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Molecular sieve/fiber composite material and preparation method therefor

A fiber composite material and molecular sieve technology, applied in the field of composite materials

Active Publication Date: 2019-06-07
杭州沸创生命科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0030] Aiming at the deficiencies of the prior art, the first technical problem to be solved by the present invention: the present invention solves the problem of molecular sieve aggregation on the fiber surface in the molecular sieve / fiber composite material for the first time, and provides a kind of Molecular sieve and fiber are firm, and the molecular sieve is uniformly distributed on the surface of the fiber. The molecular sieve in the composite material still maintains the original large effective specific surface area and strong pore material exchange capacity.

Method used

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  • Molecular sieve/fiber composite material and preparation method therefor
  • Molecular sieve/fiber composite material and preparation method therefor
  • Molecular sieve/fiber composite material and preparation method therefor

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Effect test

Embodiment 1

[0176] The preparation method of Y-type molecular sieve / cotton fiber composite material of the present invention may further comprise the steps:

[0177] ① Prepare the molecular sieve precursor solution, according to the following molar ratio 10Na 2 O: Al 2 o 3 :9SiO2 2 :200H 2 O constitutes the starting material to synthesize the molecular sieve precursor solution. The molecular sieve precursor solution is mixed with cotton fiber, and the mass ratio of cotton fiber to molecular sieve precursor solution is 1:20.

[0178] ②The cotton fiber and the homogeneously mixed molecular sieve precursor solution were transferred and heat-treated at 100°C for 24 hours to obtain a Y-type molecular sieve / cotton fiber composite material.

[0179] Randomly take 10 samples of the prepared Y-type molecular sieve / cotton fiber composite material at different positions, and analyze the content of the Y-type molecular sieve on the fiber surface by a thermogravimetric analyzer. The contents of t...

Embodiment 2

[0246] The preparation method of chabazite / cotton fiber composite material of the present invention, comprises the following steps:

[0247] ① Prepare the molecular sieve precursor solution, according to the following molar ratio 10Na 2 O: Al 2 o 3 :9SiO2 2 :300H 2 O constitutes the starting material to synthesize the molecular sieve precursor solution. The molecular sieve precursor solution is mixed with cotton fiber, and the mass ratio of cotton fiber to molecular sieve precursor solution is 1:0.5.

[0248] ②The cotton fiber and the uniformly mixed molecular sieve precursor solution were heat-treated at 80°C for 36 hours to obtain the chabazite / cotton fiber composite material.

[0249] Randomly get 10 samples of the prepared chabazite / cotton fiber composite material in different positions, analyze the content of chabazite on the fiber surface, the average content of molecular sieve on the fiber can be 25wt% in the 10 samples, and the sample standard deviation is 2.5wt%...

Embodiment 3

[0251] The preparation method of X-type molecular sieve / silk fiber composite material of the present invention comprises the following steps:

[0252] ① Prepare the molecular sieve precursor solution according to the following molar ratio 5.5Na 2 O:1.65K 2 O: Al 2 o 3 :2.2SiO2 2 :122H 2 O constitutes the starting material to synthesize the molecular sieve precursor solution. The molecular sieve precursor solution is mixed with the silk fiber, and the mass ratio of the silk fiber to the molecular sieve precursor solution is 1:10.

[0253] ②The silk fiber and the uniformly mixed molecular sieve precursor solution were heat-treated at 100°C for 12 hours to obtain the X-type molecular sieve / silk fiber composite material.

[0254] The obtained X-type molecular sieve / silk fiber composite material is randomly taken 8 samples in different positions, and the content of the X-type molecular sieve on the fiber surface is analyzed, and the average content of the molecular sieve on t...

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Abstract

The invention provides a molecular sieve / fiber composite material. The molecular sieve / fiber composite material comprises molecular sieves and fibers, wherein the molecular sieves are distributed on surfaces of the fibers and are in contact with the surfaces of the fibers directly, the particle size D90 of the molecular sieves is 0.01 to 50 microns, and the particle size D50 of the molecular sieves is 0.005 to 30 microns; and the molecular sieves are uniformly distributed on the surfaces of the fibers. The invention further provides a preparation method for the molecular sieve / fiber compositematerial and various uses of the molecular sieve / fiber composite material. According to the molecular sieve / fiber composite material, the preparation method therefor and various uses of the molecularsieve / fiber composite material, the problem of molecular sieve / fiber composite materials that molecular sieves are gathered on surfaces of fibers is solved for the first time, the molecular sieve / fiber composite material prepared is bran-new and has relatively high strength, elasticity restorability and dimensional stability, and thus, the composite material is firm and durable. The molecular sieve / fiber composite material provided by the invention is simple in structure, low in cost, high in stability, high in performance repeatability and high in practical efficiency and can be applied to the fields of arresting bleeding, facial beautification, deodorization, sterilization, water purification, air purification and antiradiation.

Description

technical field [0001] The invention relates to the field of composite materials, in particular to a molecular sieve / fiber composite material and a preparation method thereof. Background technique [0002] Substances with regular micropore structure and the function of screening molecules are called molecular sieves (moleculesieves). TO 4 Tetrahedron (T is selected from Si, Al, P, B, Ga, Ge, etc.) is the most basic structural unit of the molecular sieve framework (SiO 4 , AlO 4 , PO 4 , BO 4 , GaO 4 , GeO 4 etc.), through the combination of shared oxygen atoms to form a three-dimensional network structure of crystals. This combination form forms cavities and channels with molecular level and uniform pore size. Skeleton T atoms usually refer to Si, Al or P atoms, and in a few cases refer to other atoms such as B, Ga, Ge, etc. For example, zeolites are aluminosilicate molecular sieves, which are aluminosilicates with molecular sieving, adsorption, ion exchange, and ca...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L1/02C08K7/26A61L24/04A61L24/02A61L24/00B01J20/24B01J20/26B01J20/30B01D53/02C02F1/28
CPCC08K7/26A61L24/046A61L24/0005A61L24/08A61L24/0089A61L24/02A61L24/001B01J20/24B01J20/262B01D53/02C02F1/288C08K2201/005A61L2400/04C08L67/00C08L1/02C08K5/08D06M11/79D06M23/08B01D2253/108B01D2253/116B01D2253/25B01D2258/06B01D2253/304C08L1/286C08L5/08A61L15/18A61L15/42A61L15/40A61L15/46A61L15/44A61L2300/404A61L2300/44A61L17/005A61L17/10B01J20/18B01J20/28028B01J20/28004B01J20/28057C02F2305/08C02F2305/04C02F1/42A61L24/00A61L24/04B01J20/26B01J20/30C02F1/28C08K3/34A61P7/04A61K31/7088A61K31/715A61K31/74A61K33/00A61K38/00A61K45/06A61L24/0031A61L24/0036A61L2400/12B01J20/28007
Inventor 范杰余丽莎肖丽萍陈昊尚小强
Owner 杭州沸创生命科技股份有限公司
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