Nanometer TiO2 photocatalyst carried by metal net and its preparation

A photocatalyst, metal mesh technology, applied in physical/chemical process catalysts, chemical instruments and methods, chemical/physical processes, etc., can solve problems such as easy loss, difficult recovery of catalysts, and reduced catalyst utilization, and achieve high commercial value. , broad industrial application prospects, simple and practical effect of the process

A photocatalyst, metal mesh technology, applied in physical/chemical process catalysts, chemical instruments and methods, chemical/physical processes, etc., can solve problems such as easy loss, difficult recovery of catalysts, and reduced catalyst utilization, and achieve high commercial value. , broad industrial application prospects, simple and practical effect of the process

CN1110361CInactive Publication Date: 2003-06-04DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI

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  • Nanometer TiO2 photocatalyst carried by metal net and its preparation
  • Nanometer TiO2 photocatalyst carried by metal net and its preparation
  • Nanometer TiO2 photocatalyst carried by metal net and its preparation

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Passivate and modify the surface of the cleaned stainless steel Φ0.4mm, 20 mesh with concentrated sulfuric acid, soak it in sodium lauryl sulfate for 10 minutes, and then put the metal mesh in a roasting furnace at 500°C in an air atmosphere Roasting for 3 hours, 900°C for 2 hours and cooling naturally; the commercially available Portland cement is sieved through a 200-mesh standard sieve, and mixed with nano-TiO 2 Powder mixed evenly, TiO 2 The amount is 20%; the mixture is added to water to adjust to a certain viscosity, and then coated on the surface of the treated metal mesh material, and the holes that may be blocked are blown away by blowing; when the cement is slightly hardened, then Spray nano-TiO on the surface several times 2 Sol, after drying and curing, the nano-TiO supported by the metal mesh can be obtained 2 Photocatalyst, see accompanying drawing 1. Roll the photocatalyst supported by the above-mentioned metal mesh material into a multi-layer cylinder...

Embodiment 2

[0031] Passivate and modify the surface of the cleaned stainless steel mesh Φ0.4mm and 20 mesh with concentrated sulfuric acid, soak it in sodium lauryl sulfate for 10 minutes, and then put the metal mesh in a roasting furnace under air atmosphere for 500 ℃ for 3 hours, 900 ℃ for 2 hours and naturally cooled; the commercially available Portland cement was sieved through a 200-mesh standard sieve, and mixed with nano-TiO 2 Powder mixed evenly, TiO 2 The amount is 20%; the mixture is added to water to adjust to a certain viscosity, and then coated on the surface of the treated metal mesh material, and the holes that may be blocked are blown away by blowing; when the cement is slightly hardened, then The surface is sprayed several times with nano-TiO containing 0.2% platinum 2 Sol, after drying and curing, the nano-TiO supported by the metal mesh can be obtained 2 Photocatalyst, see accompanying drawing 1. Roll the photocatalyst supported by the above-mentioned metal mesh mate...

Embodiment 3

[0033] Passivate and modify the surface of the cleaned stainless steel mesh Φ0.4mm and 20 mesh with concentrated sulfuric acid, soak it in sodium lauryl sulfate for 10 minutes, and then put the metal mesh in a roasting furnace under air atmosphere for 500 ℃ for 3 hours, 900 ℃ for 2 hours and naturally cooled; the commercially available Portland cement was sieved through a 200-mesh standard sieve, and mixed with nano-TiO 2 Mix powder and 2% activated carbon evenly, TiO 2 The amount is 20%; the mixture is added to water to adjust to a certain viscosity, and then coated on the surface of the treated metal mesh material, and the holes that may be blocked are blown away by blowing; when the cement is slightly hardened, then The surface is sprayed several times with nano-TiO containing 0.2% platinum 2 Sol, after drying and curing, the nano-TiO supported by the metal mesh can be obtained 2 Photocatalyst, see accompanying drawing 1. Roll the photocatalyst supported by the above-men...

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Abstract

The photocatalyst is carried by one 10-200 mesh metallic base net of 0.05-2 mm diameter stainless steel,galvanized iron, copper or aluminum wires. The metallic net is coated with a homogenous layer of mixture of nanometer-level TiO2 in 5-50% and cement or high molecular adhesive as fixing agent in 50-95% and then with a layer of nanometer-level TiO2. The present invention has high activity and less loss of catalyst and is easy to realize in industry.

Description

technical field [0001] The invention relates to a kind of nano-TiO solid-carried by metal mesh 2 Photocatalyst and preparation. Background technique [0002] The control and treatment of environmental pollution is an important issue in the rapid development of photocatalytic technology in the past five years. Nano-TiO 2 As an efficient, non-toxic and long-life photocatalyst, the powder can completely oxidize various organic substances in water to CO 2 and H 2 O, no secondary pollution, has attracted much attention recently. How people have improved TiO 2 A lot of fruitful work has been done in terms of activity. However, because most of them are confined to the suspension system, although the catalyst activity is high, it is easy to lose, and it is difficult to separate from water, and the operating cost is also high, so it is difficult to be applied on a large scale in practice. [0003] At present, on the one hand, the immobilization of catalysts at home and abroad ...

Claims

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Application Information

Patent Timeline
04 Jun 2003
Publication
CN1110361C
IPC
B01J21/06
Inventors
吴鸣; 吴合进