A kind of online hydrophilic treatment method of polyethylene sheet surface

A processing method, polyethylene technology, applied in the direction of coating, etc., can solve the problems of long processing time, increase hydrophilicity, and long time consumption, and achieve the effect of maintaining long processing effect, reducing volatile characteristics, and shortening processing time

A processing method, polyethylene technology, applied in the direction of coating, etc., can solve the problems of long processing time, increase hydrophilicity, and long time consumption, and achieve the effect of maintaining long processing effect, reducing volatile characteristics, and shortening processing time

CN108707245BActive Publication Date: 2019-06-07GUANGDONG JUHANG INST FOR ADVANCED MATERIALS CO LTD +1

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  • A kind of online hydrophilic treatment method of polyethylene sheet surface
  • A kind of online hydrophilic treatment method of polyethylene sheet surface

Examples

Experimental program
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Effect test

Embodiment 1

[0031] In the embodiment of the present invention: an online hydrophilic treatment method for the surface of a polyethylene sheet is provided, which specifically includes the following steps: the sheet is preheated by a heating plate, and the modifier forming liquid is sprayed on the upper surface of the preheated sheet The film is then sent to the ozone treatment room by the conveyor belt for secondary heating, surface catalytic oxidation and film curing. At the same time, the exhaust gas after ozone treatment is collected and purified, and provided to the ozone generator for recycling. Finally, the sheet winding and deposit.

[0032] Among them, the preheating of the heating plate adopts the method of upper and lower heating plates to preheat the sheet. The upper and lower heating plates are equidistant from the sheet and adopts synchronous isothermal control. The plane distance between the sheet and the upper and lower heating plates is 8-25cm, and the temperature range of t...

Embodiment 2

[0037] Based on the description of the above-mentioned embodiment 1, in order to further introduce the present invention, the following specific embodiments are also provided: including an online conveyor belt 2, an upper heating plate 3 for preheating, a lower heating plate 4 for preheating, a modified liquid sprayer 5, and an ozone generator Device 6, exhaust gas recovery and purification device 7, ozone treatment chamber 8, ozone oxidation heating plate 9, film layer curing heating plate 10 and sheet material winding device 11; wherein, one end of the online conveyor belt 2 is placed polyethylene sheet 1, pre- The upper heating plate 3 for heating and the lower heating plate 4 for preheating are installed symmetrically on the upper and lower sides of the online conveyor belt 2 respectively, and the modified liquid sprayer 5 is arranged at the outlet of the upper heating plate 3 for preheating and the lower heating plate 4 for preheating. At the material end, an ozone treatme...

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Abstract

Disclosed is an online hydrophilia treatment method for surface of a polyethylene sheet material. The sheet material is heated through a heating plate, a liquid film is formed by coating the surface of the preheated material with a modifier, the sheet material is then sent into an ozone treatment chamber through a conveyor belt for secondary heating to achieve surface catalytic oxidation and filmcuring, and meanwhile, waste gas generated after ozone treatment is collected and purified and then supplies to an ozone generator for recycling, and finally the sheet material is rolled up and stored. Since butyl methacrylate oligomer serves as the surface modifier, volatility of butyl methacrylate monomer is reduced, a good film forming effect is achieved based on the high fluidity, the treatment process of soaking after use of solvents is avoided, and energy saving and environmental protection are achieved, while the molding process is simplified. Besides, the ozone treatment chamber utilizes a staged heating treatment manner, time for treatment is shortened greatly; only upper surface of the sheet material is subjected to treatment, so that the circumstance that both inner and outer surface of a finished product are hydrophilic and tacky is avoided.

Description

technical field [0001] The invention relates to the technical field of polyethylene sheet production, in particular to an online hydrophilic treatment method for the surface of polyethylene sheets. Background technique [0002] Since polyethylene is a non-polar material, its surface energy is low, and its contact angle to polar solvents such as aqueous solutions is large. In the ideal mixed state, it is difficult to effectively transfer stress between the interfaces during the stress process, resulting in unsatisfactory comprehensive properties of the material. There are many ways to improve the compatibility of polyethylene with other materials and increase the hydrophilicity of the surface, such as changing the main structure of the molecular chain through copolymerization, grafting or crosslinking in chemical modification, or through blending and reactive extrusion. In order to increase the polar groups in the polyethylene matrix, the above modification method is to adju...

Claims

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Application Information

Patent Timeline
07 Jun 2019
Publication
CN108707245B
IPC
C08J7/16; C08J7/12; C09D4/02; C09D7/61; C08L23/06
CPC
C08J7/08; C08J7/12; C08J7/16; C08J2323/06; C09D4/00; C09D7/61; C09D7/67
Inventors
甄智勇; 朱永祥