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Axial radial micro-catalysis reaction unit and its application

A catalytic reaction, axial radial technology, applied in chemical instruments and methods, chemical/physical processes, chemical/physical/physical chemical processes, etc., can solve problems such as large height and diameter, short residence time, local overheating, etc., to achieve Reduce production costs, prolong service life, and ensure smooth operation

Active Publication Date: 2019-01-11
SINOPEC ENG +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Axial reactor design, relatively easy processing, and simple operation, but there are problems with large reactor equipment, large bed pressure drop, prone to local overheating, slow heat transfer, low conversion rate, obvious amplification effect, and the need for materials for the reactor. higher grade questions
The radial bed reactor has a large height-to-diameter ratio, a small bed pressure drop, and a short residence time of the reactants in the catalyst bed, but it is difficult to achieve uniform distribution of the reactants in the radial direction, and the production intensity of the unit catalyst bed is low
[0003] In order to overcome the problems of low heat transfer and mass transfer efficiency in traditional chemical industry, microchemical technology emerged in the 1980s and 1990s.

Method used

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  • Axial radial micro-catalysis reaction unit and its application
  • Axial radial micro-catalysis reaction unit and its application
  • Axial radial micro-catalysis reaction unit and its application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0056] Such as figure 1 As shown, the axial radial micro-catalytic reaction unit adopted in this embodiment includes a central cylinder 1 and a sleeve 2 composed of a top sealing plate, a bottom sealing plate and side surfaces, and the central cylinder 1 is a cylinder. The upper and lower sides of the central cylinder 1 are in fluid communication through the axial micro-reaction channel 5 , and the inside and outside of the sleeve 2 are in fluid communication through the radial micro-reaction channel 6 . Such as Figure 9 As shown, the axial micro-reaction channel 5 and the radial micro-reaction channel 6 of the tapered tube structure, the tube wall is coated with methanation active components, and the two ends are respectively sealed with the top sealing plate and the bottom sealing plate of the central cylinder 1 The connection and the two ends are hermetically connected to the side of the sleeve 2 respectively.

[0057] The axial and radial micro-catalytic reaction unit h...

Embodiment 2

[0060] Such as figure 2 As shown, the difference between embodiment 2 and embodiment 1 is that the length of the micro-reaction channel in the axial direction of the tapered tube used is 120 mm, the diameter of the tapered tube inlet is 4 mm, and the diameter of the outlet is 10 mm. The length of the micro-reaction channel is 50 mm, the diameter of the inlet of the conical tube is 4 mm, and the diameter of the outlet is 6 mm. This type of reactor is suitable for chemical reactions with increased reaction volume, such as cyclohexane dehydrogenation, ethylbenzene dehydrogenation, and ammonia decomposition reactions.

[0061] The axial micro-catalytic reaction unit is used for cyclohexane dehydrogenation reaction. The dehydrogenation reaction of cyclohexane is an endothermic reaction with volume increase. Cyclohexane enters the conical tube coated with platinum metal on the inner surface evenly from the side and top open end of the conical tube, and dehydrogenation occurs on th...

Embodiment 3

[0063] Such as Figure 7 and Figure 8 As shown, the number of integrated axial radial micro-catalysis reaction units used in Example 3 is 18, arranged in a 3×2×3 cuboid, the central column 1 is a quadrangular prism, and the upper and lower adjacent axial radial micro-catalysis The side of the reaction unit is sealed, and the bottom sealing plate of the lowest catalytic micro-reaction unit is sealed and connected.

[0064] The conical tube micro-reaction channel in the integrated module is coated with Ni-based active metal components, and the module can be used for methanation reaction. The synthesis gas enters between the axial and radial micro-catalysis reaction units from the upper feed port, and the synthesis gas evenly enters each radial micro-catalysis reaction channel and passes through the uppermost axial micro-catalysis reaction channel, on the Ni-based active metal surface The methanation reaction occurs, and the reaction product enters the gap between the axial an...

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Abstract

The invention discloses an axial-radial micro-catalytic reaction unit and application thereof. The axial-radial micro-catalytic reaction unit contains a central column and a sleeve which coaxially sleeves the central column. The central column has axial micro-reaction channels which axially pass through the central column. Radial micro-reaction channels which pass through the sleeve are arranged in the radial direction of the sleeve. The axial-radial micro-catalytic reaction unit provided by the invention can be used for a reaction with reaction volume changing. In addition, use amount of a catalyst is small; pressure drop is low; retention time is short; utility rate of space is high; and there is no gas bias current or short circuit phenomenon.

Description

technical field [0001] The invention relates to an axial radial micro-catalysis reaction unit and its application. Background technique [0002] At present, there are mainly two types of fixed bed reactors, one is axial fixed bed reactor, and the other is radial fixed bed reactor. Axial reactor design, relatively easy processing, and simple operation, but there are problems with large reactor equipment, large bed pressure drop, prone to local overheating, slow heat transfer, low conversion rate, obvious amplification effect, and the need for materials for the reactor. high-level issues. The radial bed reactor has a large height-to-diameter ratio, a small bed pressure drop, and a short residence time of the reactants in the catalyst bed, but it is difficult to achieve uniform distribution of the reactants in the radial direction, and the production intensity of the unit catalyst bed is low. [0003] In order to overcome the problems of low heat transfer and mass transfer ef...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J19/00
Inventor 张旭戴文松王子宗蒋荣兴
Owner SINOPEC ENG
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