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A kind of nitrogen foam gel plugging regulating agent and its preparation method and application

A foam gel, nitrogen foam technology, applied in chemical instruments and methods, earthwork drilling, wellbore/well components, etc., can solve the problems of unreachable temperature, inability to form glue, inapplicability, etc., and achieve good membrane strength , good plugging effect, and the effect of improving mining efficiency

Active Publication Date: 2020-03-10
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The nitrogen foam gel temporary plugging agent provided by the prior art cannot be gelled at 30°C-70°C because the temperature does not meet the conditions for cross-linking reaction, so it is not suitable for medium and low temperature oil reservoirs at 30°C-70°C

Method used

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  • A kind of nitrogen foam gel plugging regulating agent and its preparation method and application

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0031] In the second aspect, the embodiment of the present invention also provides a preparation method of the above nitrogen foam gel temporary plugging agent, the method includes:

[0032] According to the mass percentage of each component, add polyacrylamide, foaming agent, foam stabilizer, organic chromium crosslinking agent, and water into the reaction kettle and stir evenly, then place the reaction kettle in the oven to stand still to obtain a gel , And finally pass nitrogen into the gel to obtain a nitrogen foam gel plugging agent.

[0033] The preparation method of the above-mentioned nitrogen foam gel plugging control agent is simple, and the obtained nitrogen foam gel plugging control agent has good plugging effect, can reduce the number of gas cones and steam channeling channels, can improve the production efficiency of crude oil, and can be widely promoted use.

[0034] Each component can be dissolved in an appropriate amount of water before being evenly mixed and stirre...

Embodiment 1

[0049] In this example, the plugging effect of the nitrogen foam gel plugging agent was evaluated. The specific test process is as follows: select a cemented core of φ250×900 for the air-sealing model experiment, first fix the core in the middle of the cylinder, then inject air from the left end of the cylinder, and install a 10L transition vessel at the other end, and then connect it Air meter, reading Q after 3 minutes ventilation at a rate of 20 mL per minute 1 Then inject 3 times the volume of the core volume of the mixed solution for preparing the gel into the core, and then inject nitrogen gas with a volume ratio of 70:1 to the gel into the cylinder, and keep it at 40°C. Let stand for 10h under the conditions of, inject air from the left end of the cylinder for 3 minutes, and read Q 2 It is 9mL, and finally calculated according to the following formula to obtain the plugging rate of the nitrogen foam gel plugging agent:

[0050]

[0051] Among them, η is the blocking rate, ...

Embodiment 2

[0055] In this example, the plugging effect of the nitrogen foam gel plugging agent was evaluated. The specific test process is the same as the process of obtaining the plugging rate of the nitrogen foam gel plugging agent in Example 1, except that it is allowed to stand at 50°C for 9 hours, and then the cylinder is injected with gelatinous substance. The volume ratio of nitrogen is 80:1. The mixed solution used to prepare the gel includes: 2kg polyacrylamide, 2kg chromium lactate, 0.5kg sodium alkylbenzene sulfonate, 1kg sodium carboxymethyl cellulose, 94.5kg water.

[0056] The test results show that the blocking rate of the above nitrogen foam gel plugging agent is 88%. It can be seen that the nitrogen foam gel plugging regulator provided by the embodiment of the present invention can be used to plug gas cones, steam channeling channels or cracks in medium and low temperature oil layers at 30°C to 70°C, so as to improve the efficiency of crude oil production and meet the requ...

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Abstract

The invention discloses a nitrogen foam gel profile control agent and a preparation method and application thereof and belongs to the field of oilfield chemistry. The profile control agent comprises afoam gel skeleton and nitrogen gas distributed in the foam gel skeleton. The foam gel skeleton is obtained through feeding nitrogen gas into the gel. The gel is prepared from 1.5%-2.5% by mass of polyacrylamide, 0.3%-1% by mass of a foaming agent, 1%-3% by mass of a foam stabilizer, 1.5%-2.5% by mass of an organic chromium cross-linking agent and the balance of water through a cross-linking reaction. The foam stabilizer comprises sodium carboxymethyl cellulose or soluble starch. A volume ratio of the nitrogen gas to the foam gel skeleton is 70-95: 1. The profile control agent can seal and profile the medium and low temperature oil layers at 30 to 70 DEG C. The nitrogen foam gel skeleton has good membrane strength and good sealing effects and can greatly improve the mining efficiency of the crude oil.

Description

Technical field [0001] The invention relates to the field of oil field chemistry, in particular to a nitrogen foam gel plugging regulator, and a preparation method and application thereof. Background technique [0002] With the deepening of oilfield development, the formation energy will continue to decrease, and the production of crude oil will decline. In addition, due to the incompatibility of oil-water, oil and gas, and the heterogeneity of the reservoir, the uneven production among the reservoirs, within the reservoir, and the reservoir plane, causing gas cones in the reservoir, or making adjacent oil wells There are steam channeling channels between them, which makes the method of injecting water back into the oil well or the method of steam huff and puff cannot greatly improve the efficiency of crude oil production, and the interference of gas cone and steam channeling may also cause the oil well to fail to work normally. At present, it is possible to inject nitrogen foam...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K8/512C09K8/518E21B43/22
CPCC09K8/512C09K8/518E21B43/16
Inventor 苏娜谢刚谢娟李善维高孟祥曹瑞民肖云刘承炜唐建茹李梦瑶
Owner PETROCHINA CO LTD