Composite fully-degradable material and preparation method thereof

A technology for fully degradable and degradable plastics, applied in the field of composite fully degradable materials and their preparation, can solve the problems of soil structure damage, not effectively solved, hindering productivity, etc., to eliminate different degradation rates, improve practicability, and reduce entanglement. Effect

Inactive Publication Date: 2017-06-30
LANZHOU XINYINHUAN RUBBER & PLASTIC PROD CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, among the currently commercially available mulch films, single-layer mulch films are the main ones, and the degradation rates of different parts of the mulch films are different. Some of the mulch films have reached the end of degradation, and the mulch films become brittle; Any degradation occurs; resulting in a large number of plastic film fragments remaining in the farmland. These plastic film fragments are not easy to be degraded by soil microorganisms, and they remain in the farmland for

Method used

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  • Composite fully-degradable material and preparation method thereof
  • Composite fully-degradable material and preparation method thereof
  • Composite fully-degradable material and preparation method thereof

Examples

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Embodiment 1

[0039] The present invention provides a composite fully degradable material, the composite fully degradable material adopts a double-layer film structure, including a first layer of film and a second layer of film; wherein, the raw material components of the first layer of film, in parts by weight, include 0.01 part by weight of iron stearate, 0.1 part by weight of barium stearate, 0.05 part by weight of 2,6-di-tert-butyl-p-cresol, 9 parts by weight of low density polyethylene LD662 and 90.74 parts by weight of linear low density polyethylene 7042; The raw material components of the second film, in parts by weight, include: 30 parts by weight of PBAT with a number-average molecular weight of 8000, 10 parts by weight of PLA 6201D, 2 parts by weight of triacetin, 0.05 part by weight of iron stearate, iron oxide 0.05 parts by weight, 5 parts by weight of low density polyethylene LD662 and 62.9 parts by weight of linear low density polyethylene 7042.

[0040] According to the abov...

Embodiment 2

[0045] The present invention provides a composite fully degradable material, the composite fully degradable material adopts a double-layer film structure, including a first layer of film and a second layer of film; wherein, the raw material components of the first layer of film, in parts by weight, include 0.05 part by weight of manganese stearate, 0.2 part by weight of magnesium stearate, 0.2 part by weight of 4,4-isopropylidene bis(phenol salicylate), 0.1 part by weight of 2,4,6-tri-tert-butylphenol , 6 parts by weight of low density polyethylene 2012TN26, 20 parts by weight of linear low density polyethylene 9020 and 73.45 parts by weight of linear low density polyethylene 7042T; the raw material components of the second layer film are calculated in parts by weight, including: the number average molecular weight is 30000 parts by weight of PBAT 40 parts by weight, PLA 4032D 10 parts by weight, 2 parts by weight of triacetin, 0.15 parts by weight of manganese stearate, 0.05 p...

Embodiment 3

[0051] The present invention provides a composite fully degradable material, the composite fully degradable material adopts a double-layer film structure, including a first layer of film and a second layer of film; wherein, the raw material components of the first layer of film, in parts by weight, include 0.1 part by weight of titanium dioxide, 0.3 part by weight of calcium stearate, 0.3 part by weight of p-tert-butylphenyl salicylate, 0.15 part by weight of 4-hydroxymethyl-2,6-di-tert-butylphenol, low density polyethylene 2426H 10 parts by weight, 79.15 parts by weight of linear low-density polyethylene 218W, and 10 parts by weight of linear low-density polyethylene 222; the raw material components of the second layer film, in parts by weight, include: 50 parts by weight of PBAT with a number average molecular weight of 20,000, PLA 15 parts by weight of 6201D, 3 parts by weight of triacetin, 0.1 part by weight of titanium dioxide, 0.1 part by weight of n-octyl ferrocene, 5 pa...

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Abstract

The invention relates to a composite fully-degradable material and a preparation method thereof. The composite fully-degradable material has a double-layer film structure and comprises a first layer film and a second layer film, wherein the degradation time of the first layer film is longer than the degradation time of the second layer film, the raw materials of the first layer film comprise a degradation agent, a heat stabilizer, a light stabilizer, an antioxidant, low density polyethylene and linear low density polyethylene, and the raw materials of the second layer film comprise polyadipic acid/butylene terephthalate and polylactic acid. According to the present invention, the composite fully-degradable material uses the double-layer structure, and various layers are prepared from the materials having different degradation characteristics and have different degradation rates, such that various parts can simultaneously achieve the degradation ending points during the actual use process of the prepared mulch film so as to significantly improve the practicality of degradation mulch film, reduce the influence of the residual film on the next crops, save the labor cost, and promote the development of agricultural productivity.

Description

technical field [0001] The invention relates to the technical field of mulch films, in particular to a composite fully degradable material and a preparation method thereof. Background technique [0002] The application of plastic film mulching technology has greatly promoted the improvement of agricultural output and efficiency, and has contributed to the transformation of agricultural production methods and the leap in agricultural productivity. However, with the increase in the coverage area of ​​plastic film, the traditional plastic film cannot be degraded, and it is difficult to recycle, and the problem of residual film pollution is becoming more and more serious. In order to reduce and eliminate white pollution, various degradable plastic films have been developed. However, among the currently available mulch films, single-layer mulch films are the main ones, and the degradation rates of different parts of the mulch film are different. Some mulch films have reached the...

Claims

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Application Information

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IPC IPC(8): C08L23/08C08L23/06C08K5/098C08K5/13C08L67/02C08L67/04C08K5/103C08K3/22A01G13/02B32B27/08B32B27/32B32B27/36
CPCC08L23/0815A01G13/0275B32B27/08B32B27/32B32B27/36C08K2201/014C08L67/02C08L2201/06C08L2203/16C08L2205/02C08L2205/025C08L2205/03C08L2205/035C08L2207/066C08L23/06C08K5/098C08K5/13C08L67/04C08K5/103C08K2003/2265
Inventor 秦文生陆海荣秦体文
Owner LANZHOU XINYINHUAN RUBBER & PLASTIC PROD CO LTD
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