Low-permeability reservoir water-lock releasing agent and preparation method thereof

A water-releasing agent and low-permeability technology, applied in chemical instruments and methods, drilling compositions, etc., can solve the problem of unsatisfactory water-locking damage effect, limited application range, and difficulty in taking into account low-permeability reservoir geology and reservoir conditions. And construction technology and other issues, to achieve the effect of removing water lock damage, wide application range, and improving water solubility

Active Publication Date: 2013-01-30
唐山冀油瑞丰化工有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] In order to solve the technical problems that a single type of water-blocking agent is difficult to take into account factors such as geology, reservoir conditions and construction techniques of low-permeability reservoirs, the effect of releasing water-locking damage is not ideal, and the scope of application is limited. The first aspect of the present invention is to provide a surface It is a low-permeability oil reservoir water-blocking agent with strong activity, which makes it easy to flow back into the well fluid, effectively relieves water-locking damage, and maintains the permeability of the reservoir; the second is to provide a preparation method for low-permeability oil reservoir water-blocking agent

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] This embodiment discloses a low-permeability oil reservoir dewatering and locking agent and its preparation method. This low-permeability oil reservoir dewatering and locking agent is composed of 50 g ethylene glycol butyl ether, 90 g N·Nˊ-dodecyl-ethylene glycol Sodium aminodipropionate, 70g ethylene glycol triethylsilyl ether, 160g distilled water. The specific preparation method is:

[0019] In a four-necked 500ml flask with a reflux condenser, a thermometer, and a dropping funnel, add 160g of distilled water, put a stirring magnet, put the flask into a magnetic stirrer with an electric heating jacket, turn on the magnetic stirrer, turn on the heating switch, and the temperature Control at 30-40°C, turn on the cooling water of the reflux condenser; add 50 g of ethylene glycol butyl ether, then add 90 g of N·Nˊ-dodecyl-ethylenediamine dipropionate, and react for 1 hour. Add 70g of ethylene glycol triethylsilyl ether, control the temperature at 70-80°C, and react for ...

Embodiment 2

[0021] This embodiment discloses a low-permeability oil reservoir dewatering and locking agent and a preparation method thereof. By mass, this low-permeability oil reservoir dewatering and locking agent is prepared by adding 50 g of polyethylene glycol methyl ether, 115g N.N'-dodecyl- Sodium ethylenediaminodiacetate, 56g ethylene glycol trimethylsilyl ether, 140g distilled water. The specific preparation method is:

[0022] In a four-necked 500ml flask with a reflux condenser, a thermometer, and a dropping funnel, add 140g of distilled water, put a stirring magnet, put the flask into a magnetic stirrer with an electric heating jacket, turn on the magnetic stirrer, turn on the heating switch, and the temperature Control at 30-40°C, turn on the cooling water of the reflux condenser; add 50 g of polyethylene glycol methyl ether, and then add 115 g of N·Nˊ-dodecyl-ethylenediaminodiacetate, and react for 1 hour. Add 56g of ethylene glycol trimethylsilyl ether, control the temperat...

Embodiment 3

[0024] This embodiment discloses a low-permeability oil reservoir dewatering and locking agent and a preparation method thereof. By mass, this low-permeability oil reservoir dewatering and locking agent consists of 35 g diethylene glycol ether, 80 g N.N'-dodecyl-ethylene glycol Sodium aminodipropionate, 75g polyethylene glycol trimethylsilyl ether, 150g distilled water. The specific preparation method is:

[0025] In a four-necked 500ml flask with a reflux condenser, a thermometer, and a dropping funnel, add 150g of distilled water, put a stirring magnet, put the flask into a magnetic stirrer with an electric heating jacket, turn on the magnetic stirrer, turn on the heating switch, and the temperature Control at 30-40°C, turn on the cooling water of the reflux condenser; add 35 g of diethylene glycol ether, then add 80 g of N·Nˊ-dodecyl-ethylenediamine dipropionate, and react for 1 hour. Add 75g of polyethylene glycol trimethylsilyl ether, control the temperature at 65-75°C, ...

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Abstract

The invention discloses an oil field chemical agent used in petroleum gas oil-pumping operation construction, and particularly relates to a low-permeability reservoir water-lock releasing agent used in working fluid and a preparation method thereof. The low-permeability reservoir water-lock releasing agent consists of the following components in percentage by weight: 1 to 15 percent of glycol ether, 15 to 45 percent of didodecyl dicarboxylic sodium, 15 to 30 percent of ethylene glycol silicon ether and 30 to 60 percent of water. The preparation method comprises the following steps of: adding 30 to 60 percent of water into an enamel reaction kettle, starting a stirrer, and heating to raise the temperature to be between 30 and 40 DEG C; adding 1 to 15 percent of glycol ether and 15 to 45 percent of didodecyl dicarboxylic sodium into the reaction kettle, controlling the temperature and stirring for 1 hour; and adding 15 to 30 percent of ethylene glycol silicon ether into the reaction kettle, controlling the temperature to be between 40 and 80 DEG C, and reacting for 1 to 2 hours to obtain the water-lock releasing agent. The water-lock releasing agent is strong in surface activity and low in use level, can well maintain the permeability of a low-permeability reservoir and release water-lock damages, and is used in the working fluid such as fracturing fluid, perforating fluid, well control fluid and the like.

Description

field of invention [0001] The invention relates to an oilfield chemical agent used in the construction of oil and gas recovery operations, in particular to a low-permeability oil reservoir dehydration and locking agent and a preparation method thereof, which are mainly used in well fluids such as fracturing fluid, perforating fluid and well killing fluid middle. Background technique [0002] Low-permeability reservoirs generally have the characteristics of high capillary pressure, strong water sensitivity, small pore throats, poor permeability, and severe heterogeneity. In the process of oil production, the well fluid is prone to capillary self-absorption in the water phase, causing a large amount of well fluid to enter the reservoir. The poor permeability of low-permeability reservoirs makes it difficult or even impossible to flow back the well fluid that invades the reservoirs, resulting in water lock damage. Domestic and foreign studies have shown that water lock damage...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/584C09K8/86C09K8/035
Inventor 乔孟占何水良彭通张强赵娜
Owner 唐山冀油瑞丰化工有限公司
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