Pesticide industry site volatile odor substance sampling and evaluation device and evaluation method
An evaluation device and volatility technology, applied in sampling devices, measuring devices, sampling, etc., can solve problems such as disturbance, large changes in the concentration of odorous substances, and large differences in diffusion attenuation of odorous substances, and achieve the effect of ensuring uniformity
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Embodiment 1
[0055] Volatile odor substances are collected in a pesticide industry site. The box body 1 has a square design of 50cm×50cm×150cm in length, width and height. The temperature inside the cabinet 1 is 24.2°C, and the relative humidity is 86.7%. The rain-proof device 9 is used to place above the sampling hole 2 of the cabinet to prevent the power supply device 5 from being wet by rain during sampling.
[0056] Turn on the fan 4 switch, unscrew the sealing plug 3 of the sampling hole 2 of the sampling evaluation device after 1 hour, and use the air bag to collect the gas in the box body 1, refer to "Ambient Air Volatile Organic Compounds Determination Adsorption Tube Sampling - Thermal Desorption Gas Chromatography - Mass spectrometry" (HJ644-2013) for detection, the concentration of benzene is 468.7μg / m 3 .
[0057] As a control, a synchronous sampling was performed at a height of 1.5 meters outside the sampling evaluation device. The sampling method was the same as in Example 1...
Embodiment 2
[0063] Volatile odor substances are collected in a pesticide industry site. The box body 1 has a square design of 50cm×50cm×100cm in length, width and height. The temperature inside the cabinet 1 is 25.1° C., and the relative humidity is 90.5%.
[0064] Turn on the fan 4 switch, unscrew the sealing plug 3 of the sampling hole 2 of the sampling evaluation device after 6 hours, and use the air bag to collect the gas in the box body 1, refer to "Ambient Air Volatile Organic Compounds Determination Adsorption Tube Sampling - Thermal Desorption Gas Chromatography -Mass spectrometry" (HJ644-2013) for detection, the gas concentration of volatile benzene was 687.3, 685.4, 686.1 μg / m3 respectively 3 .
Embodiment 3
[0066] Volatile odor substances are collected in a pesticide industry site, and the box 1 is a cylindrical design with a diameter of 50 cm and a height of 150 cm. The temperature inside the cabinet 1 is 28.6° C., and the relative humidity is 80%.
[0067] Turn on the fan switch, use an air bag to collect samples and evaluate the gas in the device after 2 hours and 3 hours respectively, refer to "Determination of Volatile Organic Compounds in Ambient Air Adsorption Tube Sampling - Thermal Desorption Gas Chromatography - Mass Spectrometry" (HJ 644-2013) Detected, the concentration of ethylbenzene obtained was 137.8 μg / m 3 and 185.0 μg / m 3 .
[0068] According to the rate of change of gas concentration with time, the average emission flux (F) of ethylbenzene from 2 hours to 3 hours can be calculated as 64.09 μg m -2 h -1 .
[0069]
[0070] In the formula: ρ is the density of the gas in the standard state, that is, 4.74g L -1 ; H is the height of box 1, that is, 1.5m; T ...
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