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Halide abx3 perovskite particles and their application in controlling photo-flux

A perovskite and particle technology, applied in the directions of lead halide, tin halide, germanium halide, etc., can solve the problems of unsatisfactory transmittance and economic efficiency

Active Publication Date: 2020-05-08
ZHEJIANG JINGYI NEW MATERIAL TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, these light valves in the prior art are unsatisfactory in terms of transmittance, economic efficiency (energy saving), ease of control and / or ease of use

Method used

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  • Halide abx3 perovskite particles and their application in controlling photo-flux
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  • Halide abx3 perovskite particles and their application in controlling photo-flux

Examples

Experimental program
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Effect test

Embodiment 1

[0042] The preparation of embodiment 1 cesium oleate

[0043] Will Cs 2 CO 3 (4.07g) was charged into a 250mL three-neck flask together with octadecene (50mL, ODE) and oleic acid (11.088g), and the mixture was dried at 120°C for 1 hour, then heated to 150°C under Ar until all Cs 2 CO 3 Both react with oleic acid. Since cesium oleate precipitates out of the ODE at room temperature, it must be warmed up to make it soluble before use.

Embodiment 2

[0044] Example 2CsPbI 3 Synthesis of nanorods

[0045] N,N-Dimethylformamide (100mL, DMF) and PbI 2 2.306 (5mmol) into a 250mL flask. 4.654 g (77.5 mmol) of acetic acid and 0.797 g (4.3 mmol) of dodecylamine were added. in PbI 2 After complete dissolution, 5 mL of cesium oleate solution (prepared as described in Example 1) was added. Then, the mixed solution was added to a 5 L flask together with 4200 mL of toluene.

[0046] Then, the reaction solution was centrifuged at 5000G for 1.5 h and the supernatant was discarded to obtain the light-controlled CsPbI 3 .

[0047] Then, the CsPbI 3 Disperse further with 500 mL of toluene, mix well with shaking and sonication (referred to as LCP-Example-2).

Embodiment 3

[0048] Example 3CsPbBr 3 Synthesis of nanorods

[0049] In the same manner as in Example 2, but using 1.835 g of PbBr 2 Instead of 2.306g PbI 2 . Contains CsPbBr 3 The toluene mixture is called LCP-Example-3.

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Abstract

A light valve containing ABX 3 perovskite particles (200) suspended in a liquid suspension (300) that can control light transmittance is provided. The preferable ABX 3 perovskite particles (200) are halide ABX 3 perovskite particles wherein A is at least one of Cs +, CH 3NH 3 +, and Rb +, B is at least one of Pb 2+, Ge 2+, and Sn 2+, and X is at least one of Cl-, Br-, and I-. Use of the light valve in the manufacture of a light control device and a method of controlling light transmittance by using the light valve are also provided.

Description

[0001] Cross References to Related Applications [0002] This application is required to be filed on July 12, 2018 and is titled "Halide ABX 3 perovskite particles and their application in controlling photo-flux", the disclosure of which is hereby incorporated by reference. technical field [0003] The present invention relates to particles comprising perovskite, in particular ABX 3 Light valves for perovskite particles. The present invention also provides a new use of the light valve and a method of controlling light transmittance by using the light valve. Background technique [0004] Light valves are devices that can electronically control light transmission, and such devices are also scientifically known as electrochromic devices. Technically, like a water valve that controls the flow of water, a light valve is a device that regulates the amount of light passing through a medium. Based on the science behind electrochromic devices, electrochromic devices can be furthe...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G02B26/02G02F1/00
CPCC01G21/006C01P2002/34C01P2004/16C01G19/006C01G17/006C01P2004/64B82Y20/00G02F1/172G02F2202/36Y02E10/549C01D17/003G02F1/155B82Y30/00G02F1/169C01D17/00C01G17/04C01G19/04C01G21/16
Inventor 李亚男张达玮赵世勇肖淑勇梁斌张昱喆
Owner ZHEJIANG JINGYI NEW MATERIAL TECH CO LTD
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