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A kind of medicinal polyester bottle with low acetaldehyde content and preparation method thereof

A polyester bottle and low acetaldehyde technology, which is applied in the field of low acetaldehyde content medicinal polyester bottle and its preparation, can solve the problem of low acetaldehyde polyester products being unsuitable, reducing product profits, and increasing the production cost of polyester bottles and other problems, to achieve the effect of strong thermal stability, environmental friendliness and non-toxicity

Active Publication Date: 2021-07-27
GUIZHOU CHIEN YEH PLASTIC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, this patented method can only control the acetaldehyde content within the range of 10-30ppm, which is 50 times higher than the limit of no more than 2 / 10000000 (that is, the acetaldehyde content does not exceed 0.200ppm) stipulated in the national pharmaceutical packaging material standard. Above, therefore, the low-acetaldehyde polyester product made by this patent is not suitable for pharmaceutical packaging materials
[0004] In order to solve the problem of excessive acetaldehyde content in polyester bottles of medicine bottles, many domestic color oil manufacturers have launched various acetaldehyde reducer products. The risk of excessive residues and easy oxides, and the cost of acetaldehyde reducer products are 30 to 50 times that of polyester chips, which greatly increases the production cost of polyester bottles, reduces product profits, and seriously affects the market for polyester bottles. Competitiveness

Method used

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  • A kind of medicinal polyester bottle with low acetaldehyde content and preparation method thereof
  • A kind of medicinal polyester bottle with low acetaldehyde content and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033]A medicinal polyester bottle with low acetaldehyde content is made of the following raw materials in parts by weight: 99.0 parts of water bottle-grade polyester chips, 0.05 parts of sarin resin, 0.50 parts of acetaldehyde reducer, and 0.10 parts of organic coloring agent; The acetaldehyde reducer is made from the following raw materials in parts by weight: 5.0 parts of anthranilamide, bis[4-(1-methyl-1-phenylethyl)-2,6-diisopropylphenyl ] 0.05 parts of carbodiimide, 40.0 parts of tributyrin.

[0034] Further, the preparation method of the described acetaldehyde-reduced medicinal polyester bottle with low acetaldehyde content is as follows:

[0035] ①Weigh anthranilamide, bis[4-(1-methyl-1-phenylethyl)-2,6-diisopropylphenyl]carbodiimide, tributyrin according to parts by weight ester;

[0036] ②Put tributyrin in a dry reaction kettle first, heat to 119°C, stir and pass dry nitrogen protection, continue stirring to keep the system at a constant temperature of 119°C;

[0...

Embodiment 2

[0044] A medicinal polyester bottle with low acetaldehyde content is made of the following raw materials in parts by weight: 100.0 parts of water bottle-grade polyester chips, 1.50 parts of sarin resin, 1.50 parts of acetaldehyde reducing agent, and 1.50 parts of organic coloring agent; The acetaldehyde reducer is made from the following raw materials in parts by weight: 40.0 parts of anthranilamide, bis[4-(1-methyl-1-phenylethyl)-2,6-diisopropylphenyl ] 0.15 parts of carbodiimide, 100.0 parts of tributyrin.

[0045] Further, the preparation method of the described acetaldehyde-reduced medicinal polyester bottle with low acetaldehyde content is as follows:

[0046] ①Weigh anthranilamide, bis[4-(1-methyl-1-phenylethyl)-2,6-diisopropylphenyl]carbodiimide, tributyrin according to parts by weight ester;

[0047] ②Put tributyrin in a dry reaction kettle first, heat to 122°C, stir and pass dry nitrogen protection, continue stirring to keep the system at a constant temperature of 1...

Embodiment 3

[0055] A medicinal polyester bottle with low acetaldehyde content, made of the following raw materials in parts by weight: 99.2 parts of water bottle-grade polyester chips, 0..50 parts of sarin resin, 0.60 parts of acetaldehyde reducing agent, and 0.50 parts of organic coloring agent part; the acetaldehyde reducer is made from the following raw materials in parts by weight: 10.0 parts of anthranilamide, two [4-(1-methyl-1-phenylethyl)-2,6-diisopropyl phenyl] carbodiimide 0.10 parts, tributyrin 50.0 parts.

[0056] Further, the preparation method of the described acetaldehyde-reduced medicinal polyester bottle with low acetaldehyde content is as follows:

[0057] ①Weigh anthranilamide, bis[4-(1-methyl-1-phenylethyl)-2,6-diisopropylphenyl]carbodiimide, tributyrin according to parts by weight ester;

[0058] ②Put tributyrin in a dry reaction kettle first, heat to 120°C, stir and pass dry nitrogen protection, continue stirring to keep the system at a constant temperature of 121°...

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Abstract

The invention discloses a medicinal polyester bottle with low acetaldehyde content, which is made of the following raw materials in parts by weight: 99.0-100.0 parts of water bottle-grade polyester chips, 0.05-1.50 parts of sarin resin, and 0.50-100 parts of acetaldehyde reducing agent. 1.50 parts, 0-1.50 parts of organic colorant; the acetaldehyde reducer is made of the following raw materials in parts by weight: 5.0-40.0 parts of anthranilamide, bis[4-(1-methyl-1-phenyl Ethyl)-2,6-diisopropylphenyl] carbodiimide 0.05-0.15 parts, tributyrin 40.0-100.0 parts. The present invention adds an acetaldehyde reducing agent, and the acetaldehyde produced in the degradation reaction process can remove more than 95% of the acetaldehyde in the medicinal polyester bottle, and can make polyester chips with an original acetaldehyde content of 1.0-2.0ppm A polyester bottle with an acetaldehyde content of less than 0.1ppm.

Description

technical field [0001] The invention belongs to the technical field of pharmaceutical packaging, in particular to a medicinal polyester bottle with low acetaldehyde content and a preparation method thereof. Background technique [0002] PET resin containers are not only light in weight, good in physical and mechanical properties, but also resistant to chemicals. It is an ideal plastic product to replace glass containers. However, at present, it is difficult for domestic water bottle-grade PET chips to meet the standard of low acetaldehyde content, and the YBB standard stipulates that the acetaldehyde content of polyester bottles shall not exceed two parts per million. The aldehyde content does not exceed the standard. For example: patent application CN201710476875.2 discloses a high heat-resistant medicinal polyester bottle and its manufacturing method. PET, PENT and PEN resins are used for blending modification to form a bottle with high heat resistance. It is a high polym...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L67/00C08L23/08C08K5/20C08K5/29C08K3/04C08K13/02
CPCC08L67/00C08L2201/10C08L23/0876C08K5/21C08K5/3465C08K3/04C08K13/02
Inventor 郑文学陈洋胡红群张亚红冯胜容张浩轩张镇宇杨昌玲王辉舒华
Owner GUIZHOU CHIEN YEH PLASTIC