Electrode structure and secondary battery
An electrode structure, electrode technology
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no. 1 Embodiment approach
[0034] The electrode structure according to the first embodiment includes an electrode and a separator. The electrode includes an active material-containing layer. The separator includes an organic fiber layer provided on a main surface of the active material-containing layer. The organic fiber layer contains a plurality of organic fibers and resin masses. The resin block is in contact with a part of the main surface of the active material-containing layer. In addition, the resin block is integrated with a part of a plurality of organic fibers. In addition, the length of one side of the circumscribed quadrilateral of the resin block and the length of the side adjacent to one side are each 10 μm or more.
[0035] The organic fiber layer of the electrode structure according to one embodiment contains a resin mass having a relatively large width of 10 μm or more. The resin mass is deposited on a part of the main surface of the active material-containing layer in a state of be...
no. 2 Embodiment approach
[0169] According to the second embodiment, there is provided a secondary battery including the electrode structure according to the first embodiment, a counter electrode, and an electrolyte.
[0170] The electrode structure and the counter electrode can constitute an electrode group. Electrolyte can be held in the electrode group. Furthermore, the secondary battery according to the second embodiment may further include an independent film-type separator disposed between the electrode structure and the counter electrode.
[0171] In addition, the secondary battery according to the second embodiment may further include an exterior member for accommodating the electrode group and the electrolyte.
[0172] In addition, the secondary battery according to the second embodiment may further include a negative terminal electrically connected to the negative electrode and a positive terminal electrically connected to the positive electrode.
[0173] The secondary battery according to ...
Embodiment 1
[0210] First, except that the raw material solution LM1 was changed to the raw material solution LM2 and the diameter of the organic fibers was changed from 0.4 μm to 1.2 μm, deposits of organic fibers were placed on the negative electrode in the same manner as in Comparative Example 1.
[0211] As the raw material solution LM2, a solution obtained by dissolving polyamide (PA) in N,N-dimethylacetamide (DMAc) was used. The concentration of PA in the raw material solution was set to 20% by mass.
[0212] Next, droplets were applied by electrospray deposition on the organic fiber deposit on the negative electrode to form a resin mass. Specifically, the raw material solution LM2 was supplied to an electrospray device, and droplets were applied to the deposit of organic fibers on the negative electrode. At this time, the supply rate of the raw material solution was set to 100 μl / min, and the distance between the spinning nozzle and the surface of the layer containing the negative ...
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Abstract
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