398results about How to "Preparation method science" patented technology

The invention discloses a preparation method of monodispersed M-phase vanadium dioxide nanoparticles. The preparation method comprises the following steps: mixing vanadium pentoxide, oxalate dihydrate and water according to a molar ratio of (1-2.5) : 1 : (500-800) to obtain mixed liquid, adding 4%-6% of a surfactant based on the volume of the mixed liquid into the mixed liquid, and stirring for at least 2 hours to obtain a precursor solution; reacting the precursor solution in a sealed state at 200-260 DEG C for at least 1 day to obtain reaction liquid; performing solid-liquid separation and washing on the reaction liquid in sequence to obtain orthogonal vanadium dioxide powder; annealing the orthogonal vanadium dioxide powder in a nitrogen atmosphere at 300-600 DEG C for 0.5 hour to obtain the monodispersed M-phase vanadium dioxide nanoparticles with particle sizes of 60nm-80nm. The preparation method has the advantages of environmental protection and no temperature gradient control during annealing, and can be widely used for preparing the M-phase vanadium dioxide nanoparticles with very good dispersity.

The hair washing and protecting composition of natural plant components is compounded with tea seed oil or tea cake powder in 75-96 weight portions and ginger powder in 1-30 weight portions as main components, as well as natural vegetable oil in 2-8 weight portions and yolk powder in 1-2 weight portions, with the natural vegetable oil being mint oil, lavender oil, olive oil or sesame oil. It may have different compounding ratio for fitting different hairs. The hair washing and protecting composition of the present invention has functions of eliminating oil and grease, eliminating scurf, stopping itching, improving blood circulation, protecting hair, restoring hair, and improving sleep quality.

The invention discloses a nanometer fire retardant coating and a preparation method thereof. The coating comprises inorganic filler, a film-forming agent, a firm-forming aid, a plasticizer, a cross-linking agent and a drier, wherein the inorganic filler is a modified nanometer composite particle of an inorganic nanometer particle of which the surface is covered with silicon dioxide particles. The preparation method comprises the following steps of: adding the inorganic nanometer particle to a sodium silicate aqueous solution; agitating; adjusting with acid; ageing to obtain mixed sol; performing suction filtration and washing for the mixed sol; drying to obtain the composite particle; sequentially adding the composite particle and a silane coupling agent to ethanol while stirring to perform reflux reaction so as to obtain reaction liquid; alternately centrifugally washing and separating the reaction liquid with ethanol to obtain the modified nanometer composite particle; and then mixing the modified nanometer composite particle, the firm-forming agent, the firm-forming aid, the plasticizer, the cross-linking agent and the drier and performing ball milling, so as to obtain the target product. The nanometer fire retardant coating can perform endothermic reaction to produce a ceramic heat insulating layer in different stages of a fire, and can be widely applied to various situations requiring fire resistance and inflaming retarding performance.

The invention discloses a micron semisphere composed of silver nano-flakes as well as a preparation method and a use thereof. The micron semisphere with the diameter of 1-30mu m is formed by stacking the silver nano-flakes adhered to a conducting substrate into a sector plate, wherein, the plane of the sector plate is vertical to the center of the semisphere; and the nano-flakes forming the sector plate are of a single crystal structure of silver, the length is 0.5-15mu m, the width is 20nm-1mu m and the thickness is 20-50nm. The preparation method comprises the following steps: firstly evenly mixing a silver nitrate aqueous solution with the concentration of 2-32g/L and a citric acid aqueous solution with the concentration of 8-144g/L based on the volume ratio of (0.8-1.2): (0.8-1.2) to obtain an electrolyte; and taking the conducting substrate as a cathode and a graphite flake as an anode to be placed in the electrolyte, and carrying out electro-deposition under constant current with the density of 0.1-1mA/cm<2> for 10-180 minutes to finally obtain the micron semisphere composed of the silver nano-flakes. The obtained micron semisphere can be utilized as a surface enhanced Ramanscattering (SERS) active substrate so as to measure content of rhodamine or polychlorinated biphenyls (PCBs) or p-methyl benzenethiol adhered thereon by utilizing a confocal Raman spectrometer.

