Green energy-saving wearproof cold-resistant and flame retardant thermoplastic rubber and preparation method thereof

A thermoplastic rubber, flame retardant technology, applied in the field of thermoplastic rubber, can solve the problems of late low rolling resistance rubber technology, poor mechanical properties, poor weather resistance, etc., achieve good processing performance, excellent flame retardant and antistatic properties, Long service life effect

Active Publication Date: 2018-09-04
ANHUI ZHONGYI RUBBER BELTS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

There are currently outstanding problems in domestic research on low-smoke halogen-free rubber: first, there are few varieties, second, poor mechanical properties, and third, the product has poor weather resistance and can only be used at room temperature. Affect
my country's research on low rolling resistance rubber technology is relatively late. At present, there are many studies on low rolling resistance tires, but there are few reports on green energy-saving, wear-resistant, cold-resistant, flame-retardant thermoplastic rubber products and technologies.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] This embodiment provides a green, energy-saving, wear-resistant, cold-resistant, and flame-retardant thermoplastic rubber and a preparation method thereof. Described thermoplastic rubber is made of the following raw materials in parts by weight:

[0024] 40 parts of SIBR, 10 parts of SBS, 40 parts of PP, 10 parts of TPU, 3 parts of zinc oxide, 2 parts of stearic acid, 1.5 parts of sulfur, 2 parts of DCP, 0.5 parts of TAIC, 1 part of accelerator M, 0.5 parts of accelerator DM, 1 part of anti-aging agent BLE, 0.5 part of anti-aging agent 4010NA, 1 part of anti-scorch agent CTP, 2 parts of antioxidant 1010, 20 parts of EB118, 20 parts of VN2, C 5 4 parts of petroleum resin, 4 parts of antistatic agent P, 1 part of silane coupling agent Si69, 20 parts of DPOP, Al(OH) 3 10 parts, 10 parts of zinc borate, 10 parts of APP, 10 parts of MPP.

[0025] The preparation method of the present embodiment comprises the following steps:

[0026] (1) Preparation of SIBR masterbatch ...

Embodiment 2

[0035] This embodiment provides a green, energy-saving, wear-resistant, cold-resistant, and flame-retardant thermoplastic rubber and a preparation method thereof. Described thermoplastic rubber is made of the following raw materials in parts by weight:

[0036] 50 parts of SIBR, 15 parts of SBS, 20 parts of PP, 15 parts of TPU, 4 parts of zinc oxide, 1.5 parts of stearic acid, 1.8 parts of sulfur, 1 part of DCP, 0.8 parts of TAIC, 0.5 parts of accelerator M, 1 part of accelerator DM , 1 part of anti-aging agent RD, 1 part of anti-aging agent 2246-S, 1 part of anti-scorch agent CTP, 1 part of antioxidant 1010, 22 parts of EB118, 18 parts of VN2, C 5 5 parts of petroleum resin, 3 parts of antistatic agent P, 0.8 parts of silane coupling agent Si69, 25 parts of TCP, Mg(OH) 2 10, APP 15, MCA 10.

[0037] The preparation method of this embodiment is the same as that of Example 1.

Embodiment 3

[0039]This embodiment provides a green, energy-saving, wear-resistant, cold-resistant, and flame-retardant thermoplastic rubber and a preparation method thereof. Described thermoplastic rubber is made of the following raw materials in parts by weight:

[0040] 60 parts of SIBR, 5 parts of SBS, 30 parts of PP, 5 parts of TPU, 5 parts of zinc oxide, 1 part of stearic acid, 2 parts of sulfur, 1.5 parts of DCP, 1 part of TAIC, 1 part of accelerator CZ, 1 part of accelerator TMTD, 1 part of anti-aging agent RD, 1 part of anti-aging agent 4010NA, 1 part of anti-scorch agent CTP, 1.5 parts of antioxidant 1010, 25 parts of EB118, 15 parts of VN2, C 5 6 parts of petroleum resin, 2 parts of antistatic agent P, 0.5 parts of silane coupling agent Si69, 30 parts of TOP, Mg(OH) 2 10 parts, 10 parts of zinc borate, 10 parts of MPP.

[0041] The preparation method of this embodiment is the same as that of Example 1.

[0042] The detection data of above-mentioned embodiment sees the follow...

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PUM

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Abstract

The invention discloses a green energy-saving wearproof cold-resistant and flame retardant thermoplastic rubber and a preparation method thereof. An SIBR/PP/SBS/TPU polymer composite system, wearproof, loss reduction factor and good cold-resistant assistant materials and a halogen-free and antimony-free compound flame-retardant system are adopted as the main components, and preparation of SIBR masterbatch, silane modification treatment of a flame retardant, high-speed mixing pre-plasticization, internal mixer and extruder combined dynamic vulcanization and other processes are carried out. Under the conditions of an internal mixer rotation speed of 40rpm and a temperature of 160DEG C-165DEG C, dynamic vulcanization is carried out for 2-3min, then dynamic vulcanization by an extruder is conducted, and under the conditions of a screw rotation speed of 50-70rpm and a temperature of 165DEG C-180DEG C, dynamic vulcanization is conducted for 5-7min so as to obtain the thermoplastic rubber. Inaddition to the basic performance of thermoplastic rubber, the thermoplastic rubber provided by the invention also has excellent energy-saving, environmental protection, flame retardant, cold-resistant and other properties, and at the same time has the advantages of simple process, easy manufacturing, and low production cost.

Description

technical field [0001] The invention relates to the technical field of thermoplastic rubber, in particular to a green, energy-saving, wear-resistant, cold-resistant, flame-retardant thermoplastic rubber and a preparation method thereof. Background technique [0002] Low-smoke halogen-free flame-retardant rubber technology has become an important part of high-clean environmental protection technology, and economically developed countries have revised their original flame-retardant standards. In early 2003, the European Union promulgated the ROHS Directive, WEEE Directive and new flame retardant regulations, making more and more countries restrict or prohibit the use of halogenated flame retardants. Developed countries have always attached great importance to the research and development and promotion of low-smoke, low-halogen, and flame-retardant rubber materials, especially in important buildings and facilities that are relatively closed or crowded, such as coal mines, build...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L9/06C08L53/02C08L23/12C08L75/04C08L57/02C08K13/06C08K9/06C08K3/22C08K3/38C08K3/32C08K5/3492C08K5/09C08K5/14C08K5/134C08K3/04C08K3/36C08K5/521C08K5/523
CPCC08K2003/2224C08K2003/2227C08K2003/2296C08K2003/323C08K2003/387C08L9/06C08L2201/02C08L2201/04C08L2201/22C08L2205/035C08L2207/04C08L53/02C08L23/12C08L75/04C08L57/02C08K13/06C08K9/06C08K3/22C08K3/38C08K3/32C08K5/34928C08K5/09C08K5/14C08K5/1345C08K3/04C08K3/36C08K5/521C08K5/523
Inventor 宋长江宋鑫魏雪梅袁陆海吕继明王从开李朝红周震宇汪健
Owner ANHUI ZHONGYI RUBBER BELTS
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