The detection method of the purity of interleukin-12 injection
A detection method and injection technology, applied in the fields of medical testing and drug analysis, can solve problems such as poor stability, achieve reliable detection results, broad application prospects, and improve specificity
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Embodiment 1
[0057] (1) Reagents: trifluoroacetic acid (TEDIA, chromatographically pure), acetonitrile (Fisher, chromatographically pure);
[0058] (2) Instruments: Agilent 1260 liquid chromatograph (Agilent, USA), Agilent 1260DAD detector and OpenLAB processing software (Agilent, USA), AUW220 electronic balance (SHIMADZU, Japan).
[0059] (3) Preparation of samples to be tested
[0060] The concentration of interleukin-12 injection was 15μg / ml.
[0061] (4) Preparation of mobile phase
[0062] Mobile phase A: Pipette 0.5mL of trifluoroacetic acid into a 1L volumetric flask, add water to make the volume, stand for 5min, and then test on the machine;
[0063] Mobile phase B: Pipette 0.5mL of trifluoroacetic acid into a 1L volumetric flask, add acetonitrile to the volume, put it into ultrasonic treatment for degassing for 20min, and set aside.
[0064] (5) Chromatographic conditions
[0065] Chromatographic column: YMC C4 liquid chromatography column (250mm×4.6mm I.D.S-5μm);
[0066] Co...
Embodiment 2
[0072] (1) Reagents: trifluoroacetic acid (TEDIA, chromatographically pure), acetonitrile (Fisher, chromatographically pure);
[0073] (2) Instruments: Agilent 1260 liquid chromatograph (Agilent, USA), Agilent 1260DAD detector and OpenLAB processing software (Agilent, USA), AUW220 electronic balance (SHIMADZU, Japan).
[0074] (3) Preparation of samples to be tested
[0075] The concentration of human interleukin-12 injection is 15 μg / ml.
[0076] (4) Preparation of mobile phase
[0077] Mobile phase A: Pipette 0.5mL of trifluoroacetic acid into a 1L volumetric flask, add water to make the volume, stand for 5min, and then test on the machine;
[0078] Mobile phase B: Pipette 0.5mL of trifluoroacetic acid into a 1L volumetric flask, add acetonitrile to the volume, put it into ultrasonic treatment for degassing for 20min, and set aside.
[0079] (5) Chromatographic conditions
[0080] Chromatographic column: YMC C4 liquid chromatography column (250mm×4.6mm I.D.S-5μm);
[00...
Embodiment 3
[0086] Example 3: Specificity, Column Efficiency, Resolution, Precision Verification Experiment
[0087] S1: Specificity verification experiment:
[0088] (S1-1) Solvent blank interference experiment
[0089] Experimental method: Use a pipette to suck up 1000 μl of mobile phase A and mobile phase B, and inject them into the liquid chromatograph respectively. The chromatographic conditions are the same as those in Example 1, and record the chromatogram to investigate whether the blank mobile phase has any interference effect on the chromatographic measurement results. , the experiment uses mobile phase A as the loading sample, and the chromatogram is obtained. figure 1 ; Take mobile phase B as the loading sample to obtain a chromatogram figure 2 .
[0090] (S1-2) Preparation Buffer Interference Experiment
[0091] Experimental method: Use a pipette to suck up 1000 μl of the preparation Buffer and inject it into a liquid chromatograph. The chromatographic conditions are the...
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