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Blends of polyolefin dispersions and epoxy resin dispersions for improved damage tolerance

A technology of epoxy resin and epoxy adduct, which can be used in epoxy resin coatings, coatings and other directions, and can solve problems such as water-based compositions that cannot provide damage-resistant epoxy resin coatings.

Active Publication Date: 2021-11-12
DOW GLOBAL TECH LLC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the composition of Malotky et al. does not provide an aqueous composition for the formation of damage-resistant epoxy coatings

Method used

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  • Blends of polyolefin dispersions and epoxy resin dispersions for improved damage tolerance
  • Blends of polyolefin dispersions and epoxy resin dispersions for improved damage tolerance
  • Blends of polyolefin dispersions and epoxy resin dispersions for improved damage tolerance

Examples

Experimental program
Comparison scheme
Effect test

example

[0074] Example:The following examples illustrate the invention. In all the examples that follow, unless otherwise indicated, temperature is room temperature and pressure is atmospheric.

Synthetic example

[0075] Synthetic Example: Dispersion Preparation: Dispersions A to J

[0076] Aqueous dispersions A to J having the compositions disclosed in Table 2 below were prepared using the raw materials disclosed in Table 1 below, using the conditions described in Table 2 below, using the following general procedure:

[0077] Components 1 to 3 listed in Table 2 below were fed into a 25 mm diameter twin-screw extruder using a controlled rate feeder; the feed rates used were in grams per minute (g / min) as follows Table 2 shows. Components 1 to 3 are advanced through the extruder and melted to form a liquid molten material.

[0078] The extruder temperature profile was ramped up to the temperatures listed in the "Polymer Melting Region" column of Table 2 below. Water and volatile base and / or neutralizing agent were mixed together and fed into the extruder at the rates shown in Table 2 to neutralize at the point of initial water introduction. Dilution water was then fed into the extru...

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Abstract

The present invention provides an aqueous composition for the preparation of a damage-resistant coating comprising a blend of (i) 2 to 30% by weight, based on the total weight of solids in the composition, An acid or anhydride functionalized polyolefin dispersion having an average particle size of , and (ii) a film-forming dispersion of one or more epoxy resins selected from the group having an epoxy equivalent weight of from 150 to 4,000 ( EEW) ​​and an epoxy resin having an average particle size of from 0.2 to 1.0 microns, wherein the polyolefin dispersion uses 2 to 8% by weight of one or more anionic surfactants based on the total weight of solids in the composition For example, sulfate-containing surfactants are stable, and, further wherein, the composition has a pH of 3 to 8.

Description

technical field [0001] The present invention relates to aqueous polyolefin dispersions and epoxy resin dispersion blends for coatings comprising 2 to 30% by weight of one or more acid or anhydride functionalizations blended with aqueous epoxy resin dispersions Polyolefin Dispersion (POD). Background technique [0002] Epoxy resins have found use in a variety of applications including coatings, molding, and adhesives. In the past, epoxy resins have proven to be susceptible to damage as they cure to produce brittle products that exhibit cracking, poor impact resistance and flexibility. Improvements in damage resistance of epoxy coatings have been achieved by various methods, including the addition of rubber, dry latex or block polymers, modification of epoxy resins, and melt blending of epoxy resins with polyolefins. However, each of these methods presents problems of choice, such as lack of compatibility between the resin and additives, difficulty or inconsistency in chemic...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L63/00C08G59/50C09D163/00C08G59/42
CPCC08G59/42C08G59/5006C09D163/00C08L63/00C08L23/00C08L51/06C08G59/4261
Inventor R·R·比尔斯陈亮D·L·马洛特基J·D·罗米克
Owner DOW GLOBAL TECH LLC