Conductive textile product based on layer-by-layer self-assembled silver nanowire/graphene
A layer-by-layer self-assembly, silver nanowire technology, used in textiles and papermaking, fiber processing, plant fibers, etc., can solve the problem of bond fastness to be improved, and achieve the effect of excellent washing fastness and excellent electrical conductivity.
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Embodiment 1
[0014] (1) Prepare silver nanowires into 1g / L aqueous solution, then add 1g / L PAMAM aqueous solution, the volume ratio of PAMAM to silver nanowire aqueous solution is 1:1, stir and react at a constant speed at room temperature for 24h, then use PAMAM-modified silver nanowires were obtained after repeated washing with ionized water and ethanol and drying. (2) Soak the cotton cloth in 1g / LPAMAM modified silver nanowire aqueous solution for 10min, the bath ratio is 1:10, take it out, rinse it repeatedly with deionized water, and dry it; then soak the above cotton cloth in 1g / L graphene oxide aqueous solution 10min, bath ratio 1:10, after taking it out, rinse it repeatedly with deionized water, dry it, place it in a hydrazine hydrate solution at 90°C for 2h, wash, filter it with suction, and dry it in vacuum to obtain a layer-by-layer self-assembled silver nanowire / graphite vinyl conductive textiles.
Embodiment 2
[0016] (1) Prepare silver nanowires into a 5g / L aqueous solution, then add 5g / L PAMAM aqueous solution, the volume ratio of PAMAM to silver nanowire aqueous solution is 1:5, stir and react at a constant speed at room temperature for 24h, then use PAMAM-modified silver nanowires were obtained after repeated washing with ionized water and ethanol and drying. (2) Soak the polyester cloth in 5g / LPAMAM modified silver nanowire aqueous solution for 30min, the bath ratio is 1:10, take it out, rinse it repeatedly with deionized water, and dry it; then soak the above polyester cloth in 5g / L graphene oxide In the aqueous solution for 30 minutes, the bath ratio is 1:10, after taking it out, rinse it repeatedly with deionized water, and dry it. So far, a layer of silver nanowires / graphene oxide has been assembled on the surface of the textile, and then the silver nanowires are modified in PAMAM and oxidized Repeat the above operation twice in the graphene finishing solution, then place it...
Embodiment 3
[0018] (1) Prepare the silver nanowires into a 10g / L aqueous solution, then add 10g / L PAMAM aqueous solution, the volume ratio of the PAMAM to the silver nanowire aqueous solution is 1:10, stir and react at a constant speed at room temperature for 24 hours, then use PAMAM-modified silver nanowires were obtained after repeated washing with ionized water and ethanol and drying. (2) Immerse the silk fabric in 10g / LPAMAM modified silver nanowire aqueous solution for 60min, the bath ratio is 1:10, take it out, rinse it repeatedly with deionized water, and dry it; then soak the above silk fabric in 10g / L graphene oxide In the aqueous solution for 60 minutes, the bath ratio is 1:10, after taking it out, rinse it repeatedly with deionized water, and dry it. So far, a layer of silver nanowires / graphene oxide has been assembled on the surface of the textile, and then the silver nanowires are modified in PAMAM and oxidized The above operation was repeated five times in the graphene finis...
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