Carboxyl modified graphene oxide modified rubber asphalt mixture and preparation method thereof

A technology of asphalt mixture and carboxyl group modification, applied in the field of road engineering, can solve the problems of high viscosity of rubber asphalt, poor high temperature performance, reduced high temperature performance, etc., and achieve the effect of good adhesion

Active Publication Date: 2019-08-20
TONGJI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Due to the limitation of material selection and other factors, the rubber asphalt mixture prepared by the above method is still unsatisfactory in terms of adhesion and anti-rutting performance
The main reason for the lack of adhesion performance is that rubber asphalt has added more than 15% of rubber powder, which makes the asphalt too viscous, so it is difficult to coat the stone surface; the main reason for the poor anti-rutting performance is the adhesion of rubber asphalt and stone After the performance is reduced, the high temperature performance will be reduced. In addition, the asphalt content added to the rubber asphalt mixture is relatively high, which is about 50% higher than that of ordinary asphalt mixture. The mixture corresponding to the higher asphalt content has poor high temperature performance.
If general modifiers are added to rubber asphalt, it will lead to higher viscosity of rubber asphalt. Although there is a patent to add it by dry method, it will still increase the construction difficulty of rubber asphalt mixture.

Method used

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  • Carboxyl modified graphene oxide modified rubber asphalt mixture and preparation method thereof
  • Carboxyl modified graphene oxide modified rubber asphalt mixture and preparation method thereof
  • Carboxyl modified graphene oxide modified rubber asphalt mixture and preparation method thereof

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preparation example Construction

[0046] A kind of preparation method of above-mentioned carboxy-modified graphene oxide modified rubber asphalt mixture, it comprises the steps:

[0047] (1) Add 0.42-1.21 parts of tire rubber powder to 5.34-10.23 parts of road petroleum asphalt, and stir at the first temperature to obtain rubber asphalt;

[0048](2), heating 100 parts of mineral stones to the second temperature, then adding 1-2 parts of carboxyl-modified graphene oxide, and stirring to obtain a mixture;

[0049] (3) Add 6-11 parts of rubber asphalt to the mixture, and stir to obtain carboxyl-modified graphene oxide-modified rubber asphalt mixture.

[0050] In fact, rubber asphalt is component A, and its total mass is 100 parts, of which, the quality of tire rubber powder is 7-11 parts, and the quality of petroleum asphalt is 89-93 parts; mineral stone is component B, and its total mass For 100 parts, component A accounts for 6‐11% of component B.

[0051] Wherein, in step (1), tire rubber powder actually acc...

Embodiment 1

[0059] The preparation method of the carboxyl-modified graphene oxide modified rubber asphalt mixture of the present embodiment comprises the steps:

[0060] (1), 0.42 parts of tire rubber powder were added to 5.58 parts of 70# road petroleum asphalt, and at the first temperature of 180 ° C, stirred and reacted for 45 minutes to obtain rubber asphalt, wherein the mass percentage of tire rubber powder actually accounted for rubber asphalt was 7%, road petroleum asphalt actually accounts for 93% of the mass percentage of rubber asphalt;

[0061] (2), heating 100 parts of mineral stones to a second temperature of 160°C, then adding 1 part of carboxy-modified graphene oxide, and stirring to obtain a mixture;

[0062] (3), add 6 parts of above-mentioned rubber asphalt in above-mentioned mixture, stir to obtain carboxyl-modified graphene oxide modified rubber-asphalt mixture.

[0063] Among them, when the sieve size is 16.0mm, the sieve pass rate of the mineral stone is 100%.

[0...

Embodiment 2

[0073] The preparation method of the carboxyl-modified graphene oxide modified rubber asphalt mixture of the present embodiment comprises the steps:

[0074] (1) Add 1.1 parts of tire rubber powder to 8.9 parts of road petroleum asphalt, and at the first temperature of 200°C, stir and react for 45 minutes to obtain rubber asphalt, wherein the tire rubber powder actually accounts for 11% by mass of the rubber asphalt , road petroleum asphalt actually accounts for 89% of the mass percentage of rubber asphalt;

[0075] (2), heating 100 parts of mineral stones to a second temperature of 200°C, then adding 1.5 parts of carboxyl-modified graphene oxide, and stirring to obtain a mixture;

[0076] (3), add 10 parts of above-mentioned rubber asphalt in above-mentioned mixture, stir to obtain carboxyl-modified graphene oxide modified rubber-asphalt mixture.

[0077] Among them, when the sieve size is 16.0mm, the sieve pass rate of the mineral stone is 100%.

[0078] When the sieve siz...

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Abstract

The invention provides a carboxyl modified graphene oxide modified rubber asphalt mixed material and a preparation method thereof. The carboxyl modified graphene oxide modified rubber asphalt mixed material comprises 5.34-10.23 parts of pavement petroleum asphalt, 0.42-1.21 parts of tyre rubber powder, 100 parts of a mineral stone material and 1-2 parts of carboxyl modified graphene oxide. The preparation method comprises the following steps of: (1) adding 0.42-1.21 parts of tyre rubber powder into 5.34-10.23 parts of pavement petroleum asphalt and stirring the mixture at a first temperature to obtain rubber asphalt; (2) heating 100 parts of mineral stone material to a second temperature, then adding 1-2 parts of carboxyl modified graphene oxide and stirring to obtain a mixed material; and (3) adding 6-11 parts of rubber asphalt in the mixed material and stirring e to obtain a product. The asphalt mixed material is prepared by combining a dry method and a wet method, so that the obtained asphalt mixed material has the characteristics of good stickiness, storage stability, high-temperature rut resistance, construction stability and etc.

Description

technical field [0001] The invention belongs to the technical field of road engineering, and in particular relates to a carboxyl-modified graphene oxide-modified rubber-asphalt mixture and a preparation method thereof. Background technique [0002] Rubber asphalt refers to the modified asphalt cementing material obtained by the tire rubber powder content of more than 15%, under the conditions of high temperature and full mixing, and asphalt swelling reaction. Due to the use of recycled tires as the main material for modification, it has a cost advantage compared to styrene-butadiene block copolymer (SBS) modified asphalt. And there are still deficiencies in construction performance. [0003] In order to improve the overall performance of rubber asphalt, other modifiers can be added to rubber asphalt for modification. The existing technology of applying rubber powder to asphalt pavement is mainly divided into two categories: wet method and dry method. The wet method refers ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B26/26
Inventor 黄卫东林鹏李彦伟
Owner TONGJI UNIV
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