Crosslinkable copolymer and application thereof

A cross-linked copolymer and monomer technology, applied in the directions of ester copolymer adhesives, adhesive types, adhesive additives, etc., to achieve the effect of prolonging construction time, less impact on peeling rate, and improving workability

Active Publication Date: 2019-05-14
长兴材料工业(广东)有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, it is difficult for the pressure-sensitive adhesive layer of the existing protective film to satisfy the above-mentioned characteristics (1) to (4) at the same time.

Method used

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  • Crosslinkable copolymer and application thereof
  • Crosslinkable copolymer and application thereof
  • Crosslinkable copolymer and application thereof

Examples

Experimental program
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preparation example Construction

[0049] The preparation method of the monomer of formula (I) includes but is not limited to obtaining by making tertiary carbonic acid glycidyl esters (tertiary carbonic acid glycidyl esters) react with (meth)acrylic acid, for example, can be obtained by making C 5 to C 13 It is obtained by reacting glycidyl carboxylate with (meth)acrylic acid, or by reacting glycidyl (meth)acrylate with C 5 to C 13 New carboxylic acid reaction obtained. C 5 to C 13 Specific examples of glycidyl neocarboxylates include, but are not limited to, glycidyl pivalate, glycidyl neoheptanoate, glycidyl neononanoate, glycidyl neodecanoate, glycidyl neoundecanoate, and Glycidyl neotridecanoate. C 5 to C 13 Specific examples of neocarboxylic acids include, but are not limited to, neopentanoic acid, neoheptanoic acid, neononanoic acid, neodecanoic acid, neodecanoic acid, neodecanoic acid, and neotridecanoic acid.

[0050] The preparation of the monomer of formula (II) includes but not limited to th...

Embodiment approach

[0053] According to one embodiment of the present invention, monomer (B) may have the structure of the following formula (III):

[0054]

[0055] In formula (III), R 11 is H or methyl, and R 12 for C 1 to C 18 alkyl.

[0056] Specific examples of monomers of formula (III) include, but are not limited to, methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate, isopropyl acrylate, Isopropyl methacrylate, n-butyl acrylate, n-butyl methacrylate, isobutyl acrylate, isobutyl methacrylate, secondary butyl acrylate, secondary butyl methacrylate, tertiary butyl acrylate , tertiary butyl methacrylate, n-pentyl acrylate, n-pentyl methacrylate, isopentyl acrylate, isopentyl methacrylate, n-hexyl acrylate, n-hexyl methacrylate, n-heptyl acrylate, methyl n-heptyl acrylate, n-octyl acrylate, n-octyl methacrylate, 2-ethylhexyl acrylate, 2-ethylhexyl methacrylate, isooctyl methacrylate, n-nonyl acrylate, methyl n-nyl acrylate, is...

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Abstract

The invention provides crosslinkable copolymer which comprises structural units derived from following monomers including monomer (A), monomer (B) and monomer (C). The monomer (A) is monomer shown asa formula (I), monomer shown as a formula (II) or a combination thereof, wherein in the formula (I) and the formula (II), A is C2-C6 alkylene with hydroxyl, R1 is H or methyl, and R2, R3 and R4 are C1-C8 alkyl independently; the monomer (B) is (methyl) acrylic C1-C18 alkyl ester monomer, the monomer (C) is copolymerizable monomer containing hydroxyl, the monomer (B) does not contain hydroxyl, andeach of the monomer (B) and the monomer (C) is of a structure shown as the formula (I) or the formula (II). The invention further provides a pressure-sensing adhesive composition comprising the crosslinkable polymer.

Description

【Technical field】 [0001] The present invention relates to a crosslinkable copolymer, a pressure-sensitive adhesive composition comprising the crosslinkable copolymer, and a protective film comprising the pressure-sensitive adhesive composition. The protective film can be applied to various optical elements . 【Background technique】 [0002] In recent years, display devices such as liquid crystal displays (LCDs) have been widely used in various fields. During the manufacturing process of the display device, a suitable protective film is generally required to provide temporary protection to various optical elements such as polarizers, so as to prevent the optical elements from being polluted or damaged during the manufacturing process. The protective film must be easy to remove after temporary protection and leave as little residue as possible on the surface of the optic. [0003] Generally speaking, the protective film includes a pressure-sensitive adhesive layer and a subst...

Claims

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Application Information

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IPC IPC(8): C08F220/18C08F220/28C08F218/10C08F220/14C09J133/08C09J11/06C09J7/38
Inventor 陳啓漳林辰羿蕭伯卓
Owner 长兴材料工业(广东)有限公司
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