Method for Reconstructing Powder Resin to Form Floc Resin to Remove Nitrate in Water

A technology of powder resin and water removal, which is applied in chemical instruments and methods, flocculation/sedimentation water/sewage treatment, water/sewage treatment, etc. It can solve the problems of non-adsorption, difficulty in popularization, and secondary pollution of water bodies, etc. question

Active Publication Date: 2020-08-14
SHANDONG JIANZHU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

For the addition of adsorption materials, on the one hand, it is necessary to solve the problem of adsorption efficiency, and on the other hand, it is necessary to solve the problem of secondary pollution. Therefore, for the safety of water quality, particle adsorption materials that do not react with water are often used, and the particle size is mostly at the millimeter level. In order to facilitate the later stage The density needs to be greater than that of water to be removed by sedimentation, causing the particles to sink to the bottom of the tank soon, and will be removed from the sedimentation tank as sediment before reaching its saturated adsorption capacity, and it is difficult to exert the non-adsorption effect
[0004] For adding equipment, there are only more than ten working days a year, which leads to low utilization rate of equipment, and daily maintenance of equipment, and requires more land occupation, which puts great pressure on the economic cost of small and medium-sized water plants. Therefore, conventional treatment methods It is not suitable as an emergency treatment measure to deal with sudden pollution, and it is difficult to promote it. It is also difficult for regulatory agencies to supervise due to the short time. Mandatory installation of nitric acid removal equipment does not conform to the trend of the times, and it is only mandatory installation without supervision. Equipment maintenance, long-term idle will also cause secondary pollution to the water body

Method used

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  • Method for Reconstructing Powder Resin to Form Floc Resin to Remove Nitrate in Water
  • Method for Reconstructing Powder Resin to Form Floc Resin to Remove Nitrate in Water
  • Method for Reconstructing Powder Resin to Form Floc Resin to Remove Nitrate in Water

Examples

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Embodiment 1

[0029] A method for reconstitution of powder resin to form floc resin to remove nitrate in water, characterized in that it comprises the following steps:

[0030] Step 1: Detect nitrate content in water;

[0031] Step 2: If the nitrate content exceeds the standard, then dosing powder resin while adding coagulant to the flocculation tank, so that the coagulant and powder resin are reconstituted to form resin flocs, the particle size of the powder resin It is 50-100 micron, and described coagulant is iron salt coagulant and / or aluminum salt coagulant; Mixing with the coagulant in the aqueous solution is conducive to the complete reconstitution of the powder resin and the coagulant to form resin flocs, preventing the unreconstructed powder resin from remaining in the water.

[0032] The powder resin is an anionic resin containing a basic group, and the basic group includes but is not limited to: —N(CH 3 ) 3 OH, -NH 2 ,—NH 2 , the reconstruction method of the structure of the...

Embodiment 2

[0038] A method for removing nitrate in water by reconstitution of powder resin to form floc resin, comprising the following steps: detecting the content of nitrate in water;

[0039] If the nitrate content exceeds the standard, then add the powdered resin while adding the coagulant to the flocculation tank, so that the coagulant and the powdered resin are reconstituted to form resin flocs, and the particle size of the powdered resin is 50- 100 microns, the powder resin is an anionic resin containing basic groups, the basic groups include but not limited to: —N(CH 3 ) 3 OH, -NH 2 ,—NH 2 , the reconstruction method of the structure of the resin by using the coagulant is adsorption neutralization and / or adsorption bridging. As a preference, before adding the powder resin while adding the coagulant to the flocculation tank, mix the powder resin with the mixture The coagulant is mixed in the aqueous solution. Specifically, the feeding pipe of the flocculant dosing device of the...

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Abstract

The invention discloses a method for removing nitrates in water by a floc resin formed by reconstruction of a powder resin. The method comprises the following steps: the nitrate content in water is detected; if the nitrate content exceeds the standard, a coagulant is added to a flocculation tank and the powder resin is simultaneously added to reconstitute the coagulant and the powder resin to formthe resin floc; and the nitrates in the water are adsorbed by the resin floc in a precipitation tank, and after reaching adsorption saturation, the resin floc settles to the bottom of the tank to remove the resin floc from the water. Any equipment is not needed to add, when sudden nitrate exceeding the standard happens, treatment equipment of an original water plant is used, removal of the nitrates can be realized by adding the powder resin and increasing an addition amount of the coagulant in the water plant, and water quality requirements for outlet water are met.

Description

technical field [0001] The invention mainly relates to the field of water treatment, in particular to a method for removing nitrate in water by reconfiguring powdered resin to form floc resin. Background technique [0002] In recent years, with the continuous improvement of people's living standards, water safety, especially the sanitation and safety of drinking water, has received more and more attention. Small and medium-sized water plants, especially some small water plants that use traditional techniques, generally use Conventional water treatment process, the conventional water treatment process basically has no ability to remove nitrate, and the excess of nitrate is only usually seasonal, often seasonal, the number of days in a year is more than ten days and it is sudden For example, in the Shandong area, when there is abundant rainwater at the lower level, the external water source will enter the reservoir. Due to the pollution of the water source, the nitrate concent...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F1/52
CPCC02F1/5236
Inventor 许兵武道吉刘佳张旭谭凤训成小翔罗从伟王凯
Owner SHANDONG JIANZHU UNIV
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