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High-brightness surface mirror resin for medium-hardness synthetic leather as well as preparation method and application of high-brightness surface mirror resin

A synthetic leather and resin technology, applied in the field of leather, can solve the problems of affecting the appearance, easy to indent, poor effect, etc., and achieve the effect of high surface toughness and excellent elasticity

Inactive Publication Date: 2019-05-17
华大化学(安徽)有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Aiming at the deficiencies of the prior art, the present invention provides a high-gloss mirror surface resin for medium-hard synthetic leather and its preparation method and application. The effect of mirror resin on the high-gloss surface of leather is poor in the application of medium-hard synthetic leather. The surface of the resin is easy to scratch and indentation, which affects the appearance. Users are quite troubled by this problem.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] Embodiment 1: A mirror-surface resin with a high-gloss surface for medium-hard synthetic leather, including the following raw materials: 160 parts of resin, 3 parts of curing agent, 5 parts of solvent, 10 parts of chain extender, 2 parts of catalyst, and 1 part of aluminum powder parts and 5 parts of polymer glycol.

[0025] 3-5 parts of curing agent is one of methyltriethoxysilane, ethyltriethoxysilane, vinyltriacetoxysilane, methyltributylketoximosilane or tetraethoxysilane, resin 160-200 parts is modified polypropylene resin, and 2-4 parts of catalyst is one of carboxylic acid, sulfonic acid, sulfinic acid or sulfuric acid.

[0026] 5-10 parts of polymer diol is polycarbonate diol mixed with polytetrahydrofuran diol, and 1-3 parts of aluminum powder is 800-1000 mesh aluminum powder.

[0027] A kind of preparation method of medium-hard synthetic leather high-gloss surface mirror resin, comprises the following steps:

[0028] 1) Prepare the reaction kettle, thermomet...

Embodiment 2

[0034] Example 2: A high-gloss mirror resin for medium-hard synthetic leather, including the following raw materials: 180 parts of resin, 4 parts of curing agent, 7 parts of solvent, 15 parts of chain extender, 3 parts of catalyst, and 2 parts of aluminum powder parts and 7 parts of polymer diol.

[0035] 3-5 parts of curing agent is one of methyltriethoxysilane, ethyltriethoxysilane, vinyltriacetoxysilane, methyltributanoximinosilane or tetraethoxysilane, resin 160-200 parts is modified polypropylene resin, and 2-4 parts of catalyst is one of carboxylic acid, sulfonic acid, sulfinic acid or sulfuric acid.

[0036]5-10 parts of polymer diol is polycarbonate diol mixed with polytetrahydrofuran diol, and 1-3 parts of aluminum powder is 800-1000 mesh aluminum powder.

[0037] A kind of preparation method of medium-hard synthetic leather high-gloss surface mirror resin, comprises the following steps:

[0038] 1) Prepare the reaction kettle, thermometer and stirring device, put 1...

Embodiment 3

[0044] Embodiment 3: A mirror-surface resin with a high-gloss surface for medium-hard synthetic leather, including the following raw materials: 200 parts of resin, 5 parts of curing agent, 9 parts of solvent, 20 parts of chain extender, 4 parts of catalyst, and 3 parts of aluminum powder parts and 10 parts of polymer diols.

[0045] 3-5 parts of curing agent is one of methyltriethoxysilane, ethyltriethoxysilane, vinyltriacetoxysilane, methyltributylketoximosilane or tetraethoxysilane, resin 160-200 parts is modified polypropylene resin, and 2-4 parts of catalyst is one of carboxylic acid, sulfonic acid, sulfinic acid or sulfuric acid.

[0046] 5-10 parts of polymer diol is polycarbonate diol mixed with polytetrahydrofuran diol, and 1-3 parts of aluminum powder is 800-1000 mesh aluminum powder.

[0047] A kind of preparation method of medium-hard synthetic leather high-gloss surface mirror resin, comprises the following steps:

[0048] 1) Prepare the reaction kettle, thermome...

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Abstract

The invention relates to the technical field of leather, and discloses high-brightness surface mirror resin for medium-hardness synthetic leather. The resin is prepared from the following raw materials in parts by weight: 160-200 parts of resin, 3-5 parts of a curing agent, 5-9 parts of a solvent, 10-20 parts of a chain extender, 2-4 parts of a catalyst, 1-3 parts of aluminum powder and 2 5-10 parts of polymer diol. According to the high-brightness surface mirror resin for the medium-hardness synthetic leather, as well as a preparation method and an application of the high-brightness surface mirror resin, 160-200 parts of resin is put in a reactor, heated to 150-200 DEG C and stirred for 3-10 minutes, 1-3 parts of aluminum powder, 2-4 parts of catalyst and 5-10 parts of polymer diol are added, the high-brightness surface mirror resin prepared in claim 1 for the medium-hardness synthetic leather is heated to 60-70 DEG C, adhered to a PU resin layer and insulated for 10 minutes. A high-brightness layer prepared from the high-brightness surface mirror resin prepared in claim 1 for the medium-hardness synthetic leather has excellent elasticity and surface toughness and cannot be easilyscratched, and permanent indentation cannot be left during extrusion.

Description

technical field [0001] The invention relates to the technical field of leather, in particular to a high-gloss mirror surface resin for medium-hard synthetic leather, a preparation method and application thereof. Background technique [0002] Leather is denatured and non-perishable animal skin obtained through physical and chemical processing such as depilation and tanning. Leather is composed of natural protein fibers tightly woven in three-dimensional space. There is a special grain layer on the surface, which has natural grain. In the process of human evolution, people found that some plant juices or mineral oils have a certain tanning effect on leather. Raw leather is more breathable and antiseptic through soaking in juice, so that the quality of the board can be improved. With physical and chemical properties such as softness, tear resistance, and bending resistance, the leather of this period really has the characteristics of leather products, and this juice is called a...

Claims

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Application Information

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IPC IPC(8): D06N3/18D06N3/14D06N3/04B32B27/08B32B27/06B32B27/32B32B27/40
Inventor 张道东刘其春王伟杰
Owner 华大化学(安徽)有限公司
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