A composite extraction system and extraction method for extracting lithium from lithium-containing brine
A technology for extracting lithium and brine, which is applied in the fields of chemical industry and extraction chemistry, can solve the problems of high preparation cost of new ionic liquids, difficulty in commercial production, difficulty in lithium recovery, etc., and achieve the effect of avoiding corrosion, simplifying the recovery process and simplifying the recovery steps
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Examples
Embodiment 1
[0026] In this example, the composition of the composite extraction system is: 40% TBP + 20% P507 as the extractant, kerosene as the diluent, and the Fe(III) loading capacity is 5.2 g / L.
[0027] In the lithium-containing brine, the lithium content is 1.6g / L, the chloride ion concentration is 298g / L, the sulfate radical concentration is 50g / L, the magnesium content is 106g / L, the sodium content is 14g / L, and the potassium content is 2.5g / L.
[0028] Using the composite extraction system and lithium-containing brine as raw materials, lithium is extracted through the following steps:
[0029] (1) Mix the composite extraction system with the lithium-containing brine at a ratio of 3:1, wherein the equivalent ratio of iron in the organic phase to lithium in the aqueous phase is 1.2. Hydrochloric acid was used to adjust the pH of the system to 0.12 for the extraction operation, and the single-stage extraction rate of lithium was 80.6%. After four stages of countercurrent extraction...
Embodiment 2
[0033] The composite extraction system is composed of: 20%TiAP+20%N503+10%P507+10%P204 as extraction agent, isotridecane as diluent, and Fe(III) loading capacity is 8.5g / L.
[0034] In lithium-containing brine, the lithium content is 1.6g / L, the chloride ion concentration is 298g / L, the sulfate radical concentration is 50g / L, the magnesium content is 106g / L, the sodium content is 14g / L, and the potassium content is 2.5g / L.
[0035] Using the composite extraction system and lithium-containing brine as raw materials, lithium is extracted through the following steps:
[0036](1) The composite extraction system is mixed with lithium-containing brine at a ratio of 3:1, wherein the equivalent ratio of iron in the organic phase to lithium in the aqueous phase is 2.0. Sulfuric acid was used to adjust the pH of the system to 0.5 for extraction operation, and the single-stage extraction rate of lithium was 85.3%. After five stages of countercurrent extraction, the extraction rate of li...
Embodiment 3
[0040] The composite extraction system consists of: 10% TBP+10% P507+10% Cyanex 272 as extractant, heptane as diluent, Fe(III) load 2.5g / L.
[0041] In lithium-containing brine, the lithium content is 0.3g / L, the chloride ion concentration is 150g / L, the sulfate radical concentration is 10g / L, the magnesium content is 45g / L, the sodium content is 12g / L, and the potassium content is 1.5g / L.
[0042] Using the composite extraction system and lithium-containing brine as raw materials, lithium is extracted through the following steps:
[0043] (1) Mix the composite extraction system with lithium-containing brine at a ratio of 1:1, wherein the equivalent ratio of iron in the organic phase to lithium in the aqueous phase is 1.0, and use sulfuric acid to adjust the pH of the system to 0.3 for extraction operations. Single-stage lithium The extraction rate was 78.2%. After five stages of countercurrent extraction, the extraction rate of lithium reaches 90.8%. The extraction rates of...
PUM
Abstract
Description
Claims
Application Information
- R&D Engineer
- R&D Manager
- IP Professional
- Industry Leading Data Capabilities
- Powerful AI technology
- Patent DNA Extraction
Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.
© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com