Compounds with antitumor activity isolated from Anemarrhena and its preparation method
A compound and a technology for preparing a column are applied in the field of compounds with anti-hepatoma activity, which can solve the problems of insufficient curative effect and normal cell death.
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[0064] Example 1 Separation, Preparation and Identification of Antitumor Compounds
[0065] The dried Anemarrhena fibrous roots (30kg) were pulverized and extracted by percolation with 70% ethanol. The ethanol percolate was concentrated under reduced pressure to obtain a brown crude extract. The crude extract was dispersed with water and extracted with ethyl acetate. Disperse the remaining water part after extraction with water, the solution flows through the AB-8 macroporous resin column, elutes with ethanol-water (10:90 and 90:10), and the 90% ethanol part passes through the silica gel column (200-300 mesh ) was further purified and eluted with dichloromethane-methanol (100:1~0:1) to obtain Fr.1~Fr.7. Fr.1 (dichloromethane-methanol=100:1 part) was subjected to silica gel column elution (gradient elution with petroleum ether-ethyl acetate system 20:1-1:1) to obtain Fr.1.1-Fr.1.4. Fr.1.3 (petroleum ether-ethyl acetate=5:1 fraction) obtained compound 4 (7mg, t R =20.3min, m...
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