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Microcrystalline glass and preparation method thereof

A glass-ceramic and micro-crystal technology, applied in the field of glass-ceramic and its preparation, can solve the problems of affecting the decorative effect and service life, cannot be used at high temperature, scratched or worn, etc., so as to overcome the problem of scratches and prolong the The effect of long service life and low cost

Active Publication Date: 2018-11-16
CDGM GLASS LLC
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] Traditional amber glass is colored by adding selenium and cadmium to the glass. Because cadmium is toxic, it is not suitable for use in the existing environment. The Mohs hardness of ordinary amber glass is 5H, while the Mohs hardness of commonly used knives is 5H. 5.5-6H, the grit or dust contains silica Mohs hardness 7H, which can cause scratches or wear on the surface of the existing amber decorative glass, affecting its decorative effect and service life, and ordinary amber glass does not High temperature resistance, it starts to soften at 700-800°C, and cannot be used at high temperatures

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  • Microcrystalline glass and preparation method thereof
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Embodiment Construction

[0028] The present invention uses ZnO(MgO)-Al 2 o 3 -SiO 2 -TiO 2 -CuO is the system, the precursor glass is prepared through the melting process, and the precursor glass is annealed and heat-treated to prepare the amber glass-ceramics. The content in weight percent and its effect will be described below.

[0029] SiO 2 、Al 2 o 3 , MgO or ZnO are the main components constituting glass-ceramic of the present invention, according to MgO (or ZnO)-Al 2 o 3 -SiO 2 phase diagram, in the present invention, SiO 2 The content of Al is 50-70%; Al 2 o 3 The content of MgO is 10-25%; the content of MgO is 0-22%, and the content of ZnO is 0-20%. In the present invention, at least one of the components in MgO and ZnO is contained, further, MgO and ZnO The total content is 5-22%, preferably 8-15%. When the contents of MgO and ZnO exceed the above range, other crystals will appear in the glass, which cannot meet the requirements of the present invention. SiO 2 and Al 2 o 3 Th...

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Abstract

The invention provides amber microcrystalline glass with high hardness and high-temperature resistance. The microcrystalline glass comprises, by weight, 50 to 70% of SiO2, 10.0 to 25% of Al2O3, 3 to 10% of TiO2, 0.2 to 0.7% of CuO, 0 to 22% of MgO and 0 to 20% of ZnO, wherein the microcrystalline glass contains at least one selected from the group consisting of MgO and ZnO. The microcrystalline glass of the invention has a Mohs hardness of 7.5-8 H, can be applied to decorative materials and decorative articles, and overcomes the problem of scratching of ordinary amber glass. The microcrystalline glass is not softened at a high temperature of 1,150 DEG C, has resistance to high temperatures, and can be further processed under high-temperature conditions. The microcrystalline glass of the invention has high mechanical strength, hardness and thermal stability, and good chemical stability, wear resistance and electrical insulation performance, and can be applied to decorative materials andused for high-grade decoration projects for interior and exterior walls, floors and pillars of buildings, etc.

Description

[0001] This application is a divisional application for the invention patent application with the application number 201510875782.8, the application date is December 3, 2015, and the title is "glass ceramics and its preparation method". technical field [0002] The invention relates to a glass-ceramic and a preparation method thereof, in particular to an amber glass-ceramic and a preparation method thereof. technical background [0003] Glass-ceramics has the advantages of glass, ceramics and natural stone, and has excellent thermodynamic properties, good chemical stability, high strength, high wear resistance, uniform and crystal-clear surface gloss, and easy cleaning. These characteristics determine the characteristics of glass-ceramics Occupying an important position in the field of materials, it can be used in high-end decoration projects such as building interior and exterior walls, floors, and corridor columns. [0004] Traditional amber glass is colored by adding sele...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C10/02C03C4/02C03B32/02
Inventor 原保平苏学剑于天来
Owner CDGM GLASS LLC
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