Seawater desalinizing scale inhibitor and preparation method thereof

A scale inhibitor and water-soluble technology, applied in the field of seawater desalination scale inhibitor and its preparation, can solve the problems of poor scale inhibitor dispersion, poor corrosion inhibition performance, insufficient environmental protection, etc., and achieves good temperature resistance, low cost and effect. long lasting effect

Inactive Publication Date: 2018-10-09
SUZHOU YOUJUN ENVIRONMENTAL SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0010] In view of the above technical problems, the present application provides a seawater desalination scale inhibitor and its preparation method, which solves the technical problems of existing water treatment scale inhibitors such as high cost, environmental protection, poor scale inhibition dispersibility and poor corrosion inhibition performance.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] Weigh 1 part of trisodium phosphate according to the ratio of parts by weight; 2 parts of amino trimethylene phosphonic acid; 2 parts of polyaspartic acid; 3 parts of benzotriazole; 100 parts of water; 4 parts of chitosan; boric acid 5 parts of zinc; 2.5 parts of water-soluble copper sulfide; 6 parts of gluconic acid; 1 part of sodium hypophosphite; 1 part of phosphonic acid; 0.5 part of 2-mercaptobenzothiazole.

[0025] Add gluconic acid and water into a four-neck flask equipped with an electric stirrer, a constant pressure dropping funnel, a thermometer and a reflux condenser, heat to 60°C, stir for 5 minutes, add trisodium phosphate and benzotriazole dropwise, and heat up To 80°C, react for 2h.

[0026] Add ethylenediamine, water-soluble copper sulfide, polyaspartic acid and sodium hypophosphite, raise the temperature to 100°C, and react for 1h.

[0027] Raise the temperature to 120°C, add the remaining raw materials, stir for 50 minutes, cool to room temperature a...

Embodiment 2

[0030] Take by weight 5 parts of trisodium phosphate; 8 parts of amino trimethylene phosphonic acid; 6 parts of polyaspartic acid; 7 parts of benzotriazole; 100 parts of water; 6 parts of chitosan; boric acid 9 parts of zinc; 6.5 parts of water-soluble copper sulfide; 10 parts of gluconic acid; 9 parts of sodium hypophosphite; 3 parts of phosphonic acid; 4.5 parts of 2-mercaptobenzothiazole.

[0031] Add gluconic acid and water into a four-neck flask equipped with an electric stirrer, a constant pressure dropping funnel, a thermometer and a reflux condenser, heat to 80°C, stir for 25 minutes, add trisodium phosphate and benzotriazole dropwise, and heat up To 100°C, react for 4h.

[0032] Add ethylenediamine, water-soluble copper sulfide, polyaspartic acid and sodium hypophosphite, raise the temperature to 120°C, and react for 6h.

[0033] Raise the temperature to 140°C, add the remaining raw materials, stir for 90 minutes, cool to room temperature and discharge to obtain the...

Embodiment 3

[0036] Take by weight 3 parts of trisodium phosphate; 5 parts of amino trimethylene phosphonic acid; 4 parts of polyaspartic acid; 5 parts of benzotriazole; 100 parts of water; 5 parts of chitosan; boric acid 7 parts of zinc; 4.5 parts of water-soluble copper sulfide; 8 parts of gluconic acid; 8 parts of sodium hypophosphite; 2 parts of phosphonic acid; 2.5 parts of 2-mercaptobenzothiazole.

[0037] Add gluconic acid and water into a four-necked flask equipped with an electric stirrer, a constant pressure dropping funnel, a thermometer and a reflux condenser, heat to 70°C, stir for 15 minutes, add trisodium phosphate and benzotriazole dropwise, and heat up To 90°C, react for 3h.

[0038] Add ethylenediamine, water-soluble copper sulfide, polyaspartic acid and sodium hypophosphite, raise the temperature to 110°C, and react for 3 hours.

[0039] Raise the temperature to 130°C, add the remaining raw materials, stir for 70 minutes, cool to room temperature and discharge to obtain ...

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PUM

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Abstract

The invention discloses a seawater desalinizing scale inhibitor and a preparation method thereof. The seawater desalinizing scale inhibitor comprises the following raw materials: trisodium phosphate,amino sanya methylphosphonic acid, polyaspartic acid, benzotriazole, water, chitosan, zinc borate, water-soluble copper sulfide, gluconic acid, sodium hypophosphite, alkenyl glyceroether, diacetylmonoxime, itaconic acid, hydroxyethyl diphosphonic acid and 2-enzothiazole; the product is mainly applied to seawater desalinization, has high calcium tolerance and high scale-inhibiting dispersibility, is antibacterial and bacteriostatic, avoids environmental pollution and has corrosion inhibition rate being 97 to 99.9 percent; the product also can be applied to submarine oil field return water and oil conveying pipelines, can prevent metal ions, particularly barium and strontium ions from forming scale, has the pH value of 7 to 9 and has environmental friendliness; and the scale inhibitor has small use amount, operation concentration of 5 to 25*10<-6> and durable effect, has the scale-inhibiting effect of 98 to 99 percent after being placed for one month at 50 to 60 DEG C, has high temperature resistance, scale-inhibiting stability and corrosion-inhibiting property, and avoids discharge of three wastes in the synthesis process.

Description

technical field [0001] The application belongs to the technical field of ring reagents, and in particular relates to an environment-friendly seawater desalination scale inhibitor with good corrosion inhibition performance and a preparation method thereof. Background technique [0002] Scale inhibitor: It is a class of agents that can disperse insoluble inorganic salts in water, prevent or interfere with the precipitation and scaling of insoluble inorganic salts on metal surfaces, and maintain good heat transfer effects on metal equipment . [0003] Scale inhibitors can remove scale and prevent the formation of scale, improve heat exchange efficiency, reduce electric energy or reduce fuel consumption; water treatment can also reduce sewage discharge, improve water utilization, and generally save more than 60%, which is in line with my country's energy saving and emission reduction new policy. [0004] Reverse osmosis antiscalant is a scale inhibitor specially used in rever...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F5/10C02F5/14C02F103/08
CPCC02F5/105C02F5/145C02F2103/08C02F2303/08
Inventor 凌云凌天阳金可心夏戊君
Owner SUZHOU YOUJUN ENVIRONMENTAL SCI & TECH
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