A method for regeneration and reuse of cutting oily iron sludge
A technology for iron sludge and degreasing agent, which is applied in the field of solid waste recycling, can solve the problems of shortened furnace life, furnace sticking, poor casting performance, etc., achieves prevention and control of iron oxidation, high environmental protection and economic value, Simple and easy operation
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Embodiment 1
[0037] Such as figure 1 As shown, the present embodiment relates to a method for recycling oily iron sludge, comprising the following steps:
[0038] (1) Degreasing: Add 100g of water to 100g of oil-containing iron sludge, add 1g of OP-10 and higher fatty acid sodium, and stir mechanically at room temperature at a speed of 10rpm for 40min, then separate and dry, weigh, and obtain degreasing Oily iron mud. Such as figure 2 Oily iron sludge in the Central Plains and iron sludge exposed to impurities after deoiling.
[0039] (2) Calcination: Calcining the deoiled iron sludge at 100°C for 3 hours to obtain high-quality calcined iron sludge.
[0040] (3) Magnetic separation: the high-quality calcined iron slime in the above-mentioned steps (2) is subjected to mineral processing under magnetic separation conditions, and the magnetic separation current is 0.2A, and the gained concentrate is again selected under this condition for 4 times, which can be Obtain iron-bearing concent...
Embodiment 2
[0046] Such as figure 1 As shown, the present embodiment relates to a method for recycling oily iron sludge, comprising the following steps:
[0047] (1) Degreasing: Add 500g of water to 100g of oil-containing iron sludge, add 10g of TX and quaternary ammonium salt cationic surfactant, heat to 90°C, stir mechanically at a speed of 600rpm, stir for 1min, then separate and dry, weigh Heavy, get deoiled iron sludge.
[0048] (2) Calcination: Calcining the deoiled iron sludge at 500°C for 0.2h to obtain high-quality calcined iron sludge.
[0049](3) Magnetic separation: the high-quality calcined iron slime in the above-mentioned steps (2) is subjected to mineral processing under magnetic separation conditions, and the magnetic separation current is 0.6A. Iron-containing concentrate and non-magnetic tailings are obtained respectively.
[0050] (4) Reduction: the iron-containing concentrate obtained in step (3) is reduced with CO in a fixed bed, and the reduction time is 0.2 h to...
Embodiment 3
[0056] This embodiment relates to a method for regenerating and recycling cutting oily iron sludge, comprising the following steps:
[0057] (1) Degreasing: Add 800g of water to 200g of oily iron sludge, add 4g of higher fatty acid sodium, heat to 50°C, stir mechanically at a speed of 550rpm, stir for 30min, then separate and dry, weigh to obtain deoiled iron mud.
[0058] (2) Calcination: calcining the degreased iron sludge at 450° C. for 1 hour to obtain high-quality calcined iron sludge.
[0059] (3) Reduction: the iron slime obtained in step (2) is reduced with hydrogen in a fixed bed, and the reduction time is 2 hours to obtain reduced ore.
[0060] (4) Magnetic separation: the reduced ore in the above-mentioned step (3) is subjected to mineral processing under magnetic separation conditions, and the magnetic separation current is 0.4A, and the gained magnetic separation is carried out 2 times of concentration under this condition again, and can obtain respectively Iron...
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