An organic light-emitting diode device comprises a glass substrate, a hole injection layer, a hole transmission layer, a green light-emitting layer, an electron transmission layer, an electron injection layer and a cathode layer which are sequentially stacked, wherein the cathode layer comprises a metal layer, a metal oxide mixed layer, a metal doped layer and a transparent conductive layer which are sequentially stacked. The metal layer is stacked on the electron injection layer and made from aluminum, nickel, gold or silver, the metal oxide mixed layer is made from a mixture formed by mixing, by same mass, two of neodymium pentoxide, vanadium pentoxide and tantalum pentoxide, the metal doped layer is made from silver doped magnesium or lithium doped aluminum, and the transparent conductive layer is made from an indium-tin oxide, an aluminum-zinc oxide or an indium-zinc oxide. The organic light-emitting diode device has high luminous efficiency. In addition, the invention further relates to a manufacturing method of the organic light-emitting diode device.