渠永平
Owner ZHONGBEI UNIV