The invention discloses a low surface energy polyester film and a preparation method and application thereof. One side of the low surface energy polyester film is a modified polyester layer, and the other side is a low surface energy polyester layer, wherein the modified polyester layer comprises the following components in percentage by weight: 300 to 5,000ppm of antiblocking agent, and the balance of modified polyester; the low surface energy polyester layer comprises the following components in percentage by weight: 90 to 99.9 percent of modified polyester, 0.1 to 10 percent of low surface energy additive, and 300 to 5,000ppm of antiblocking agent. The low surface energy polyester film is simple in structure, scientific in formula and simple and convenient in preparation method, overcomes lots of defects of the prior art, has the advantages of safety, sanitation, corrosion resistance, no conglutination to packaged contents and tight connection with a metal base material, and can be widely applied to metal can food packing industry.

A colloidal gold-silver united test paper used for detecting etiology of important disease on Felidae and Canidae animal is prepared mix-enveloping mouse source RV, CDV, RPV and CPV single-anti being labeled with colloidal gold on glass cellulose membrane to form combination pad; enveloping IgG of purified dog-resisting RV, CDV, FPV and CPV on R, D, F and P positions of detection line at nitric acid cellulose membrane and enveloping rabbit resisting mouse IgG on C position of quality control line at nitric acid cellulose membrane to from detection membrane.

The invention discloses a preparation method of a titanium dioxide nanopore array film. The preparation method comprises the steps of: mixing ammonium fluoride, water and ethylene glycol to obtain an electrolyte, oxidizing a two-electrode system by using a titanium sheet as a positive electrode and graphite as a negative electrode to obtain an electrolyte 1 and an electrolyte 2; then sequentially placing the titanium sheet in the electrolyte 1, the electrolyte 2 and the electrolyte to be oxidized to obtain a titanium oxide sheet; placing the titanium oxide sheet in a hydrofluoric acid to be corroded, blowing the hydrofluoric acid solution by air in a bypass to obtain a titanium oxide film stripped from the titanium oxide sheet; and finally, sequentially respectively placing the titanium oxide film into hydrofluoric acid solutions with different concentrations for being corroded, gradually diluting the hydrofluoric acid solutions until the concentrations reach 0.004-0.006wt percent, and finally preparing the titanium dioxide nanopore array film with thickness of 10-50nm. A target product prepared by adopting the preparation method can be used as a mask for preparing a quantum dot, and can be used as a micro gate to be applied to a sample support of a transmission electron microscope, and is a good filter bacterium film material further.

The invention discloses a film formed by silver nanosheets and a preparation method and application of the film. The film is 200-500nm in thickness and is formed by covering a nanometer flat branch cluster on a conductive substrate, wherein a gap between every two nanometer flat branches in the cluster is 1-15nm; and the film is formed by connecting nanosheets with arc-shaped edges in series, wherein the thickness of each nanosheet is 10-50nm, width is 30-300nm and length is 90-150nm. The preparation method comprises the following steps of: mixing and stirring a silver nitrate water solution, a citric acid water solution and water to obtain a mixed solution, and injecting a sodium borohydride water solution into the mixed solution and stirring and aging to obtain a silver seed crystal solution; then coating the silver seed crystal solution onto the conductive substrate and then airing the conductive substrate; and then putting the conductive substrate which is coated with silver seed crystals and is used as a cathode in electrolyte consisting of the silver nitrate water solution and the citric acid water solution, and carrying out electro-deposition for 5-120 minutes under the constant current of which the current density is 0.1-1mA/cm<2> to obtain the target product. The film disclosed by the invention can be used as an SERS (Surface Enhanced Raman Scattering) active substrate to rapidly detect the content of trace rhodamine 6G or tetrachlorobiphenyl-77 attached onto the SERS active substrate.

