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A Method for Realizing Ultra-low Emission of Nox from Circulating Fluidized Bed Boiler

A circulating fluidized bed and boiler technology, which is applied in the direction of fluidized bed combustion equipment, combustion methods, fuel burned in a molten state, etc., can solve problems such as escape, reduce boiler thermal efficiency, and regular replacement of catalysts, and achieve reduction of original NOx emissions Effect

Active Publication Date: 2020-05-15
TSINGHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The cost of SNCR technology is low, but the denitrification efficiency is low, it cannot meet the standard requirements of ultra-low emissions, and to a certain extent, it reduces the thermal efficiency of the boiler
Compared with SNCR, SCR uses catalysts to catalytically reduce NOx under medium and low temperature conditions, and its denitrification efficiency is higher, but the initial investment and operating costs are higher, the floor area is large, and the catalyst needs to be replaced regularly
In addition, regardless of SNCR or SCR, ammonia is used as a reducing agent. In order to achieve a high denitrification efficiency, it is necessary to use an excessive amount of ammonia, so that a small amount of NH 3 escape

Method used

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  • A Method for Realizing Ultra-low Emission of Nox from Circulating Fluidized Bed Boiler
  • A Method for Realizing Ultra-low Emission of Nox from Circulating Fluidized Bed Boiler

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] Example 1: On a 90t / h circulating fluidized bed boiler, the change of NOx emission before and after the improvement of the separator was compared. The boiler uses high-quality bituminous coal, with a low calorific value of 5100-5200kcal / kg, an ash content of about 25%, a sulfur content of 0.4-0.9%, and a volatile content of 32-37% on a dry, ash-free basis.

[0040] The separator has been improved on this boiler, and the efficiency of the separator has been significantly improved. The improved separator corresponds to d 50 = 10 μm, d 90 = 54 μm. Under rated working conditions, the boiler meets the following parameters during operation: the air pressure in the boiler air chamber is about 6.2kPa, the differential pressure at the upper part of the furnace is about 1000Pa; the bed temperature is about 865°C. At this time, the original NOx emission of the boiler is 80~100mg / m 3 ,

[0041] And when a low-efficiency separator is used, its corresponding d 50 = 22 μm, d 90 ...

Embodiment 2

[0042] Example 2: A comparative experiment of bed material inventory adjustment was carried out on a 150t / h low-volatile bituminous coal circulating fluidized bed boiler. The boiler uses a fuel with a calorific value of 4500-4800kcal / kg, an ash content of about 30-33%, and a dry ash-free base volatile content of 21-23%.

[0043] Under rated working conditions, the air pressure in the boiler air chamber is controlled at 7.5-8.0kPa, the differential pressure at the upper part of the furnace is 1.4-1.5kPa, the bed temperature is around 878°C, and the oxygen content of the flue gas at the furnace outlet is controlled at less than 3.25%. At this time, the original NOx emission of the boiler is 50mg / m 3 .

[0044] When the wind pressure in the air chamber is 6.0-6.5kPa, the differential pressure at the upper part of the furnace is 1.0-1.1kPa, and the bed temperature is around 895°C, the original NOx emission rises to 75mg / m 3 .

Embodiment 3

[0045] Example 3: On a 150 / h high-quality bituminous coal-fired circulating fluidized bed boiler, a comparative experiment was carried out on the effect of bed temperature on NOx formation. The boiler uses Shenhua coal, the calorific value of the fuel is about 5000kcal / kg, the ash content is about 16%, the dry ash-free base volatile matter is about 36%, and the sulfur content is about 0.6%.

[0046] Under the rated working conditions, the air pressure of the boiler air chamber is controlled at 7.7-8.0kPa, the differential pressure at the upper part of the furnace is 1.6-1.8kPa, and when the bed temperature is 820-830°C, the original NOx emission is 50-60mg / m 3 .

[0047] Under rated working conditions, the air pressure in the air chamber is controlled at about 7.0kPa, the differential pressure at the upper part of the furnace is 1.3-1.4kPa, and when the bed temperature is 830-840°C, the original NOx emission increases to 60-70mg / m 3 ;

[0048] All other conditions remain the...

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Abstract

The invention provides a method for realizing ultra-low NOx emission of a circulating fluidized bed boiler, belonging to the technical field of controlling of pollutants in boiler flue gas. Accordingto the method, ammonia water, urea and other reducing agents are not used in the operation process of the circulating fluidized bed boiler, and the original NOx emission of the circulating fluidized bed boiler can be substantially reduced by controlling the granularity of a bed material and circulating ash, bed pressure drop, bed temperature, oxygen content at a hearth outlet, the granularity of particles escaping from the outlet of a separator, primary air share, fluidizing velocity and other operation parameters; the original NOx emission of the circulating fluidized bed boiler basically satisfy the ultra-low emission index of less than 50 mg / m<3>; the concentration of CO at the hearth outlet is lower than 150 mg / m<3>, and impact combustion efficiency is not obvious; at the same time, compared with SNCR or SCR, the method provided by the invention is free of the problems of ammonia escape and the like, so the performance of a circulatory system is improved, a reducing atmosphere in the boiler is strengthened, the NOx emission of the boiler reaches ultra-low emission standard, and environmental pollution is reduced.

Description

technical field [0001] The invention belongs to the technical field of boiler flue gas pollutant control, and in particular relates to a low-cost method and device for reducing NOx emissions from circulating fluidized bed boiler flue gas. Background technique [0002] NOx is one of the important culprits causing environmental problems such as acid rain and smog. Its main source is the combustion process of various fuels, especially the emissions from power stations and industrial boilers. According to the latest revision of "Emission Standards of Air Pollutants for Thermal Power Plants" (GB13223-2011), the NOx emission requirement for new boilers is <100mg / m 3 , the ultra-low emission index proposed in recent years requires NOx emission <50mg / m 3 (under the condition of the reference oxygen content of 6%). [0003] Due to the characteristics of medium-temperature combustion (800-900°C) and a large amount of reducing materials in the boiler, circulating fluidized bed ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): F23C10/10F23C10/18
CPCF23C10/10F23C10/18F23C2206/10
Inventor 柯希玮蔡润夏吕俊复岳光溪张缦杨海瑞张海吴玉新刘青
Owner TSINGHUA UNIV