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Tea saponin modified electrolytic manganese residues and compound flooring tile prepared from tea saponin modified electrolytic manganese residues and waste plastics

A technology for electrolytic manganese slag and waste plastics, which is applied to buildings, building structures, floors, etc., can solve the problems of poor two-phase compatibility, high price, uneven dispersion, etc., and achieves increased filling and improved bonding. , the effect of increased strength

Inactive Publication Date: 2017-08-18
GUIZHOU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In addition, most of the floor tiles currently used for laying on the ground in public places and family houses are made of clay, porcelain clay, and stone. The production process is complicated and the price is high. There are still some defects in the degree of improvement, and a new material that uses waste, reduces pollution, and saves resources is urgently needed to solve the problem.
On the other hand, in the blending process of waste polyvinyl chloride plastics and electrolytic manganese slag, electrolytic manganese slag is a polar inorganic substance and is hydrophilic, while waste and old polyvinyl chloride plastic is a non-polar organic substance and is lipophilic. The shape and chemical structure are very different, so that there is a lack of chemical bonding between the two, resulting in uneven dispersion of inorganic fillers in the above-mentioned organic matter during two-phase blending, and poor compatibility between the two phases, thus affecting the performance of composite floor tiles

Method used

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  • Tea saponin modified electrolytic manganese residues and compound flooring tile prepared from tea saponin modified electrolytic manganese residues and waste plastics
  • Tea saponin modified electrolytic manganese residues and compound flooring tile prepared from tea saponin modified electrolytic manganese residues and waste plastics
  • Tea saponin modified electrolytic manganese residues and compound flooring tile prepared from tea saponin modified electrolytic manganese residues and waste plastics

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] Make tea saponin modified electrolytic manganese slag according to the following steps:

[0036] Add 93Kg electrolytic manganese slag and 2Kg NaOH into a high-speed mixer at 25°C, stir for 6-7 minutes, add 5Kg tea saponin at 65°C and heat and stir for 5-6 minutes to obtain tea saponin-modified electrolytic manganese slag.

[0037] Follow the steps below to make composite floor tiles:

[0038] a. After cleaning 200Kg of waste polyvinyl chloride plastic, dry it at 120°C for 1 hour, and then crush it to less than 4mm to obtain product A;

[0039] b. After mixing product A and 800Kg tea saponin modified electrolytic manganese slag with a high-speed mixer, product B is obtained;

[0040] c. Put product B on a three-roller mill and masticate it into a sheet at a temperature of 120-160°C and a thickness of 0.5-0.8mm, and then send it to a hot press for molding at a temperature of 150°C-160°C and a pressure of 3.5 MPa, the time is 4 to 5 minutes, and the C product is obtained...

Embodiment 2

[0064] Make tea saponin modified electrolytic manganese slag according to the following steps:

[0065] Add 92Kg of electrolytic manganese slag and 4Kg of NaOH into a high-speed mixer at 25°C, stir for 6-7 minutes, add 6Kg of tea saponin at 65°C, and heat and stir for 5-6 minutes to obtain tea saponin-modified electrolytic manganese slag.

[0066] Follow the steps below to make composite floor tiles:

[0067] a. After washing 250Kg of waste polyvinyl chloride plastic, dry it at 120°C for 1 hour, and then crush it to less than 4mm to obtain product A;

[0068] b. After mixing product A and 750Kg tea saponin modified electrolytic manganese slag with a high-speed mixer, product B is obtained;

[0069] c. Put product B on a three-roller mill and masticate it into a sheet at a temperature of 120-160°C and a thickness of 0.5-0.8mm, and then send it to a hot press for molding at a temperature of 150°C-160°C and a pressure of 3.5 MPa, the time is 4 to 5 minutes, and the C product is...

Embodiment 3

[0094] Make tea saponin modified electrolytic manganese slag according to the following steps:

[0095] Add 88Kg electrolytic manganese slag and 5Kg NaOH into a high-speed mixer at 25°C, stir for 6-7 minutes, add 7Kg tea saponin at 65°C, and heat and stir for 5-6 minutes to obtain tea saponin-modified electrolytic manganese slag.

[0096] Follow the steps below to make composite floor tiles:

[0097] a. After washing 300Kg of waste polyvinyl chloride plastic, dry it at 120°C for 1 hour, and then crush it to less than 4mm to obtain product A;

[0098] b. After mixing product A and 700Kg tea saponin modified electrolytic manganese slag with a high-speed mixer, product B is obtained;

[0099] c. Put product B on a three-roller mill and masticate it into a sheet at a temperature of 120-160°C and a thickness of 0.5-0.8mm, and then send it to a hot press for molding at a temperature of 150°C-160°C and a pressure of 3.5 MPa, the time is 4 to 5 minutes, and the C product is obtained...

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Abstract

The invention discloses tea saponin modified electrolytic manganese residues. The tea saponin modified electrolytic manganese residues are characterized by comprising 5wt%-7wt% of tea saponin, 2wt%-5wt% of NaOH and 88wt%-93wt% of electrolytic manganese residues. The tea saponin modified electrolytic manganese residues are prepared through the following steps: the electrolytic manganese residues and NaOH are added to a high-speed mixer at 25 DEG C and stirred for 6-7 min, tea saponin is added when the temperature reaches 65 DEG C, the mixture is heated and stirred for 5-6 min, and the tea saponin modified electrolytic manganese residues are obtained. A compound flooring tile prepared from the tea saponin modified electrolytic manganese residues and waste plastics is prepared from raw materials in parts by weight as follows: 20-30 parts of waste polyvinyl chloride plastics and 70-80 parts of the tea saponin modified electrolytic manganese residues through stirring, plastication into sheets, die pressing and cutting into sheets. The surface property of the modified electrolytic manganese residues is changed from hydrophilicity to lipophilicity by means of tea saponin, blending compatibility and binding performance of the modified electrolytic manganese residues with waste polyvinyl chloride are improved greatly, the performance of the compound flooring tile is improved greatly, filling parts of the electrolytic manganese residues in the compound flooring tile are increased, and product cost is reduced effectively.

Description

technical field [0001] The invention belongs to the field of building materials, and in particular relates to tea saponin modified electrolytic manganese slag used as waste polyvinyl chloride plastic filler and a composite floor tile made of waste polyvinyl chloride plastic. Background technique [0002] At present, the industrial waste electrolytic manganese slag discharged by my country's chemical industry is increasing year by year. These electrolytic manganese slags are not only used to produce electrolytic manganese slag bricks and cement, but also many ash storage yards are stacked in electrolytic manganese slag. land, but also cause serious environmental pollution. In addition, with the increasing production capacity and consumption of polyvinyl chloride plastics in my country, the output of plastic waste formed by discarded polyvinyl chloride plastics is increasing, causing serious "white pollution". In addition, the floor tiles currently used for laying the ground i...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L27/06C08K9/04C08K3/36E04F15/10
CPCC08K3/36C08K9/04E04F15/105C08L27/06
Inventor 张龙刘彤
Owner GUIZHOU UNIV
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