Method for making hydrophobic and oleophobic easy-to-clean glass
An oleophobic and glass-based technology, which is applied to biocide-containing paints, anti-fouling/underwater coatings, coatings, etc., can solve the problems of affecting the appearance of glass, fast curing of organic solvent volatilization film surface, and easy pitting.
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Embodiment 1
[0024] Take 1000 grams of AR ethanol and adjust the pH to 2.5 with hydrochloric acid to form an acidic ethanol solution. Under stirring conditions, add 210 grams of tetraethyl orthosilicate and 3 grams of tridecafluorooctyltriethoxysilane to the acidic ethanol solution. After stirring, add 200 grams of deionized water to the system to promote the hydrolysis of siloxane, let it stand and age for 48 hours, pour the resulting solution into 1500 grams of deionized water under vigorous stirring conditions, and stir to form a water-based hydrophobic and oleophobic Easy to clean paint.
[0025] Take 6mm flat glass, toughen and clean it, spray water-based hydrophobic and oil-repellent easy-clean coating under the conditions of spray gun speed of 50m / min, pressure of 0.3Mpa, and spraying flow rate of 40mL / min, and pre-condition at 120°C after spraying. After curing for 15 minutes, after curing at room temperature for 24 hours, clean the dust on the glass surface to obtain hydrophobic a...
Embodiment 2
[0027] Take 600 grams of AR ethanol and adjust the pH to 3 with hydrochloric acid to form an acidic ethanol solution. Under stirring conditions, add 12 grams of heptadecafluorodecyltriethoxysilane to the acidic ethanol solution, stir well and then add 100 grams of Deionized water is used to promote the hydrolysis of siloxane, and the resulting solution is poured into 1000 grams of deionized water under vigorous stirring conditions, and stirred to form a water-based hydrophobic and oil-repellent easy-to-clean coating.
[0028] Take 5 mm flat glass, use abrasive paste to grind and remove glass surface attachments, spray paint under the conditions of spray gun speed of 60m / min, pressure of 0.4Mpa, spray flow rate of 30ml / min, pre-cure at 100°C after spraying After 10 minutes and curing at room temperature for 24 hours, clean the dust on the glass surface to obtain hydrophobic and oil-repellent easy-to-clean glass. The film surface is black and has the effect of anti-reflection and...
Embodiment 3
[0030] Take 620 grams of AR ethanol and adjust the pH to 3 with nitric acid to form an acidic ethanol solution. Under stirring conditions, add 10 grams of tridecafluorooctyltriethoxysilane to the acidic ethanol solution, stir well and then add 100 grams to the system Deionized water is used to promote the hydrolysis of siloxane, and the resulting solution is poured into 1000 grams of deionized water under vigorous stirring conditions, and stirred to form a water-based hydrophobic and oil-repellent easy-to-clean coating.
[0031] Take 8 mm flat glass, use abrasive paste to grind and remove glass surface attachments, spray paint under the conditions of spray gun speed of 50m / min, pressure of 0.4Mpa, spray flow rate of 30ml / min, pre-cure at 100°C after spraying After 10 minutes and curing at room temperature for 24 hours, clean the dust on the glass surface to obtain hydrophobic and oil-repellent easy-to-clean glass. The hydrophobic film has no effect on the appearance of the glas...
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