The invention relates to a method for producing
sulfuric acid and co-producing
calcium carbide by
phosphogypsum, and belongs to the technical field of
environmental protection. According to the method,
phosphogypsum is subjected to a
water washing and purification pretreatment by a multi-stage
cyclone; then the pretreated
phosphogypsum is dried and dewatered; the dewatered phosphogypsum enters a multi-stage suspension
heat exchanger to carry out preheating; the hot state
gypsum enters a circulating
fluidized bed decomposing furnace, then primary air and secondary air are respectively introduced to carry out decompositions; high temperature
sulfur dioxide-containing
flue gas discharged from the top of the circulating
fluidized bed decomposing furnace enters the multi-stage suspension
heat exchanger to carry out heat exchanging and cooling with the cold state
gypsum; dust in the cooled hot
flue gas is removed by a multi-stage dust removing device; the dust-removed
flue gas enters an
acid washing and purification
system to further remove the dust and the gaseous impurities in the
flue gas; the purified and cleaned
flue gas is conveyed into an acid preparation
system to produce the
sulfuric acid product; the hot state
calcium oxide discharged from the bottom of the circulating
fluidized bed decomposing furnace is cooled, and conveyed into a sealed
calcium carbide furnace to carry out an electrical arc reaction with a carbon material to generate the
calcium carbide product; the high temperature furnace gas discharged from the top of the sealed
calcium carbide furnace is directly conveyed into the decomposing furnace, wherein the high temperature furnace gas is adopted as a fuel and a
reducing agent. The method of the present invention has good
environmental protection benefits and strong economic advantages.