The invention discloses a ferroferric oxide nano-composite particle and a preparation method and applications thereof. The composite particle is a ferroferric oxide nano-composite particle with the particle size of 10-30nm, and 1,4-dihydroxy anthraquinone and fluorenylmethoxycarbonyl are modified on the surface of the ferroferric oxide nano-composite particle. The preparation method comprises the steps of: firstly, carrying out a hydrothermal method on ferric trichloride hexahydrate, sodium acetate, 1,6-hexanediamine and ethanediol to obtain the ferroferric oxide nano-composite particle, then producing 1,4-dihydroxy anthraquinone, chloroacetyl chloride, and N,N-dimethylformamide into dyes, then adding the ferroferric oxide nano-composite particle, sodium carbonate and the dyes into acetonitrile to carry out a reflux reaction, carrying out solid-liquid separation, washing and drying on the obtained reaction liquor to obtain an intermediate product, then dispersing the intermediate product into the N,N-dimethylformamide, adding dispersion liquid into the fluorenylmethoxycarbonyl, stirring for 2 hours, and carrying out solid-liquid separation, washing and drying to obtain a target product. The ferroferric oxide nano-composite particle can be used for fast detecting four heavy metal ions, namely copper, zinc, cadmium and mercury in an aqueous solution.

The invention discloses a nanostructure tungsten-zirconium carbide alloy. The nanostructure tungsten-zirconium carbide alloy comprises the following components by weight percentage: 98-99.8% of tungsten, and 0.2-2.0% of zirconium carbide with the grain diameter of 5-300 nm, wherein the zirconium carbide grains are mostly uniformly distributed in the interiors of the tungsten crystal grains. The invention further discloses a preparation method of the alloy. The prepared alloy has good mechanical property and high-temperature stability; the zirconium carbide nanograins can be uniformly distributed in the interiors of the tungsten crystal grains, so that stress concentration and embrittlement generated by coarse particle in the tungsten crystal grains are avoided; the strength and high-temperature performance can be improved by pinning dislocation, and meanwhile, the toughness is ensured.

The invention discloses a nano-composite coating with low surface energy and a preparation method thereof. The nano-composite coating consists of a transition layer and a surface layer, wherein the thickness of the transition layer is between 2 and 200 mu m, and the transition layer consists of more than one layer of mixture of bulbs, clubs and flakes; and the thickness of the surface layer is between 2 and 40 mu m, and the surface layer consists of a reticulated silica glassy substance. The method comprises the steps of: performing cleaning and roughing treatment on the surface of a substrate first, then mixing the bulbs, the clubs, the flakes, a slurry forming agent and a solvent to obtain slurry of the transition layer, using the slurry of the transition layer to coat the substrate, placing the coated substrate at a temperature of between 180 and 250 DEG C to obtain the transition layer, then mixing organosiloxane water solution and alcohol solution of ethyl orthosilicate to obtain hydrolytic polycondensation reaction solution first, then dripping acid into the hydrolytic polycondensation reaction solution to obtain coating solution of the surface layer, coating the substrate coated with the transition layer by the coating solution of the surface layer, and then placing the substrate at a temperature of between 180 and 250 DEG C to obtain the nano-composite coating with low surface energy. The coating has the characteristics of low surface energy, high density, adjustable hardness, good flexibility and strong adhesion force.

The invention discloses a preparation method for a silver nanoparticle chain. At first, an aluminum sheet is processed through an anodic oxidation method so that a through-hole alumina template is obtained; a gold film is plated on one side of the through-hole alumina template in an evaporated mode and then the through-hole alumina template is used as a negative pole and placed in silver electrolyte and bismuth electrolyte respectively for multiple times of alternative electrolytic depositions, so that the alumina template is obtained, wherein the through holes of the through-hole alumina template are placed with the silver cylinders and the bismuth cylinders, the silver cylinders and the bismuth cylinders are connected alternatively and one side of the alumina template is plated with the gold film; then the alumina template is soaked in aqueous alkali, so that a nanowire array which is formed by the alternative connection of the silver cylinders and the bismuth cylinders is obtained; and then the nanowire array is placed in ethylalcohol for ultrasonic dispersion, so that a nanowire which is formed by the alternative connection of the silver cylinders and the bismuth cylinders is obtained; and the nanowire which is formed by the alternative connection of the silver cylinders and the bismuth cylinders is placed in an environment with a vacuum degree<=10 Pa to 3 Pa and a temperature 450 DEG C to 500 DEG C to be annealed for 2 hours to 6 hours, so that a target product is obtained. The preparation method for the silver nanoparticle chain has the advantages of being simple in process, low in cost, high in practical value, and capable of being widely used in the preparation of one-dimensional nanoparticle chains of various metal materials.

