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Method for synthesizing aluminum alloy powder through carbon thermal reduction method

A technology of aluminum alloy powder and reduction method, which is applied in the field of metal materials, can solve problems such as inability to apply oil extraction technology and insoluble alloys, and achieve the effects of saving industrial production costs, high costs, and improving utilization rates

Active Publication Date: 2018-02-09
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, these alloys cannot be dissolved in the oilfield mining environment and cannot be used in fracturing in the oil extraction process, so it is necessary to provide a soluble aluminum-based alloy

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] The process steps of synthesizing aluminum alloy powder by carbothermal reduction method proposed by the present invention are:

[0042] (1) Aluminum ore crushing: industrial aluminum ore (alumina>45%wt) is crushed with a crusher, and ball milled until the average particle size is less than 100 μm.

[0043] (2) Uniformly mixing zinc oxide with a particle size of less than 50 μm and industrial aluminum ore after ball milling to obtain a mixed powder.

[0044] (3) Mix the mixed powder prepared in step (2) with carbon powder, then react under the protection of argon, and raise the temperature from room temperature to 1100°C at a heating rate of 3°C / min, and keep it warm for 1.5h to make the reaction Fully generate carbides or carbon oxides, then continue to heat up from 1100°C to 1450°C at a rate of 2°C / min, keep it warm for 1.5h, and then cool to room temperature with the furnace; wherein, the mass ratio of mixed powder to carbon powder is 5:1;

[0045] (4) ball-milling...

Embodiment 2

[0048] (1) Aluminum ore crushing: industrial aluminum ore (alumina>45%wt) is crushed with a crusher, and ball milled until the average particle size is less than 100 μm.

[0049] (2) uniformly mixing metal oxides with a particle size of less than 50 μm and ball-milled industrial aluminum ore to obtain a mixed powder, wherein the metal oxide is tin oxide.

[0050] (3) Mix the mixed powder prepared in step (2) with carbon powder, then react under the protection of argon, and raise the temperature from room temperature to 1030°C at a heating rate of 4°C / min, and keep it warm for 2.5h to make the reaction Fully generate carbides or carbon oxides, then continue to heat up to 1300°C at a rate of 3°C / min, keep it warm for 3 hours, and then cool to room temperature with the furnace; wherein, the mass ratio of mixed powder to carbon powder is 5:1;

[0051] (4) Ball milling the reaction synthesis product obtained in step (3) and removing impurities therein to obtain aluminum alloy powde...

Embodiment 3

[0054] (1) Aluminum ore crushing: industrial aluminum ore (alumina>45%wt) is crushed with a crusher, and ball milled until the average particle size is less than 100 μm.

[0055] (2) Uniformly mixing metal oxides with a particle size of less than 50 μm and ball-milled industrial aluminum ore to obtain a mixed powder, wherein the metal oxide is a mixture of gallium oxide and tin oxide.

[0056] (3) Mix the mixed powder prepared in step (2) with carbon powder, then react under the protection of argon, and raise the temperature from room temperature to 1000°C at a heating rate of 5°C / min, and keep it warm for 3h to make the reaction fully Generate carbides or carbon oxides, then continue to heat up to 1400°C at a rate of 4°C / min, keep it warm for 2 hours, and then cool to room temperature with the furnace; wherein, the mass ratio of mixed powder to carbon powder is 5:1;

[0057] (4) Ball milling the reaction synthesis product obtained in step (3) and removing impurities therein t...

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Abstract

Disclosed is a method for synthesizing aluminum alloy powder through a carbon thermal reduction method. The method for synthesizing the aluminum alloy powder through the carbon thermal reduction method comprises the steps that metallic oxide with the particle size of being less than 50 [mu]m and industrial aluminum ore with the particle size of being less than 100 [mu]m are mixed, and the mixed powder is obtained; and after the mixed powder is mixed with carbon power, heat insulating is conducted for 1.5-3 h under the temperature of 1000-1100 DEG C under the inert gas protection, then the temperate is heated up to 1300-1450 DEG C, heat insulating is conducted for 1.5-3 h, cooling is conducted, and the soluble aluminum alloy powder is obtained. According to the method for synthesizing the aluminum alloy powder through the carbon thermal reduction method, steps for industrial synthesizing of an aluminum alloy are reduced, mineral raw materials are fully used, the synthesizing cost is reduced, the industrial aluminum ore is used as the raw material, when some compounds in the industrial aluminum ore are dissolved, a dissolved solution is alkaline, and the solubility uniformity is improved; and some industrial oxide can be used as reinforcing phases, the compressive strength of the degradable aluminum base alloy is moderately improved, the utilization ratio of the aluminum ore is improved, the process is simplified, and the industrial production cost is saved.

Description

technical field [0001] The invention belongs to the field of metal materials, and in particular relates to a method for synthesizing aluminum alloy powder by a carbothermal reduction method. Background technique [0002] The advanced technology in the exploitation of unconventional oil and gas fields in the world is multi-layer and multi-stage hydraulic fracturing technology, which uses a large number of downhole tools in the process of exploitation. High-strength dissolvable materials can be used to manufacture such downhole tools, which can meet the basic application performance requirements during use, especially under complex external conditions, can withstand high temperature and high pressure during working hours, and can be used as original after fracturing work Without grinding or flowback, the oil and gas pipeline can be restored unimpeded, which greatly saves manpower, material and financial resources, and greatly improves the speed of project progress. [0003] A...

Claims

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Application Information

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IPC IPC(8): B22F9/20
Inventor 郭思文张华光张文星胡开斌桂捷任国富赵敏琦薛晓伟邵媛
Owner PETROCHINA CO LTD