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A kind of ultra-low temperature curing epoxy anticorrosion coating

A technology of epoxy anti-corrosion coatings and anti-corrosion coatings, applied in the direction of anti-corrosion coatings, coatings, etc., can solve the problems of high curing temperature, reduced adhesion, narrow application range, etc., to reduce the curing reaction temperature, improve climate tolerance, Effect of improving volume change rate

Active Publication Date: 2021-04-27
CHANGSHU FANGTA COATING CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, commonly used epoxy resins have problems such as high viscosity and high curing temperature at room temperature. The curing temperature of conventional epoxy resin / anhydride systems is 180-200°C, and the curing time is 15-30 minutes. On the one hand, the temperature consumes a lot of energy, and it will affect the substrate with poor heat resistance, which limits its application on heat-sensitive substrates, resulting in a narrow application range; and limits the wide application of epoxy resin
Moreover, since the coating film of epoxy coatings will expand or shrink with the change of ambient temperature, this kind of thermal expansion and contraction will easily lead to easy cracking of the coating film. If it is applied in an outdoor environment, it will easily cause the film layer to be corroded and the color of the coating will change color. , Adhesion reduction, peeling and other disadvantages

Method used

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  • A kind of ultra-low temperature curing epoxy anticorrosion coating

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] An ultra-low temperature curing epoxy anti-corrosion coating, the ultra-low temperature curing epoxy anti-corrosion coating includes: component A and component B, and the addition ratio between the raw material A and raw material B is 20:3;

[0019] The component A includes 25 parts of bisphenol F epoxy resin, 20 parts of silane-modified epoxy resin, 2 parts of auxiliary agents compounded by coupling agent, degassing agent and leveling agent, 15 parts of nano silicon dioxide part, 2 parts of lignocellulose, 3 parts of titanium dioxide, and 10 parts of deionized water, the coupling agent is a silane coupling agent in the compounding auxiliary agent, the degassing agent is benzoin, and the leveling agent is butyl acrylate, The butyl acrylate also has the effect of increasing light, and the compounding ratio is 3:9:9;

[0020] The component B is a curing agent prepared in a ratio of 10 parts of phenalkamine, 2 parts of ethylenediamine, 2 parts of polyamide, and 10 parts of...

Embodiment 2

[0028] An ultra-low temperature curing epoxy anti-corrosion coating, the ultra-low temperature curing epoxy anti-corrosion coating includes: component A and component B, and the addition ratio between the raw material A and raw material B is 20:3;

[0029] The component A includes 25 parts of bisphenol F-type epoxy resin, 40 parts of silane-modified epoxy resin, 3 parts of auxiliary agents compounded by coupling agent, degassing agent and leveling agent, 20 parts of nano-silica part, 8 parts of lignocellulose, 4 parts of titanium dioxide, and 15 parts of deionized water, the coupling agent is a silane coupling agent in the compounding auxiliary agent, the degassing agent is benzoin, and the leveling agent is butyl acrylate, The butyl acrylate also has the effect of increasing light, and the compounding ratio is 3:9:9;

[0030] The component B is a curing agent prepared in a ratio of 3 parts of phenalkamine, 5 parts of ethylenediamine, 5 parts of polyamide, and 5 parts of deion...

Embodiment 3

[0038] An ultra-low temperature curing epoxy anti-corrosion coating, the ultra-low temperature curing epoxy anti-corrosion coating includes: component A and component B, and the addition ratio between the raw material A and raw material B is 5:1;

[0039] The component A includes 45 parts of bisphenol F type epoxy resin, 40 parts of silane modified epoxy resin, 4 parts of auxiliary agents compounded by coupling agent, degassing agent and leveling agent, 25 parts of nano silicon dioxide part, 10 parts of lignocellulose, 5 parts of titanium dioxide, and 20 parts of deionized water, the coupling agent is a silane coupling agent in the compounding auxiliary agent, the degassing agent is benzoin, and the leveling agent is butyl acrylate, The butyl acrylate also has the effect of increasing light, and the compounding ratio is 1:5:5;

[0040] The component B is a curing agent prepared in the proportion of 10 parts of phenalkamine, 3 parts of ethylenediamine, 3 parts of polyamide, and...

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Abstract

The invention discloses an ultra-low temperature curing epoxy anticorrosion coating. The ultralow temperature curing epoxy anticorrosion coating is composed of two components A and B. The component A is composed of film-forming resin, auxiliary agent, filler, pigment and deionized Composed of water, the film-forming resin is composed of 25-45 parts of bisphenol F epoxy resin, 20-40 parts of silane-modified epoxy resin, 2-4 parts of the auxiliary agent, and the filler includes nano-silica 15~25 parts and 2~10 parts of lignocellulose, the pigment is 3~5 parts of titanium dioxide, and the deionized water is 10~20 parts; the component B is a curing agent, consisting of 3~10 parts of phenalkamine, B It consists of 2~5 parts of diamine, 2~5 parts of polyamide and 5~10 parts of deionized water. The above formulation system can effectively improve the weather resistance of the coating, prevent cracking, and has the advantages of good anti-corrosion properties and high adhesion. The curing agent used is a mixed curing system with phenalkamine as the main body, which can effectively Accelerate the reaction speed of epoxy resin, reduce the curing reaction temperature and reduce the curing energy consumption.

Description

technical field [0001] The invention relates to the field of epoxy coatings, in particular to an ultra-low temperature curing epoxy anticorrosion coating. Background technique [0002] Epoxy coatings have excellent technological properties, mechanical properties and physical properties, and are widely used. However, commonly used epoxy resins have problems such as high viscosity and high curing temperature at room temperature. The curing temperature of conventional epoxy resin / anhydride systems is 180-200°C, and the curing time is 15-30 minutes. On the one hand, the temperature consumes a lot of energy, and on the other hand, it will affect the substrate with poor heat resistance, which limits its application on heat-sensitive substrates, resulting in a narrow application range; and limits the wide application of epoxy resin. Moreover, since the coating film of epoxy coatings will expand or shrink with the change of ambient temperature, this kind of thermal expansion and co...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D4/06C09D4/02C09D5/08C09D7/61C09D7/63C09D7/65
Inventor 钱强
Owner CHANGSHU FANGTA COATING CHEM
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