560results about How to "Shorten crystallization time" patented technology

The invention discloses a titanium silicalite TS-1 catalyst preparation method. Cheap inorganic Titanium silicalite is used as raw material, low quantity of tetrapropylammonium hydroxide or tetrapropylammonium bromide is adopted as template agent, and inorganic alkali such as ammonia water is used as alkali source so that the raw materials for preparation have low price and the production cost isgreatly reduced. The precursor preparation process is simple and easy to control, seed crystal is added to reduce the crystallization time and the repeatability is good. As secondary crystallization is adopted, the non-framework titanium is further reduced, and the acid site of the molecular sieve is reduced, the grain size is controllable within certain range, the molecular sieve channel becomessmoother to facilitate direct membrane separation of micrometer crystalline grains, and the obtained Titanium silicalite TS-1 catalyst has large grains, high activity, stable catalytic performance and broad industrial application prospect.

A silicon film provided on a blocking film 102 on a substrate 101 is made amorphous by doping Si+, and in a heat-annealing process, crystallization is started in parallel to a substrate from an an 100 where lead serving as a crystallization-promoting catalyst is introduced.

The invention relates to ZSM-5 molecular sieve with small crystal grains and application thereof, mainly solving the technical problems that the silica-alumina molar ratio (SiO2/Al2O3) of ZSM-5 molecular sieves with small crystal grains is less than 200, and the traditional ZSM-5 molecular sieves have poor catalyst stability and short service life when used for reaction for preparing propylene from methanol in the prior art. The invention well solves the problems by the technical scheme that the ZSM-5 molecular sieve with small crystal grains, which has a crystal diameter less than 300 microns and a SiO2/Al2O3 molar ratio not less than 200, is used for reaction for preparing the propylene from the methanol. The invention can be used in industrial production for preparing the propylene from the methanol.

Provided is a method for rapidly synthesizing a silicoaluminophosphate SAPO-34 molecular sieve, wherein triethylamine and/or diethylamine are/is used as templating agents, an organic amine accelerator is added to the initial gel for synthesis at the same time, and the gel mixture is optionally subjected to aging treatment. The method could give SAPO-34 molecular sieves with high crystallization degree in a relative short crystallization period. The SAPO-34 molecular sieve catalysts synthesized by the method can be used in the MTO or DTO reaction, the selectivity of C₂~C₃ olefins in the product could be up to about 90%.

A method for synthesizing MCM-22 molecular screen, which possesses MWW topological structure, employing silicon, aluminium, alkali, mould agent and deionized water as reacting raw material, blooming under the temperature of 135-185 Deg C for some time, hydrothermal synthesizing the needed molecular screen; the invention is characterized by using diamin liquid mixture (BA) as mould agent to prepare molecular screen, one (SDAI) is hexamethylene amine (HMI), another (SDA2) is any one of the followings: cyclohexylamine (CHA)or buta (BuA) or isopropyl amine (IPA).

An IM-5 molecular sieve synthesis method comprises the following steps: 1, dissolving an inorganic alkali, an aluminum source and a template in deionized water, and uniformly mixing to prepare a mixed solution; 2, adding a solid silica gel to the mixed solution obtained in step 1, adding a template precursor, and uniformly mixing to prepare a colloid or a solid-liquid mixture; and 3, transferring the colloid or solid-liquid mixture obtained in step 2 to a crystallization kettle, carrying out hydrothermal crystallization for 1-10 days, cooling after the crystallization to obtain a mixed liquid, and washing, filtering and drying the mixed liquid to obtain raw IM-5 molecular sieve powder, wherein reactants comprise SiO2, Al2O3, M2O, R, A and H2O, a molar ratio of SiO2:Al2O3:M2O:R:A:H2O is 60:(0.3-6):(6-20):(4-15):(1.2-6):(300-1200), M2O is an alkali metal oxide, R is the template, and A is the template precursor. The IM-5 molecular sieve synthesis method has the advantages of good product repeatability, effective reduction of the water content, increase of the concentration of the template, crystallization time shortening and single kettle yield increase.

