Concrete crack resistance reinforcing additive and preparation method thereof
An additive and concrete technology, applied in the field of construction, can solve the problems of easy cracks, high brittleness, and low bending strength of concrete, and achieve high tensile strength and compressive strength, which is conducive to industrial production, crack resistance and impermeability good performance
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Embodiment 1
[0025] A concrete anti-crack strengthening additive, comprising the following raw materials in parts by weight: 16 parts of chitosan, 15 parts of sodium 4-cumene sulfonate, 12 parts of 2-mercaptobenzothiazole, methyl dihydrojasmonate 6 parts, 11 parts of p-nitrosoxylidine, 7 parts of isooctyl acetate.
[0026] A preparation method of a concrete anti-crack strengthening additive, the specific steps are: (1) adding p-nitrosoxylidine, chitosan and methyl dihydrojasmonate into a reaction kettle, and adding 20 parts of 85% Ethanol solution, under nitrogen protection, placed at -70°C and stirred for 2 hours; (2) Mix 2-mercaptobenzothiazole and isooctyl acetate, add 2 times the weight of the mixture in 75% ethanol solution, and mix evenly; Liquid one; (3) Add the mixed solution dropwise to the reaction kettle of step (1), and the rate of addition is 100 drops / min; (4) The reaction kettle is warmed up to -5°C, and 4-sodium cumenesulfonate is added, Stir and react for 1 hour; (5) cont...
Embodiment 2
[0028] A concrete anti-crack strengthening additive, comprising the following raw materials in parts by weight: 32 parts of chitosan, 22 parts of sodium 4-cumene sulfonate, 19 parts of 2-mercaptobenzothiazole, methyl dihydrojasmonate 17 parts, 17 parts of p-nitrosoxylidine, and 15 parts of isooctyl acetate.
[0029] A preparation method of a concrete anti-crack strengthening additive, the specific steps are: (1) adding p-nitrosoxylidine, chitosan and methyl dihydrojasmonate into a reaction kettle, and adding 35 parts of 85% Ethanol solution, under nitrogen protection, placed at -70°C and stirred for 3 hours; (2) Mix 2-mercaptobenzothiazole and isooctyl acetate, add 4 times the weight of the mixture in 75% ethanol solution, and mix uniformly; Liquid one; (3) Add the mixed solution dropwise to the reaction kettle of step (1), and the rate of addition is 200 drops / min; (4) The reaction kettle is warmed up to -5°C, adding 4-sodium cumene sulfonate, Stir and react for 3 hours; (5)...
Embodiment 3
[0031] A concrete anti-crack strengthening additive, comprising the following raw materials in parts by weight: 25 parts of chitosan, 17 parts of sodium 4-cumene sulfonate, 15 parts of 2-mercaptobenzothiazole, methyl dihydrojasmonate 11 parts, 13 parts of p-nitrosoxylidine, and 11 parts of isooctyl acetate.
[0032] A preparation method of a concrete anti-crack strengthening additive, the specific steps are: (1) adding p-nitrosoxylidine, chitosan and methyl dihydrojasmonate into a reaction kettle, and adding 25 parts of 85% Ethanol solution, under nitrogen protection, placed at -70°C and stirred for 2.5 hours. (2) Mix 2-mercaptobenzothiazole and isooctyl acetate, add 2.4 times the weight of the mixture in 75% ethanol solution, and mix evenly; a mixed solution 1 is obtained. (3) Add the mixed solution dropwise to the reaction kettle of step (1) at a rate of 150 drops / min. (4) Heat the reaction kettle to -5°C, add sodium 4-cumene sulfonate, and stir for 2 hours. (5) Continue ...
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