The invention relates to a half artificially fed cabbage moth feed and a preparation method thereof. The feed is prepared by mixtures A, B and C, agar and distilled water, wherein the mixture A comprises casein, sucrose, malt meal and wild cabbage powder; the mixture B comprises cellulose, para hydroxybenzoic acid, potassium sorbate and Watkins salt; the mixture C comprises vitamin C, streptomycin sulphate, propyl gallate, vitamin B complex, edible vegetable oil, potassium hydroxide and formalin. The preparation method comprises the following steps: components of the mixture A, B and C are respectively put into a container; 5/6 of the distilled water and the agar powder are added into the container for heating and stirring to thawing; the mixture A is poured into the agar liquid and stirred until uniformity; the mixture B is added and stirred until uniformity; the rest distilled water is added, and the mixture C is added when the temperature is decreased to 70 DEG C, and then stirred until uniformity; the obtained product is filled into moth feeding cups; after the surface moisture is dried, the cups are put into a refrigerator for storage. The preparation method and the feed of the invention are scientific, simple, and easy to standardize propagation the cabbage moth indoors with large scale; the cabbage moth fed with the feed has high larva survival rate, orderly development and sound growth; and the descendants of the cabbage moth have high hatching rate.

The invention relates to a traditional Chinese medicine for treating the chronic pulmonary heart disease. The traditional Chinese medicine comprises the following raw materials, by weight, 10-15 parts of ginseng, 10-15 parts of Radix Ophiopogonis, 10-15 parts of Chinese magnoliavine, 10-15 parts of Rhizoma Atractylodis Macrocephalae, 10-15 parts of Sappanwood, 5-8 parts of Cassia Twig, 10-15 parts of Radix Astragali, 10-15 parts of Salvia miltiorrhiza, 10-15 parts of salted aconite root, 8-12 parts of Tokay Gecko, 10-15 parts of epimeddium, 10-15 parts of Chinese yam, 10-15 parts of bitter apricot kernel, 10-15 parts of Malaytea Scurfpea Fruit, 10-15 parts of Pepperweed Seed, 10-15 parts of Stemona sessilifolia, 10-15 parts of Poria cocos, 10-15 parts of peach kernel, 10-15 parts of Common Coltsfoot Flower, 5-8 parts of fried licorice, 10-15 parts of lumbricus and 10-15 parts of Herba Houttuyniae. The traditional Chinese medicine for treating the chronic pulmonary heart disease of theinvention has the advantages of simple preparation method, easily controlled quality, high cure rate, difficult recurrence, and no toxic side effect.

The present invention discloses an ordered structure array of two-dimensional hollow balls and a preparing method thereof. The array is a single-layer hollow ball array which is provided with an ordered hexagonal arrangement on a substrate. The outer diameter of each hollow ball in the single-layer hollow ball array is 220nm-10.8mu m. An outer surface of each ball is a rough surface. Each hollow ball is composed of a gold metal inner surface and metal gold or polypyrrole or zinc oxide which is coated on the gold metal inner surface. The rough surface is composed of particle-shaped objects or vertical rod-shaped objects. The method comprises the following steps: performing ion sputtering on a conductive substrate which is provided with a single-layer colloid crystal template for depositinga gold film and obtaining a gold film wall array; then placing the conductive substrate which is adhered with the gold film array into electrolyte; performing electrodeposition for 10s-3h with a deposition current density of -1.0-1.0Ma/cm2 for obtaining a complex array; then placing the complex array into a dichloromethane solvent for removing polystyrene colloid balls and preparing the ordered structure array of the two-dimensional hollow balls. The ordered structure array of the two-dimensional hollow balls can be widely used for the following fields: medicament engineering, cosmetic, biotechnology, photocatalysis, photonic device, etc.