The invention aims at providing a pantoprazole sodium freeze-dried powder injection and comprises pantoprazole sodium and mannitol with the weight ratio of 1: 2 to 5. The invention is simple in formula and little in side effect; products prepared by the method are plump in appearance, good in complex solubility and excellent in quality with the adoption of an advanced freezing and drying process.

The invention relates to a doping modified phase change material and a phase change storage unit containing same and preparation thereof. The formula of the doping modified phase change material is (Sb2Se3)100-xYx, wherein, x is the atom percentage of an element and is more than 0 and less than or equal to 20, and Y is a doped element and is any one of Ni, Cr, Bi, As, Ga, In, Ge, Si, Sn, Ag, Al, C, N and O. The doping modified (Sb2Se3)100-xYx storage material not only remains the advantages of the fast phase change speed and the low melting point of Sb2Se3 storage material, but also increases crystallization temperature, thus overcoming the disadvantage of poor data retentivity of the Sb2Se3 storage material. The phase change storage containing the (Sb2Se3)100-xYx storage material has the advantages of high speed, low power consumption and favorable data retentivity and the like.

A silicon film provided on a blocking film 102 on a substrate 101 is made amorphous by doping Si+, and in a heat-annealing process, crystallization is started in parallel to a substrate from an area 100 where nickel serving as a crystallization-promoting catalyst is introduced.

The invention relates to a method for preparing a NaY molecular sieve with a high aluminum-silicon ratio, which comprises the following steps of: mixing a silicon source, an aluminum source and deionized water, uniformly mixing two guide agents in different molar ratios, water glass, acidic aluminum salt and sodium aluminate solution in a molar ratio of gel materials to prepare two gels, and crystallizing respectively, wherein the molar ratio of the gel materials is (1.0-6.5)Na2O:Al2O3:(5.0-18)SiO2:(100-280)H2O, and Al2O3 in the guide agents accounts for 0.01 to 15 percent of the total weightof Al2O3; uniformly mixing the two gels in a mass ratio of 1:(0.1-10) to prepare a mixed gel; and crystallizing the prepared mixed gel at the temperature of between 80 and 120 DEG C for 2 to 50 hoursto prepare the NaY molecular sieve. Compared with the prior art, the method has the advantages that: the NaY molecular sieve with the high aluminum-silicon ratio can be prepared in shorter time underthe condition of the same feeding molar ratio.

The invention relates to a preparation method of a molecular sieve, and provides a method for preparing ZSM-22 molecular sieve by using a seed crystal synthesis method. The method comprises the following steps of: uniformly mixing deionized water with aluminum sulfate; adding alkali sources into a mixture; adding tetraethoxysilane under stirring; continuously stirring until the solution is uniform to form silicon-aluminum gel; adding ZSM-22 molecular sieve crystal seed to stir; putting the mixture into a reaction kettle for crystallization reaction; and filtering and drying a product to obtain ZSM-22 molecular sieve raw powder. By using the preparation method, the application of organic template agent is eliminated, the crystallization time is shortened, the crystallization temperature is reduced, and the industrial application is facilitated; the product keeps good crystallization degree and purity and high catalytic reaction activity; the unnecessary loss during production is reduced; the product has a potential application value on some important catalytic reaction; and inorganic raw materials used in production is environmentally-friendly and low in cost.

