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A method for regeneration and reuse of cutting oily iron sludge

A technology for iron sludge and degreasing agent, which is applied in the field of solid waste recycling, can solve the problems of shortened furnace life, furnace sticking, poor casting performance, etc., achieves prevention and control of iron oxidation, high environmental protection and economic value, Simple and easy operation

Active Publication Date: 2020-12-11
INST OF PROCESS ENG CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At the same time, the cutting process of the cutting machine will involve alumina (corundum), resulting in an increase in the aluminum content in the generated iron sludge; and the higher the aluminum content in the iron filings, the worse the performance of the casting made
[0004] Domestic methods for this iron sludge mainly include stockpiling and sending them to steel plants for recycling. The stockpiling method will not only cause secondary pollution, but also lead to serious waste of resources
Sending iron slime to the iron and steel plant for recycling can reduce land occupation, but the iron slime with high oil content and high impurity content will cause serious pollution and sticky furnace problems during the smelting process, resulting in the decline of steel quality and shortened furnace life.

Method used

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  • A method for regeneration and reuse of cutting oily iron sludge
  • A method for regeneration and reuse of cutting oily iron sludge

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] Such as figure 1 As shown, the present embodiment relates to a method for recycling oily iron sludge, comprising the following steps:

[0038] (1) Degreasing: Add 100g of water to 100g of oil-containing iron sludge, add 1g of OP-10 and higher fatty acid sodium, and stir mechanically at room temperature at a speed of 10rpm for 40min, then separate and dry, weigh, and obtain degreasing Oily iron mud. Such as figure 2 Oily iron sludge in the Central Plains and iron sludge exposed to impurities after deoiling.

[0039] (2) Calcination: Calcining the deoiled iron sludge at 100°C for 3 hours to obtain high-quality calcined iron sludge.

[0040] (3) Magnetic separation: the high-quality calcined iron slime in the above-mentioned steps (2) is subjected to mineral processing under magnetic separation conditions, and the magnetic separation current is 0.2A, and the gained concentrate is again selected under this condition for 4 times, which can be Obtain iron-bearing concent...

Embodiment 2

[0046] Such as figure 1 As shown, the present embodiment relates to a method for recycling oily iron sludge, comprising the following steps:

[0047] (1) Degreasing: Add 500g of water to 100g of oil-containing iron sludge, add 10g of TX and quaternary ammonium salt cationic surfactant, heat to 90°C, stir mechanically at a speed of 600rpm, stir for 1min, then separate and dry, weigh Heavy, get deoiled iron sludge.

[0048] (2) Calcination: Calcining the deoiled iron sludge at 500°C for 0.2h to obtain high-quality calcined iron sludge.

[0049](3) Magnetic separation: the high-quality calcined iron slime in the above-mentioned steps (2) is subjected to mineral processing under magnetic separation conditions, and the magnetic separation current is 0.6A. Iron-containing concentrate and non-magnetic tailings are obtained respectively.

[0050] (4) Reduction: the iron-containing concentrate obtained in step (3) is reduced with CO in a fixed bed, and the reduction time is 0.2 h to...

Embodiment 3

[0056] This embodiment relates to a method for regenerating and recycling cutting oily iron sludge, comprising the following steps:

[0057] (1) Degreasing: Add 800g of water to 200g of oily iron sludge, add 4g of higher fatty acid sodium, heat to 50°C, stir mechanically at a speed of 550rpm, stir for 30min, then separate and dry, weigh to obtain deoiled iron mud.

[0058] (2) Calcination: calcining the degreased iron sludge at 450° C. for 1 hour to obtain high-quality calcined iron sludge.

[0059] (3) Reduction: the iron slime obtained in step (2) is reduced with hydrogen in a fixed bed, and the reduction time is 2 hours to obtain reduced ore.

[0060] (4) Magnetic separation: the reduced ore in the above-mentioned step (3) is subjected to mineral processing under magnetic separation conditions, and the magnetic separation current is 0.4A, and the gained magnetic separation is carried out 2 times of concentration under this condition again, and can obtain respectively Iron...

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Abstract

The invention provides a method for regenerating reuse of cutting oil-containing iron sludge. The method comprises the following experimental steps that (1) oil removal is carried out, specifically, the oil-containing iron sludge is dispersed, and an oil removal agent is added to obtain the oil-removed iron sludge; (2), calcining is carried out, specifically, the oil-removed iron sludge obtained in the step (1) is subjected to calcining to obtain the calcined iron sludge; (3), magnetic separation reduction is carried out, specifically, a, magnetic separation is carried out firstly, and then reduction is carried out; or, b, reduction is carried out firstly, and then magnetic separation is carried out; (4) forming is carried out, specifically, iron concentrate obtained in a of the step (3) or iron-containing concentrate obtained in b of the step (3) is formed through a cold pressing process to obtain the formed concentrate; and (5) sintering is carried out, specifically, the formed concentrate obtained in the step (4) is processed under reduction atmosphere protection to obtain a powder metallurgy casting. According to the method for regenerating reuse of the oil-containing iron sludge, oil-containing iron sludge solid waste is used as a raw material so as to produce fine iron powder and stainless steel powder or to prepare the powder metallurgy casting, and thus the resourceful high-value utilization of dangerous solid is realized.

Description

technical field [0001] The invention relates to the technical field of solid waste resource treatment, in particular to a method for recycling oily iron sludge from cutting. Background technique [0002] Bearing steel is a kind of high-carbon chromium bearing steel with less alloy content, good performance and the most widely used. After quenching and tempering, it has high and uniform hardness, good wear resistance and high contact fatigue performance. At present, cutting steel products are used to make various bearing rings and rolling elements. For example: steel balls, rollers and rings for making internal combustion engines, electric locomotives, automobiles, tractors, machine tools, rolling mills, drilling machines, mining machinery, general machinery, and high-load mechanical transmission bearings rotating at high speeds. In addition to making balls, bearing rings, etc., it is sometimes used to make tools, such as dies, measuring tools, etc. [0003] In the process...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22B1/02B02C23/08B03C1/02C21B13/00C21B13/10B22F3/10B22F8/00
CPCB02C23/08B03C1/02B22F3/1007B22F8/00B22F2999/00C21B13/0033C21B13/0073C21B13/10C22B1/02B22F2201/01Y02W30/50Y02P10/20
Inventor 王勇齐涛常朝
Owner INST OF PROCESS ENG CHINESE ACAD OF SCI
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