A kind of industrial waste slag imitating natural gypsum and its preparation method and application
An industrial waste residue, imitating natural technology, applied in the field of building materials, can solve the problems of unstable sulfur trioxide, ultra-high moisture and high cost, and achieve the effects of suitable large-scale production, low cost and simple operation
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[0028] The present invention provides the preparation method of industrial waste slag imitation natural gypsum described in the technical scheme, comprising the following steps:
[0029] Mix fluorine gypsum, manganese sulfate waste residue and sodium sulfate waste residue, carry out industrial crystallization reaction, and obtain industrial waste residue imitating natural gypsum;
[0030] The temperature of the industrial crystallization reaction is <65°C.
[0031] In the present invention, the temperature of the industrial crystallization reaction is <65°C, more preferably 50-60°C, most preferably 55-60°C. The invention controls the temperature of the industrial crystallization reaction below 65 DEG C, and can effectively control and prevent crystallization water from being transformed into external moisture. In the present invention, during the industrial crystallization reaction process, fluorogypsum undergoes a crystallization reaction under the excitation of sodium sulfa...
Embodiment 1
[0038] Stir and mix fluorine gypsum, manganese sulfate waste residue and sodium sulfate waste residue according to the mass ratio of 4:5:1, and react at 60°C until the external moisture content meets the national standard (<10wt%). At this time, the reaction time After 5 days, the obtained coarse gypsum was crushed into granules (with a particle size of 50 mm) to obtain industrial waste slag imitating natural gypsum.
Embodiment 2
[0040] Stir and mix fluorine gypsum, manganese sulfate waste residue and sodium sulfate waste residue according to the mass ratio of 2:7:1, and react at 60°C until the external moisture content meets the national standard (<10wt%). At this time, the reaction time After 5 days, the obtained coarse gypsum was crushed into granules (with a particle size of 40 mm) to obtain industrial waste slag imitating natural gypsum.
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