The invention relates to a method for preparing a composite catalyst for decomposing ozone. The method comprises the following steps: separately dissolving permanganate, an Mn<II> salt and a Cu<II> salt, so as to obtain three kinds of salt solutions; rapidly mixing the three kinds of salt solutions, stirring, carrying out an oxidation-reduction reaction, and then, carrying out filtrating and washing, so as to obtain filtrated residue of a composite oxide; adding the filtrated residue into water, carrying out mixing so as to form a suspension of the filtrated residue and the water, carrying out extra-fine grinding treatment on the suspension so as to thoroughly grind the suspension, and then, carrying out a freeze-drying process, thereby obtaining the composite catalyst for decomposing the ozone. According to the method provided by the invention, the number of synthesis steps is small, the synthesis conditions are simple, the process of extra-fine grinding treatment is simple, the dispersion effect is good, and various substances in the prepared composite catalyst are thoroughly mixed and doped, so that the catalysis effect is improved remarkably.