A kind of preparation method of mesh copper foil for lithium ion battery
A lithium-ion battery and copper foil technology, which is applied to battery electrodes, circuits, electrical components, etc., can solve the problems of burrs on the surface of through holes, high precision of abrasive tools, and easy deformation of holes, so as to achieve regular hole shape, High production efficiency, improved charge and discharge performance and energy density
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preparation example Construction
[0034] A kind of preparation method of reticular copper foil for lithium ion battery of the present invention, the method comprises the following steps:
[0035] (1) The surface of the copper foil is activated and cleaned by using a dilute sulfuric acid solution with a concentration of 2-10% to obtain a fully roughened surface with good adhesion to the photosensitive dry film.
[0036] (2) Using an automatic film laminating machine at a pressure roller temperature of 100-130°C and a pressure of 3-6kg / cm 2 The photosensitive dry film is pasted on the copper foil after activation and cleaning under certain conditions; the thickness of the photosensitive dry film is 10-40 μm, and then exposure and development are carried out; the exposure is using a laser exposure machine under ultraviolet light with a wavelength of 325-365 nm To expose, the exposure tool is a film film, and the light-transmitting area of the film film undergoes a cross-linking polymerization reaction under the...
Embodiment 1
[0041] A preparation method of mesh copper foil for lithium ion battery, the method comprises the steps of:
[0042] (1) using a dilute sulfuric acid solution with a concentration of 2% to activate and clean the surface of the copper foil;
[0043] (2) Using an automatic film laminating machine at a pressure roller temperature of 100°C and a pressure of 3kg / cm 2 The photosensitive dry film is pasted on the copper foil after activation and cleaning under certain conditions; the thickness of the photosensitive dry film is 10 μm, and then exposure and development are carried out; ; The development is the use of a concentration of 1.2% Na 2 CO 3 The solution acts as a developer for development.
[0044] (3) Etching the developed copper foil with an etchant, and performing stripping and cleaning in sequence after etching; the stripping is to use a NaOH solution with a concentration of 1% as the stripping solution to strip the strip. Described etchant is with HCl and CuCl 2 The...
Embodiment 2
[0048] A preparation method of mesh copper foil for lithium ion battery, the method comprises the steps of:
[0049] (1) using a dilute sulfuric acid solution with a concentration of 5% to activate and clean the surface of the copper foil;
[0050] (2) Using an automatic film laminating machine at a pressure roller temperature of 120°C and a pressure of 4kg / cm 2 The photosensitive dry film is pasted on the copper foil after activation and cleaning under certain conditions; the thickness of the photosensitive dry film is 20 μm, and then it is exposed and developed; ; The development is using a concentration of 1.0% K 2 CO 3 The solution acts as a developer for development.
[0051] (3) Etching the developed copper foil with an etchant, followed by film removal and cleaning after etching; the film removal is performed using NaOH solution with a concentration of 3% as the film removal solution. The etching solution is CuCl 2 , NH 3 ·H 2 O and NH 4 Alkaline etching solutio...
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