The invention relates to a cubic mesoporous molecular sieve catalyst with micropore canals, a preparation method and use thereof. The catalyst comprises the raw materials of an aluminium source, a silicon source, sodium hydroxide, a template, surfactant and de-ionized water, and is prepared through the following steps: firstly preparing a silicon-aluminium precursor; and then utilizing a self-assembly function between the precursor and the surfactant to obtain stable molecular sieve materials. The preparation method comprises two methods of hydro-thermal synthesis and microwave synthesis. Dueto the adoption of the microwave synthesis method, the cubic mesoporous molecular sieve catalyst in the invention has the advantages of shortening the crystallization time, obtaining a synthesized molecular sieve with a cubic mesoporous structure, having micropore canals, having acid strength similar to that of a ZSM-5 molecular sieve, and having relatively higher catalytic activity when used forthe catalytic cracking reaction of 1,3,5-tri-isopropyl benzene.

The invention provides a clindamycin phosphate freeze-dried powder injection, which is prepared by the steps that: clindamycin phosphate solution is added with NaOH and is freeze-dried, wherein, the weight ratio of clindamycin phosphate to the NaOH is between 12 and 18 to 1, and the preferred weight ratio is 16.5 to 1. The clindamycin phosphate freeze-dried powder injection has simple formula and less auxiliary materials, overcomes side effects due to the fact that the auxiliary materials are excessively added, and ensures that patients are safer for use.

The present invention relates to the technical field of a zeolite molecular sieve synthesis, concretely speaking, relating to a preparation method of a zeolite molecular sieve of a nano heteroatom. A sodium silicate or a soluble glass, an inorganic acid, an inorganic ferric salt, an organic amine and deionized water serve as the material. After the steps of liquor preparation, two variable temperature crystallizations, washing-up centrifugalization, drying and roasting, the zeolite molecular sieve of nano Fe-ZSM-5 is produced with a grain size less than 100nm. The present invention can be used in the petrochemical industry, fine chemical industry and the environmental protection field.

The invention discloses a synthesis method of an SAPO-34 molecular sieve. The method includes the following steps of: (1) uniformly mixing a template agent, aluminum source, silicon source and water to obtain mixed liquid; (2) adding the solid-state seed crystal of raw powder of the SAPO-34 molecular sieve not less than 0.1 time of the mass of SiO2 in the silicon source to the mixed liquid obtained in the step (1) and mixing uniformly to obtain mixed liquid; (3) adding phosphorus source to the mixed liquid obtained in step (2) and mixing uniformly to obtain mixed liquid; (4) filling the mixed solution obtained in step (3) in a crystallization kettle and crystallizing at crystallization temperature; and (5) conducting centrifugal separation and filtration of the crystallized mixed solution and finally obtaining SAPO-34 raw powder after drying solid samples. The method mainly solves the problems of high cost of catalyst preparation and serious pollution caused by large amount of the template agent used for synthesizing the SAPO-34 molecular sieve in the prior art.

The invention relates to a synthetic method for a hierarchical-pore ZSM-5 molecular sieve. The method synthesizes the hierarchical-pore ZSM-5 molecular sieve with a high crystallization degree, strong acidity and good hydro-thermal stability from a small amount of a microporous template and a polymer of quaternary ammonium salt without usage of a hard template.

The invention relates to a method for preparing mesoporous gamma-Al2O3 by a dynamic hydrothermal method, belonging to the field of preparation of inorganic porous materials. The invention aims to solve the problems that in the prior art, reaction steps are multiple, experimental conditions are difficult to control, products are incompletely crystallized, the reaction time is too long, and a static reaction does not facilitate full contact among reaction materials. The method comprises the following steps of: adding inorganic aluminum salt and a precipitating agent into surfactant solution respectively, and uniformly mixing the inorganic aluminum salt with the precipitating agent; continuously stirring the mixed solution, and performing hydrothermal treatment; and washing and calcinating obtained products after finishing the reaction, and thus obtaining the mesoporous gamma-Al2O3. The method has the advantages that: the reaction is performed more fully, the formation of alumina precursors can be simply controlled, the formation of mesoporous alumina can be effectively controlled, the crystallization time is shortened to be less than 24 hours, the preparation period is short, and the method is suitable for large-scale continuous production.