Halide abx3 perovskite particles and their application in controlling photo-flux
A perovskite and particle technology, applied in the directions of lead halide, tin halide, germanium halide, etc., can solve the problems of unsatisfactory transmittance and economic efficiency
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Embodiment 1
[0042] The preparation of embodiment 1 cesium oleate
[0043] Will Cs 2 CO 3 (4.07g) was charged into a 250mL three-neck flask together with octadecene (50mL, ODE) and oleic acid (11.088g), and the mixture was dried at 120°C for 1 hour, then heated to 150°C under Ar until all Cs 2 CO 3 Both react with oleic acid. Since cesium oleate precipitates out of the ODE at room temperature, it must be warmed up to make it soluble before use.
Embodiment 2
[0044] Example 2CsPbI 3 Synthesis of nanorods
[0045] N,N-Dimethylformamide (100mL, DMF) and PbI 2 2.306 (5mmol) into a 250mL flask. 4.654 g (77.5 mmol) of acetic acid and 0.797 g (4.3 mmol) of dodecylamine were added. in PbI 2 After complete dissolution, 5 mL of cesium oleate solution (prepared as described in Example 1) was added. Then, the mixed solution was added to a 5 L flask together with 4200 mL of toluene.
[0046] Then, the reaction solution was centrifuged at 5000G for 1.5 h and the supernatant was discarded to obtain the light-controlled CsPbI 3 .
[0047] Then, the CsPbI 3 Disperse further with 500 mL of toluene, mix well with shaking and sonication (referred to as LCP-Example-2).
Embodiment 3
[0048] Example 3CsPbBr 3 Synthesis of nanorods
[0049] In the same manner as in Example 2, but using 1.835 g of PbBr 2 Instead of 2.306g PbI 2 . Contains CsPbBr 3 The toluene mixture is called LCP-Example-3.
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