Method for preparing cellulosic fibers from straws
A cellulose fiber and cellulose technology, which is applied in the field of cellulose fiber preparation from straw, can solve the problems of cellulose destruction and unfavorable spinning, and achieve the effect of avoiding damage
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Embodiment 1
[0036] Embodiment 1: a method for preparing cellulose fibers from straws, comprising the steps of:
[0037] 1) Cut the straw into 1-2 mm wide straw strips with a rolling cutter;
[0038] 2) Put the strips of straw in step 1) into a pool and soak them in hydrogen peroxide for bleaching, and at the same time make the strips of straw fully absorb water to become wet straws;
[0039] 3) Freeze the wet straw in step 2) with an ultra-low temperature freezer, then put it into an ultrasonic oscillator and vibrate and pulverize it into straw powder, sieve the straw powder, and sieve out the straw that is not fully broken and repeat freezing, shaking, and sieving;
[0040] 4) Put the straw powder obtained in step 3) into the reaction kettle, soak in warm water at 40°C for 2 hours according to the mass ratio of solid-to-liquid ratio of 1:3, then extract the water and re-inject it into hot water at 60°C for 30 minutes;
[0041] 5) Add acetic acid to the reaction kettle in step 4) to adju...
Embodiment 2
[0049] Embodiment 2: a method for preparing cellulose fibers from straws, comprising the steps of:
[0050] 1) Cut the straw into 1-2 mm wide straw strips with a rolling cutter;
[0051] 2) Put the strips of straw in step 1) into a pool and soak them in hydrogen peroxide for bleaching, and at the same time make the strips of straw fully absorb water to become wet straws;
[0052] 3) Freeze the wet straw in step 2) with an ultra-low temperature freezer, then put it into an ultrasonic oscillator and vibrate and pulverize it into straw powder, sieve the straw powder, and sieve out the straw that is not fully broken and repeat freezing, shaking, and sieving;
[0053] 4) Put the straw powder obtained in step 3) into the reactor, soak in warm water at 50°C for 1.5 hours according to the solid-to-liquid ratio of 1:4, then extract the water and re-inject it into hot water at 65°C for 20 minutes;
[0054]5) Add acetic acid to the reaction kettle in step 4) to adjust the pH value betwe...
Embodiment 3
[0062] Embodiment three: a method for preparing cellulose fiber from straw, comprising the following steps:
[0063] 1) Cut the straw into 1-2 mm wide straw strips with a rolling cutter;
[0064] 2) Put the strips of straw in step 1) into a pool and soak them in hydrogen peroxide for bleaching, and at the same time make the strips of straw fully absorb water to become wet straws;
[0065] 3) Freeze the wet straw in step 2) with an ultra-low temperature freezer, then put it into an ultrasonic oscillator and vibrate and pulverize it into straw powder, sieve the straw powder, and sieve out the straw that is not fully broken and repeat freezing, shaking, and sieving;
[0066] 4) Put the straw powder obtained in step 3) into the reaction kettle, soak in warm water at 60°C for 1 hour according to the solid-to-liquid ratio of 1:5, then extract the water and re-inject it into hot water at 70°C for 15 minutes;
[0067] 5) Add acetic acid to the reaction kettle in step 4) to adjust the...
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