Method for making hydrophobic and oleophobic easy-to-clean glass

An oleophobic and glass-based technology, which is applied to biocide-containing paints, anti-fouling/underwater coatings, coatings, etc., can solve the problems of affecting the appearance of glass, fast curing of organic solvent volatilization film surface, and easy pitting.

Inactive Publication Date: 2017-09-01
浙江鼎昇新材料科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Compared with the three coating modification methods of spraying, wiping and scraping, wiping and scraping are more likely to produce rainbow phenomena, and spraying is more likely to cause pitting and affect the appearance of the glass, which is the main reason for this result. It is because the organic solvent volatilizes quickly, which leads to the fast curing of the film surface, which makes it impossible to carry out secondary coating. In the coating process, repeated coating will produce obvious defects.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] Take 1000 grams of AR ethanol and adjust the pH to 2.5 with hydrochloric acid to form an acidic ethanol solution. Under stirring conditions, add 210 grams of tetraethyl orthosilicate and 3 grams of tridecafluorooctyltriethoxysilane to the acidic ethanol solution. After stirring, add 200 grams of deionized water to the system to promote the hydrolysis of siloxane, let it stand and age for 48 hours, pour the resulting solution into 1500 grams of deionized water under vigorous stirring conditions, and stir to form a water-based hydrophobic and oleophobic Easy to clean paint.

[0025] Take 6mm flat glass, toughen and clean it, spray water-based hydrophobic and oil-repellent easy-clean coating under the conditions of spray gun speed of 50m / min, pressure of 0.3Mpa, and spraying flow rate of 40mL / min, and pre-condition at 120°C after spraying. After curing for 15 minutes, after curing at room temperature for 24 hours, clean the dust on the glass surface to obtain hydrophobic a...

Embodiment 2

[0027] Take 600 grams of AR ethanol and adjust the pH to 3 with hydrochloric acid to form an acidic ethanol solution. Under stirring conditions, add 12 grams of heptadecafluorodecyltriethoxysilane to the acidic ethanol solution, stir well and then add 100 grams of Deionized water is used to promote the hydrolysis of siloxane, and the resulting solution is poured into 1000 grams of deionized water under vigorous stirring conditions, and stirred to form a water-based hydrophobic and oil-repellent easy-to-clean coating.

[0028] Take 5 mm flat glass, use abrasive paste to grind and remove glass surface attachments, spray paint under the conditions of spray gun speed of 60m / min, pressure of 0.4Mpa, spray flow rate of 30ml / min, pre-cure at 100°C after spraying After 10 minutes and curing at room temperature for 24 hours, clean the dust on the glass surface to obtain hydrophobic and oil-repellent easy-to-clean glass. The film surface is black and has the effect of anti-reflection and...

Embodiment 3

[0030] Take 620 grams of AR ethanol and adjust the pH to 3 with nitric acid to form an acidic ethanol solution. Under stirring conditions, add 10 grams of tridecafluorooctyltriethoxysilane to the acidic ethanol solution, stir well and then add 100 grams to the system Deionized water is used to promote the hydrolysis of siloxane, and the resulting solution is poured into 1000 grams of deionized water under vigorous stirring conditions, and stirred to form a water-based hydrophobic and oil-repellent easy-to-clean coating.

[0031] Take 8 mm flat glass, use abrasive paste to grind and remove glass surface attachments, spray paint under the conditions of spray gun speed of 50m / min, pressure of 0.4Mpa, spray flow rate of 30ml / min, pre-cure at 100°C after spraying After 10 minutes and curing at room temperature for 24 hours, clean the dust on the glass surface to obtain hydrophobic and oil-repellent easy-to-clean glass. The hydrophobic film has no effect on the appearance of the glas...

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PUM

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Abstract

The invention belongs to the technical field of coated glass making, and in particular relates to a method for making hydrophobic and oleophobic easy-to-clean glass. The method comprises the following steps: mixing organosiloxane with absolute ethyl alcohol, adjusting the pH value of a solution, adding deionized water to promote hydrolysis, further adding fluorosilicone modified silicon dioxide, stirring to implement hydrolysis so as to form modified silica gel, leaving to stand, aging, and pouring the silica gel into deionized water which is violently stirred, thereby obtaining an aqueous hydrophobic and oleophobic easy-to-clean coating. The aqueous hydrophobic and oleophobic easy-to-clean coating prepared with the method is environmental-friendly since the amount of an organic solvent is reduced; when the surface of glass is coated by the prepared aqueous hydrophobic and oleophobic easy-to-clean coating, the solvent is slow in volatilization speed, so that the coating surface thickness uniformity is improved, and a phenomenon that a hydrophobic coating surface has spots as the solvent is volatilized too rapidly is avoided.

Description

technical field [0001] The invention belongs to the technical field of coated glass manufacturing, and in particular relates to a method for preparing hydrophobic, oil-repellent and easy-to-clean glass. Background technique [0002] Easy-to-clean glass uses coating modification on the glass surface to reduce the surface tension and surface energy of the glass. When water droplets and organic oils and other substances come into contact with the glass surface, the contact angle becomes larger, and the water droplets or oils form droplets, which roll freely on the glass surface. . [0003] At present, fluorosiloxane materials are mainly used to modify the glass surface to reduce the surface tension of the glass. The main method of coating modification is to coat the fluorine-containing silicone organic solvent on the glass surface by spraying, wiping, scraping, etc., among which organic Solvents are mainly alcohols. Compared with the three coating modification methods of spra...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C17/00C09D1/00C09D5/16
CPCC03C17/009C03C2217/40C03C2217/76C03C2218/112C09D1/00C09D5/1618C09D5/1662
Inventor 高升魏礼杰王昕高尔明
Owner 浙江鼎昇新材料科技股份有限公司
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