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A kind of easy-to-clean nano antifouling and antibacterial coating and preparation method thereof

An antibacterial coating and easy-to-clean technology, applied in antifouling/underwater coatings, anti-corrosion coatings, coatings, etc., can solve problems such as low coating strength and wear resistance, decreased surface smoothness, and weak surface adhesion. Achieve good antibacterial effect, easy to clean, not easy to fall off

Active Publication Date: 2020-04-14
张积喜
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The present invention solves the aforementioned problems such as cracking of the antibacterial coating, or weak adhesion to the coated surface causing the coating to fall off, or low coating strength and wear resistance resulting in a decrease in surface smoothness, or the damaged coating is difficult to clean, etc., adopts the following Technical solution: the raw materials include the following components in parts by weight, 2-20 parts of nano-titanium dioxide, 5-20 parts of bentonite, 3-8 parts of silica airgel, 0.5-20 parts of modified rare earth, and 5-20 parts of nano-graphene , Isophorone 5-20, Diacetone Alcohol 1-20, Antifouling Agent 1-10, Modified Silicone Resin 6-20, Ethylene Glycol Butyl Ether / Propylene Glycol Butyl Ether 2-20, Butyl Acetate 6- 30;

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] An easy-to-clean nano antifouling and antibacterial coating, its raw materials include the following components in parts by weight: 10 parts of nano-titanium dioxide, 8 parts of bentonite, 5 parts of silica airgel, 4 parts of modified rare earth, and 6 parts of nano-graphene , 4 parts of isophorone, 6 parts of diacetone alcohol, 7 parts of antifouling agent, 10 parts of modified silicone resin, 5 parts of ethylene glycol butyl ether, 6 parts of butyl acetate;

[0029] Wherein, the modified rare earth is modified nano-cerium oxide and nano-lanthanum oxide, and the weight ratio of nano-cerium oxide and nano-lanthanum oxide is 0.35:1; a titanate coupling agent is used to modify nano-cerium oxide and nano-lanthanum oxide treatment, the particle size of the modified rare earth is 1-100nm; the particle size of the nano-graphene is 3-5nm;

[0030] Wherein, the nano-titanium dioxide particle size is 8-15nm, 22-35nm, wherein the aforementioned nano-titanium dioxide particle size...

Embodiment 2

[0041] An easy-to-clean nano antifouling antibacterial coating, its raw materials include the following components in parts by weight: 20 parts of nano-titanium dioxide, 10 parts of bentonite, 6 parts of silica airgel, 15 parts of modified rare earth, and 6 parts of nano-graphene , 10 parts of isophorone, 4 parts of diacetone alcohol, 5 parts of antifouling agent, 15 parts of modified silicone resin, 10 parts of ethylene glycol butyl ether, 8 parts of butyl acetate;

[0042] Wherein, the particle diameter of described modified rare earth, described nano titanium dioxide and the weight ratio of different particle diameters are identical with embodiment 1;

[0043] Wherein, the antifouling agent is 3 parts of polymethylsiloxane compound, 2 parts of carnauba wax, 2 parts of beeswax, 1 part of solid paraffin, 6 parts of petroleum spirit, 3 parts of sorbitan monostearate Part, POE sorbitol monostearate (POE20mol) 1 part, all the other are water;

[0044] Wherein, the modified sili...

Embodiment 3

[0047] An easy-to-clean nano antifouling and antibacterial coating, its raw materials include the following components in parts by weight: 15 parts of nano-titanium dioxide, 10 parts of bentonite, 5 parts of silica airgel, 15 parts of modified rare earth, and 10 parts of nano-graphene , 4 parts of isophorone, 6 parts of diacetone alcohol, 7 parts of antifouling agent, 10 parts of modified silicone resin, 5 parts of ethylene glycol butyl ether, 6 parts of butyl acetate;

[0048] Wherein, the particle diameter of described modified rare earth, described nano titanium dioxide and the weight ratio of different particle diameters are identical with embodiment 1;

[0049] Wherein, the antifouling agent is 2 parts of polymethylsiloxane compound, 1 part of carnauba wax, 1 part of beeswax, 2 parts of solid paraffin, 7 parts of petroleum spirit, 3 parts of sorbitan monostearate Part, POE sorbitol monostearate (POE20mol) 1 part, all the other are water;

[0050] Wherein, the modified si...

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Abstract

The invention discloses an easy-to-clean nano antifouling antibacterial paint and a preparation method thereof. The paint comprises the following raw materials by weight: 2-20 parts of nano titanium dioxide, 5-20 parts of bentonite, 3-8 parts of silica aerogel, 0.5-20 parts of modified rare earth, 5-20 parts of nano graphene, 5-20 parts of isophorone, 1-20 parts of diacetone alcohol, 1-10 parts ofan antifoulant, 6-20 parts of modified organic silicon resin, 2-20 parts of ethylene glycol butyl ether / propylene glycol butyl ether, and 6-30 parts of butyl acetate. The modified rare earth is modified nano cerium oxide and nano lanthanum oxide in a weight ratio of 0.35:1, and a titanate coupling agent is employed for modification treatment of nano cerium oxide and lanthanum oxide, the modifiedrare earth has a particle size of 1-100nm, and the nano graphene has a particle size of 3-5nm. The paint prepared by the technical scheme adopted by the invention can achieve the following effects after application to a substrate surface: 1. good anti-fouling effect; 2. easy cleaning; 3. good antibacterial effect; 4. strong adhesion; and 5. high hardness.

Description

technical field [0001] The invention relates to an antibacterial coating, in particular to an easy-to-clean nano antifouling antibacterial coating and a preparation method thereof. Background technique [0002] In daily life, the cleanliness of the home environment is getting more and more attention. In the residence, the kitchen, bathroom and other spaces, as well as the products used in the above-mentioned spaces and various household appliances and operating surfaces are undoubtedly the most vulnerable places to be polluted, because the temperature, humidity, pH, etc. of the above-mentioned spaces are more obvious. Changes, resulting in problems such as roughness, staining, aging, and cracking on the surface of the product or operating surface, and bacteria and viruses are more likely to adhere to it. Simultaneously, it is also very difficult to clean the above-mentioned space and the surface of the product. When the surface is severely damaged, replacement is inevitable...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D183/04C09D5/16C09D5/08C09D7/61C09D7/63
CPCC08K2003/221C08K2003/2213C08K2003/2241C08K2201/011C08K2201/014C08L2205/025C08L2205/035C09D5/08C09D5/1637C09D5/1675C09D5/1687C09D183/04C08L83/04C08L91/06C08K13/06C08K9/04C08K3/22C08K3/346C08K7/26C08K3/04
Inventor 张积喜
Owner 张积喜
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