Resin composition for semiconductor encapsulation, prepreg and clad laminate using same
A technology of resin composition and semiconductor, which is applied in the direction of metal layered products, semiconductor/solid device components, lamination, etc., and can solve the problems of reduced flow characteristics and restrictions of prepregs
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preparation example Construction
[0170] (2) Preparation of prepreg and copper clad laminate
[0171] The resin composition for semiconductor encapsulation (resin varnish) prepared above was immersed in glass fiber (T-glass #1017, manufactured by Nittobo) with a thickness of 15 μm, and then dried with hot air at a temperature of 170° C. for 2 to 5 minutes to A prepreg having a thickness of 25 μm was prepared.
[0172] The two sheets of prepreg prepared above were laminated, and copper foil (12 μm in thickness, manufactured by Mitsui) was placed and laminated on both sides thereof, and heated at 220° C. and 35 kg / cm 2 Cured for 100 minutes under certain conditions.
[0173] [Table 1]
[0174] The composition of the resin composition for semiconductor encapsulation of the embodiment
[0175]
[0176]
[0177] *DDS: 4,4’-Diaminodiphenylsulfone
[0178] *TFB: 2,2’-bis(trifluoromethyl)benzidine; 2,2’-bis(trifluoromethyl)-4,4’-benzidine
[0179] *DDM: 4,4’-Diaminodiphenylmethane
[0180] *DDE: 4,4’-Diami...
experiment example
[0213]
[0214] The physical properties of the resin compositions for semiconductor encapsulation, prepregs, and copper clad laminates obtained in Examples and Comparative Examples were measured by the following methods, and the results are shown in Table 3 below.
[0215] 1. Coefficient of thermal expansion (CTE)
[0216] The copper foil layers of the copper clad laminates obtained in Examples and Comparative Examples were removed by etching, and then test specimens were prepared in the MD direction. The measurement was performed from 30°C to 260°C at a heating rate of 10°C / min by using TMA (TA Instruments, Q400), and the measured value in the temperature range of 50°C to 150°C was recorded as the coefficient of thermal expansion.
[0217] 2. Resin flow rate (RF)
[0218] (1) Initial resin flow rate
[0219]In the prepreg states obtained in Examples and Comparative Examples, RF was measured according to IPC-TM-650 (2.3.17) using a Carver press (Carver, Inc., #3893.4NE0000...
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