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A method for low-temperature solidification of waste gypsum into high-strength building materials

A building material, high-strength technology, applied in the field of new high-strength building materials, can solve problems such as environmental pollution, and achieve the effects of solving pollution, low energy consumption, and high utilization rate

Active Publication Date: 2020-03-17
上海海顾新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The object of the present invention is to provide a method for solidifying waste gypsum into high-strength building materials at low temperature. This method helps to solve the problems of stacking waste gypsum and environmental pollution. The flexural strength and compressive strength are sufficient to meet the needs of various building materials, and the process is simple, the cost is low, and it is suitable for mass production

Method used

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  • A method for low-temperature solidification of waste gypsum into high-strength building materials
  • A method for low-temperature solidification of waste gypsum into high-strength building materials
  • A method for low-temperature solidification of waste gypsum into high-strength building materials

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Effect test

Embodiment 1

[0024] Take waste gypsum, ground construction sand, cement, and fly ash as raw materials, and take 50% waste gypsum, 20% construction sand and gravel, 15% cement, 5% fly ash, and 10% water according to the quality. After the raw materials are fully pulverized and stirred, they are pressed and molded by the FW-4 tablet press to obtain a green body. The sample shape is a rectangular block with a length of about 40 mm, a width of about 15 mm, and a thickness of about 5 mm. The molding pressure is 30 MPa; the formed green body is transferred To the airtight hydrothermal reactor, add a certain volume of water to the reactor, the specific addition amount is 15% of the volume of the reactor, and then heat treatment, the heating temperature is 200 ℃, the time is 8 hours; the sample after the treatment is taken out Place it in an oven at 80°C and dry for 24 hours to obtain a cured product. The three-point method was used to test the flexural strength, and the results showed that the fle...

Embodiment 2

[0026] Take waste gypsum, ground construction sand, cement, and fly ash as raw materials, and take 40% waste gypsum, 20% construction sand and gravel, 20% cement, 10% fly ash, and 10% water according to the quality. After the raw materials are fully pulverized and stirred, they are pressed and molded by the FW-4 tablet press to obtain a green body. The sample shape is a rectangular block with a length of about 40mm, a width of about 15mm, and a thickness of about 5mm. The molding pressure is 20MPa; the formed green body is transferred Add a certain volume of water to the airtight reaction kettle, the specific addition amount is 15% of the volume of the reaction kettle, then heat treatment, the heating temperature is 160℃, the time is 16h; the sample after the treatment is taken out and placed The cured product can be obtained by drying in an oven at 80°C for 24 hours. The three-point method was used to test the flexural strength, and the results showed that the flexural strengt...

Embodiment 3

[0028] Using waste gypsum, ground construction sand, cement, and fly ash as raw materials, 60% waste gypsum, 10% construction sand and gravel, 12% cement, 8% fly ash, and 10% water are taken as raw materials. After the raw materials are fully pulverized and stirred, they are pressed and molded by the FW-4 tablet press to obtain a green body. The sample shape is a rectangular block with a length of about 40 mm, a width of about 15 mm, and a thickness of about 5 mm. The molding pressure is 30 MPa; the formed green body is transferred Add a certain volume of water to the airtight reaction kettle, the specific addition amount is 15% of the volume of the reaction kettle, and then heat treatment, the heating temperature is 120 ℃, the time is 24h; the sample after the treatment is taken out and placed The cured product can be obtained by drying in an oven at 80°C for 24 hours. The three-point method was used to test the flexural strength, and the results showed that the flexural stren...

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Abstract

The invention relates to a method for curing waste gypsum under low temperature into a novel high-strength building material, which belongs to the technical field of recycling gypsum waste produced inthe process of industrial production. 40 to 75 percent of waste gypsum, 10 to 20 percent of building aggregate, 5 to 25 percent of cement, 5 to 30 percent of fly ash and 5 to 25 percent of water arefirst weighed according to percentage by mass, the sum of all the component contents needs to be equal to 100 percent, a mixture is obtained by uniform grinding and stirring, the mixture is pressed tobe shaped into a green under the pressure of 10Mpa to 40Mpa, the green is demoulded and then put into a hydrothermal reactor, and after 8 to 24 hours of curing under 120 DEG C to 220 DEG C, the high-strength building material is obtained. The invention effectively solves the difficulty in recycling waste gypsum and problems such as easily causing secondary pollution on the environment, the utilization rate of the waste gypsum is increased, moreover, both the breaking strength and compressive strength of the produced high-strength building material are better than the use standard of ordinarybuilding materials (for example, wall and floor tiles, pavement bricks, footpath bricks and river embankment materials), the production process is simple, energy consumption in the production processis low, the period is short, the product cost is lower, and the method is suitable for mass production.

Description

Technical field [0001] The invention relates to a method for low-temperature solidification of waste gypsum into a new high-strength building material. It belongs to the technical field of the reuse of gypsum waste generated in the industrial production process. Background technique [0002] In the industrial production process, gypsum is a common accompanying product. Taking the phosphoric acid industry as an example, the production of one ton of phosphoric acid will produce 5 tons of phosphogypsum. With the gradual development of my country’s industry, the emission of gypsum is increasing, and the gypsum itself The utilization rate is extremely low, and a large amount of gypsum produced by the chemical plant is piled up like a mountain, occupying good land, causing serious pollution to the environment and also affecting the quality of life of the residents around the storage site. For example, Anhui Xuancheng Sirte Fertilizer Co., Ltd. produces nearly one million tons of phosph...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B28/14C04B40/02
CPCC04B28/142C04B28/143C04B28/144C04B40/024C04B2201/50C04B14/068C04B14/06C04B7/00C04B18/08C04B22/002
Inventor 成铭钊景镇子
Owner 上海海顾新材料科技有限公司